The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Constructing NiCo/Fe3O4 Heteroparticles within MOF-74 for Efficient Oxygen Evolution Reactions
Abstract
Metal–organic frameworks (MOF) have recently emerged as versatile precursors to fabricate functional MOF derivatives for oxygen evolution reactions (OER). Herein, we developed a controlled partial pyrolysis strategy to construct robust NiCo/Fe 3 O 4 heteroparticles within MOF-74 for efficient OER using trimetallic NiCoFe-MOF-74 as precursor. The partial pyrolysis method preserves the framework structure of MOF for effective substrates diffusion while producing highly active nanoparticles. The as-prepared NiCo/Fe 3 O 4 /MOF-74 delivered remarkably stable OER current with an overpotential as low as 238 mV at 10.0 mA cm –2 and an Tafel slop of 29 mV/dec, outperforming those of pristine NiCoFe-MOF-74, totally decomposed MOF derivatives, and most reported non-noble metal based electrocatalysts. The key for the formation of NiCo/Fe 3 O 4 /MOF-74 nanostructures is that the metals can be decomposed from NiCoFe-MOF-74 in the order of Ni, Co, and Fe under controlled heat treatment. Density functional theory calculations reveals that the underlying NiCo promotes the OER activity of Fe 3 O 4 through exchange stabilization of active oxygen species.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
Suen, N.-T., Hung, S.-F., Quan, Q., Zhang, N., Xu, Y.-J., & Chen, H. M. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00328a · Cited by 6,307
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00470a · Cited by 5,388
Yang, Y., Lin, Z., Gao, S., Su, J., Lun, Z., Xia, G., Chen, J., Zhang, R., & Chen, Q. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b02573 · Cited by 423
Cited by
Karimi-Maleh, H., Yola, M. L., Atar, N., Orooji, Y., Karimi, F., Senthil Kumar, P., Rouhi, J., & Baghayeri, M. (2021) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2021.02.066 · Cited by 404
Tan, L., Yu, J., Wang, C., Wang, H., Liu, X., Gao, H., Xin, L., Liu, D., Hou, W., & Zhan, T. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202200951 · Cited by 345
Liu, M., Li, N., Cao, S., Wang, X., Lu, X., Kong, L., Xu, Y., & Bu, X. (2022) · Advanced Materials · doi:10.1002/adma.202107421 · Cited by 341
Self-citationDo, V., Prabhu, P., Jose, V., Yoshida, T., Zhou, Y., Miwa, H., Kaneko, T., Uruga, T., Iwasawa, Y., & Lee, J. (2023) · Advanced Materials · doi:10.1002/adma.202208860 · Cited by 254
Metadata
- Authors
- Wang, X., Xiao, H., Li, A., Li, Z., Liu, S., Zhang, Q., Gong, Y., Zheng, L., Zhu, Y., Chen, C., Wang, D., Peng, Q., Gu, L., Han, X., Li, J., & Li, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-10-23
- Volume
- 140
- Issue
- 45
- Pages
- 15336-15341
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2898365681
- Cited by
- 422
- References
- 4
- FWCI
- 9.39
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, X., Xiao, H., Li, A., Li, Z., Liu, S., Zhang, Q., Gong, Y., Zheng, L., Zhu, Y., Chen, C., Wang, D., Peng, Q., Gu, L., Han, X., Li, J., & Li, Y. (2018). Constructing NiCo/Fe3O4 Heteroparticles within MOF-74 for Efficient Oxygen Evolution Reactions. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.8b08744
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