The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Cationic Surfactant-Based Electrolyte Additives for Uniform Lithium Deposition via Lithiophobic Repulsion Mechanisms
Abstract
Lithium metal is among the most promising anode materials for high-energy batteries due to its high theoretical capacity and lowest electrochemical potential. However, dendrite formation is a major challenge, which can result in fire and explosion of the batteries. Herein, we report on hexadecyl trimethylammonium chloride (CTAC) as an electrolyte additive that can suppress the growth of lithium dendrites by lithiophobic repulsion mechanisms. During the lithium plating process, cationic surfactant molecules can aggregate around protuberances via electrostatic attraction, forming a nonpolar lithiophobic protective outer layer, which drives the deposition of lithium ions to adjacent regions to produce dendrite-free uniform Li deposits. Thus, an excellent cycle of 300 h at 1.0 mA cm –2 and rate performance up to 4 mA cm –2 are available safely in symmetric Li|Li cells. In particular, significantly enhanced cycle and rate performance were achieved when the electrolyte with CTAC additives was used in lithium–sulfur and Li|LiNi 0.5 Co 0.2 Mn 0.3 O 2 full cells. The effects of carbon chains, anions of surfactant, and electrostatic repulsion on the deposition of lithium anodes are reported. This work advances research in inhibiting Li dendrite growth with a new electrolyte additive based on cationic surfactants.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Reviving the lithium metal anode for high-energy batteries
Lin, D., Liu, Y., & Cui, Y. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2017.16 · Cited by 6,763
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review
Cheng, X.-B., Zhang, R., Zhao, C.-Z., & Zhang, Q. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00115 · Cited by 6,197
Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
Ding, F., Xu, W., Graff, G. L., Zhang, J., Sushko, M. L., Chen, X., Shao, Y., Engelhard, M. H., Nie, Z., Xiao, J., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja312241y · Cited by 2,107
Self-citationMore Reliable Lithium‐Sulfur Batteries: Status, Solutions and Prospects
Fang, R., Zhao, S., Sun, Z., Wang, D., Cheng, H., & Li, F. (2017) · Advanced Materials · doi:10.1002/adma.201606823 · Cited by 1,785
Yang, C.-P., Yin, Y.-X., Zhang, S.-F., Li, N.-W., & Guo, Y.-G. (2015) · Nature Communications · doi:10.1038/ncomms9058 · Cited by 1,589
Self-citationReviving Lithium‐Metal Anodes for Next‐Generation High‐Energy Batteries
Guo, Y., Li, H., & Zhai, T. (2017) · Advanced Materials · doi:10.1002/adma.201700007 · Cited by 1,215
Zhou, T., Lv, W., Li, J., Zhou, G., Zhao, Y., Fan, S., Liu, B., Li, B., Kang, F., & Yang, Q.-H. (2017) · Energy & Environmental Science · doi:10.1039/c7ee01430a · Cited by 1,056
The rechargeable revolution: a better battery
Van Noorden, R. (2014) · Nature · doi:10.1038/507026a · Cited by 1,047
Liu, Y., Lin, D., Yuen, P. Y., Liu, K., Xie, J., Dauskardt, R. H., & Cui, Y. (2017) · Advanced Materials · doi:10.1002/adma.201605531 · Cited by 990
A Novel Conductive Polymer-Sulfur Composite Cathode Material for Rechargeable Lithium Batteries
Wang, J., Yang, J., Xie, J., & Xu, N. (2002) · Advanced Materials · doi:10.1002/1521-4095(20020704)14:13/14<963::aid-adma963>3.0.co;2-s · Cited by 818
Zhang, H., Eshetu, G. G., Judez, X., Li, C., Rodriguez‐Martínez, L. M., & Armand, M. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201712702 · Cited by 774
Coralloid Carbon Fiber-Based Composite Lithium Anode for Robust Lithium Metal Batteries
Zhang, R., Chen, X., Shen, X., Zhang, X.-Q., Chen, X.-R., Cheng, X.-B., Yan, C., Zhao, C.-Z., & Zhang, Q. (2018) · Joule · doi:10.1016/j.joule.2018.02.001 · Cited by 728
Ultrafine Silver Nanoparticles for Seeded Lithium Deposition toward Stable Lithium Metal Anode
Yang, C., Yao, Y., He, S., Xie, H., Hitz, E., & Hu, L. (2017) · Advanced Materials · doi:10.1002/adma.201702714 · Cited by 661
Beyond lithium ion batteries: Higher energy density battery systems based on lithium metal anodes
Shen, X., Liu, H., Cheng, X.-B., Yan, C., & Huang, J.-Q. (2018) · Energy Storage Materials · doi:10.1016/j.ensm.2017.12.002 · Cited by 653
