The DOI matches its Crossref record; 40 of the 40 references it cites were found in a registry or an index.
Boosting Ethane/Ethylene Separation within Isoreticular Ultramicroporous Metal–Organic Frameworks
Abstract
The separation of ethane from its analogous ethylene is of great importance in the petrochemical industry, but very challenging and energy intensive. Adsorptive separation using C 2 H 6 -selective porous materials can directly produce high-purity C 2 H 4 in a single operation but suffers from poor selectivity. Here, we report an approach to boost the separation of C 2 H 6 over C 2 H 4, involving the control of pore structures in two isoreticular ultramicroporous metal–organic framework (MOF) materials with weakly polar pore surface for strengthened binding affinity toward C 2 H 6 over C 2 H 4 . Under ambient conditions, the prototypical compound shows a very small uptake difference and selectivity for C 2 H 6 /C 2 H 4, whereas its smaller-pore isoreticular analogue exhibits a quite large uptake ratio of 237% (60.0/25.3 cm 3 cm –3 ), remarkably increasing the C 2 H 6 /C 2 H 4 selectivity. Neutron powder diffraction studies clearly reveal that the latter material shows self-adaptive sorption behavior for C 2 H 6, which enables it to continuously maintain close van der Waals contacts with C 2 H 6 molecules in its optimized pore structure, thus preferentially binds C 2 H 6 over C 2 H 4 . Gas sorption isotherms, crystallographic analyses, molecular modeling, selectivity calculation, and breakthrough experiment comprehensively demonstrate this unique MOF material as an efficient C 2 H 6 -selective adsorbent for C 2 H 4 purification.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
Selective gas adsorption and separation in metal–organic frameworks
Li, J.-R., Kuppler, R. J., & Zhou, H.-C. (2009) · Chemical Society Reviews · doi:10.1039/b802426j · Cited by 8,932
Seven chemical separations to change the world
Sholl, D. S., & Lively, R. P. (2016) · Nature · doi:10.1038/532435a · Cited by 4,769
Stable Metal–Organic Frameworks: Design, Synthesis, and Applications
Yuan, S., Feng, L., Wang, K., Pang, J., Bosch, M., Lollar, C., Sun, Y., Qin, J., Yang, X., Zhang, P., et al. (2018) · Advanced Materials · doi:10.1002/adma.201704303 · Cited by 2,981
Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
Bloch, E. D., Queen, W. L., Krishna, R., Zadrozny, J. M., Brown, C. M., & Long, J. R. (2012) · Science · doi:10.1126/science.1217544 · Cited by 1,928
Metal–Organic Frameworks as Platforms for Functional Materials
Cui, Y., Li, B., He, H., Zhou, W., Chen, B., & Qian, G. (2016) · Accounts of Chemical Research · doi:10.1021/acs.accounts.5b00530 · Cited by 1,699
Self-citationPore chemistry and size control in hybrid porous materials for acetylene capture from ethylene
Cui, X., Chen, K., Xing, H., Yang, Q., Krishna, R., Bao, Z., Wu, H., Zhou, W., Dong, X., Han, Y., et al. (2016) · Science · doi:10.1126/science.aaf2458 · Cited by 1,449
Self-citationAdil, K., Belmabkhout, Y., Pillai, R. S., Cadiau, A., Bhatt, P. M., Assen, A. H., Maurin, G., & Eddaoudi, M. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00153c · Cited by 1,324
Metal–Organic Frameworks for Separation
Zhao, X., Wang, Y., Li, D., Bu, X., & Feng, P. (2018) · Advanced Materials · doi:10.1002/adma.201705189 · Cited by 1,305
Adsorbents: fundamentals and applications
(2004) · Focus on Catalysts · doi:10.1016/s1351-4180(04)00383-6 · Cited by 1,256
Metal-Organic Frameworks for Energy Applications
Wang, H., Zhu, Q.-L., Zou, R., & Xu, Q. (2017) · Chem · doi:10.1016/j.chempr.2016.12.002 · Cited by 1,200
A metal-organic framework–based splitter for separating propylene from propane
Cadiau, A., Adil, K., Bhatt, P. M., Belmabkhout, Y., & Eddaoudi, M. (2016) · Science · doi:10.1126/science.aaf6323 · Cited by 1,193
Adsorbents: Fundamentals and Applications
Yang, R. T. (2003) · doi:10.1002/047144409x · Cited by 1,182
New Trends in Olefin Production
Amghizar, I., Vandewalle, L. A., Van Geem, K. M., & Marin, G. B. (2017) · Engineering · doi:10.1016/j.eng.2017.02.006 · Cited by 835
Controlling guest conformation for efficient purification of butadiene
Liao, P.-Q., Huang, N.-Y., Zhang, W.-X., Zhang, J.-P., & Chen, X.-M. (2017) · Science · doi:10.1126/science.aam7232 · Cited by 751
Gücüyener, C., van den Bergh, J., Gascon, J., & Kapteijn, F. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1089765 · Cited by 737
Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene
Li, K., Olson, D. H., Seidel, J., Emge, T. J., Gong, H., Zeng, H., & Li, J. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9039983 · Cited by 713
Yang, S., Ramirez-Cuesta, A. J., Newby, R., Garcia-Sakai, V., Manuel, P., Callear, S. K., Campbell, S. I., Tang, C. C., & Schröder, M. (2015) · Nature Chemistry · doi:10.1038/nchem.2114 · Cited by 665
Efficient purification of ethene by an ethane-trapping metal-organic framework
Liao, P.-Q., Zhang, W.-X., Zhang, J.-P., & Chen, X.-M. (2015) · Nature Communications · doi:10.1038/ncomms9697 · Cited by 660
Potential of microporous metal–organic frameworks for separation of hydrocarbon mixtures
Bao, Z., Chang, G., Xing, H., Krishna, R., Ren, Q., & Chen, B. (2016) · Energy & Environmental Science · doi:10.1039/c6ee01886f · Cited by 647
Self-citationOptimized Separation of Acetylene from Carbon Dioxide and Ethylene in a Microporous Material
Lin, R.-B., Li, L., Wu, H., Arman, H., Li, B., Lin, R.-G., Zhou, W., & Chen, B. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03850 · Cited by 559
Self-citationControl of zeolite framework flexibility and pore topology for separation of ethane and ethylene
Bereciartua, P. J., Cantín, Á., Corma, A., Jordá, J. L., Palomino, M., Rey, F., Valencia, S., Corcoran, E. W., Kortunov, P., Ravikovitch, P. I., et al. (2017) · Science · doi:10.1126/science.aao0092 · Cited by 460
Li, B., Zhang, Y., Krishna, R., Yao, K., Han, Y., Wu, Z., Ma, D., Shi, Z., Pham, T., Space, B., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja502119z · Cited by 455
Grand Challenges and Future Opportunities for Metal–Organic Frameworks
Hendon, C. H., Rieth, A. J., Korzyński, M. D., & Dincă, M. (2017) · ACS Central Science · doi:10.1021/acscentsci.7b00197 · Cited by 434
Nanoscale metal–organic frameworks for phototherapy of cancer
Lan, G., Ni, K., & Lin, W. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.09.007 · Cited by 420
Li, B., Cui, X., O'Nolan, D., Wen, H., Jiang, M., Krishna, R., Wu, H., Lin, R., Chen, Y., Yuan, D., et al. (2017) · Advanced Materials · doi:10.1002/adma.201704210 · Cited by 410
Self-citationTsuzuki, S., Honda, K., Uchimaru, T., Mikami, M., & Tanabe, K. (2000) · Journal of the American Chemical Society · doi:10.1021/ja001901a · Cited by 403
Li, P., Chen, Q., Wang, T. C., Vermeulen, N. A., Mehdi, B. L., Dohnalkova, A., Browning, N. D., Shen, D., Anderson, R., Gómez-Gualdrón, D. A., et al. (2018) · Chem · doi:10.1016/j.chempr.2018.03.001 · Cited by 380
Tuning Pore Size in Square‐Lattice Coordination Networks for Size‐Selective Sieving of CO2
Chen, K., Madden, D. G., Pham, T., Forrest, K. A., Kumar, A., Yang, Q., Xue, W., Space, B., Perry, J. J., Zhang, J., et al. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201603934 · Cited by 303
Direct detection of CH/π interactions in proteins
Plevin, M. J., Bryce, D. L., & Boisbouvier, J. (2010) · Nature Chemistry · doi:10.1038/nchem.650 · Cited by 287
An ethane-trapping MOF PCN-250 for highly selective adsorption of ethane over ethylene
Chen, Y., Qiao, Z., Wu, H., Lv, D., Shi, R., Xia, Q., Zhou, J., & Li, Z. (2018) · Chemical Engineering Science · doi:10.1016/j.ces.2017.09.032 · Cited by 242
Self-citationAbsolute Molecular Sieve Separation of Ethylene/Ethane Mixtures with Silver Zeolite A
Aguado, S., Bergeret, G., Daniel, C., & Farrusseng, D. (2012) · Journal of the American Chemical Society · doi:10.1021/ja305663k · Cited by 240
Bachman, J. E., Kapelewski, M. T., Reed, D. A., Gonzalez, M. I., & Long, J. R. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b06397 · Cited by 236
A phase transformable ultrastable titanium-carboxylate framework for photoconduction
Wang, S., Kitao, T., Guillou, N., Wahiduzzaman, M., Martineau-Corcos, C., Nouar, F., Tissot, A., Binet, L., Ramsahye, N., Devautour-Vinot, S., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-04034-w · Cited by 208
Yang, L., Cui, X., Yang, Q., Qian, S., Wu, H., Bao, Z., Zhang, Z., Ren, Q., Zhou, W., Chen, B., et al. (2018) · Advanced Materials · doi:10.1002/adma.201705374 · Cited by 192
Self-citationPorous Materials and the Age of Gas
Kitagawa, S. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201503835 · Cited by 189
Liang, W., Xu, F., Zhou, X., Xiao, J., Xia, Q., Li, Y., & Li, Z. (2016) · Chemical Engineering Science · doi:10.1016/j.ces.2016.04.016 · Cited by 169
Self-citationMukherjee, S., Desai, A. V., & Ghosh, S. K. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2018.04.001 · Cited by 132
Sen, S., Hosono, N., Zheng, J., Kusaka, S., Matsuda, R., Sakaki, S., & Kitagawa, S. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b10110 · Cited by 94
Energy use and energy intensity of the U.S. chemical industry
Worrell, E., Phylipsen, D., Einstein, D., & Martin, N. (2000) · eScholarship (California Digital Library) · Cited by 45
Cited by
Porous metal-organic frameworks for gas storage and separation: Status and challenges
Li, H., Li, L., Lin, R.-B., Zhou, W., Zhang, Z., Xiang, S., & Chen, B. (2019) · EnergyChem · doi:10.1016/j.enchem.2019.100006 · Cited by 891
Self-citationYang, L., Qian, S., Wang, X., Cui, X., Chen, B., & Xing, H. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00756c · Cited by 746
Self-citationWang, Y., Peh, S. B., & Zhao, D. (2019) · Small · doi:10.1002/smll.201900058 · Cited by 342
Selective Ethane/Ethylene Separation in a Robust Microporous Hydrogen-Bonded Organic Framework
Zhang, X., Li, L., Wang, J.-X., Wen, H.-M., Krishna, R., Wu, H., Zhou, W., Chen, Z.-N., Li, B., Qian, G., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b12428 · Cited by 331
Self-citationYang, H., Wang, Y., Krishna, R., Jia, X., Wang, Y., Hong, A. N., Dang, C., Castillo, H. E., Bu, X., & Feng, P. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b12924 · Cited by 328
Metadata
- Authors
- Lin, R.-B., Wu, H., Li, L., Tang, X.-L., Li, Z., Gao, J., Cui, H., Zhou, W., & Chen, B.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-09-14
- Volume
- 140
- Issue
- 40
- Pages
- 12940-12946
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2892299285
- Cited by
- 452
- References
- 40
- FWCI
- 14.66
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