Lithium Metal Anodes with an Adaptive “Solid-Liquid” Interfacial Protective Layer
Liu, K., Pei, A., Lee, H. R., Kong, B., Liu, N., Lin, D., Liu, Y., Liu, C., Hsu, P.-C., Bao, Z., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b13314 · Cited by 560
Liu, L., Yin, Y., Li, J., Wang, S., Guo, Y., & Wan, L. (2018) · Advanced Materials · doi:10.1002/adma.201706216 · Cited by 538
Lockett, V., Sedev, R., Ralston, J., Horne, M., & Rodopoulos, T. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp7100732 · Cited by 515
Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability
Zhao, J., Liao, L., Shi, F., Lei, T., Chen, G., Pei, A., Sun, J., Yan, K., Zhou, G., Xie, J., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b05251 · Cited by 514
Dendrite-Free Li-Metal Battery Enabled by a Thin Asymmetric Solid Electrolyte with Engineered Layers
Duan, H., Yin, Y.-X., Shi, Y., Wang, P.-F., Zhang, X.-D., Yang, C.-P., Shi, J.-L., Wen, R., Guo, Y.-G., & Wan, L.-J. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b10864 · Cited by 482
Zhang, Z., Kong, L., Liu, S., Li, G., & Gao, X. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201602543 · Cited by 472
Ogihara, N., Itou, Y., Sasaki, T., & Takeuchi, Y. (2015) · The Journal of Physical Chemistry C · doi:10.1021/jp512564f · Cited by 463
Stabilizing Lithium Metal Anodes by Uniform Li-Ion Flux Distribution in Nanochannel Confinement
Liu, W., Lin, D., Pei, A., & Cui, Y. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b08730 · Cited by 455
Effects of Polymer Coatings on Electrodeposited Lithium Metal
Lopez, J., Pei, A., Oh, J. Y., Wang, G.-J. N., Cui, Y., & Bao, Z. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b06047 · Cited by 452
Sulfur–carbon nano-composite as cathode for rechargeable lithium battery based on gel electrolyte
Wang, J. L., Yang, J., Xie, J. Y., Xu, N. X., & Li, Y. (2002) · Electrochemistry Communications · doi:10.1016/s1388-2481(02)00358-2 · Cited by 315
Xue, P., Liu, S., Shi, X., Sun, C., Lai, C., Zhou, Y., Sui, D., Chen, Y., & Liang, J. (2018) · Advanced Materials · doi:10.1002/adma.201804165 · Cited by 257
Self-citationSurfactant adsorption at solid-liquid interfaces
Zhu, B.-Y., & Gu, T. (1991) · Advances in Colloid and Interface Science · doi:10.1016/0001-8686(91)80037-k · Cited by 235
Xing, L., Xi, K., Li, Q., et al. (2015) · Journal of Power Sources · doi:10.1016/j.jpowsour.2015.10.097 · Cited by 193
Self-citationCell energy density and electrolyte/sulfur ratio in Li–S cells
Hagen, M., Fanz, P., & Tübke, J. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.04.018 · Cited by 177
Perspective—Commercializing Lithium Sulfur Batteries: Are We Doing the Right Research?
Cleaver, T., Kováčik, P., Marinescu, M., Zhang, T., & Offer, G. J. (2017) · Journal of The Electrochemical Society · doi:10.1149/2.0071801jes · Cited by 159
Sepúlveda, L., & Cortes, J. (1985) · The Journal of Physical Chemistry · doi:10.1021/j100270a040 · Cited by 156
Study of Electrolyte Additives Using Electrochemical Impedance Spectroscopy on Symmetric Cells
Petibon, R., Aiken, C. P., Sinha, N., Burns, J. C., Ye, H., VanElzen, C. M., Jain, G., Trussler, S., & Dahn, J. R. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.005302jes · Cited by 155
Three-dimensional pie-like current collectors for dendrite-free lithium metal anodes
Yan, K., Sun, B., Munroe, P. R., & Wang, G. (2017) · Energy storage materials · doi:10.1016/j.ensm.2017.10.012 · Cited by 144
Conductivity, Viscosity, and Their Correlation of a Super-Concentrated Aqueous Electrolyte
Ding, M. S., Cresce, A. V. W., & Xu, K. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.6b12636 · Cited by 114
Lithium sulfur and lithium oxygen batteries: new frontiers of sustainable energy storage
Carbone, L., Greenbaum, S., & Hassoun, J. (2017) · Sustainable Energy & Fuels · doi:10.1039/c6se00124f · Cited by 85
Hwang, J., Kim, H. M., & Sun, Y. (2017) · Journal of The Electrochemical Society · doi:10.1149/2.0131801jes · Cited by 49
Cited by
A Review of Solid Electrolyte Interphase (SEI) and Dendrite Formation in Lithium Batteries
Li, B., Chao, Y., Li, M., Xiao, Y., Li, R., Yang, K., Cui, X., Xu, G., Li, L., Yang, C., et al. (2023) · Electrochemical Energy Reviews · doi:10.1007/s41918-022-00147-5 · Cited by 406
Li, F., He, J., Liu, J., Wu, M., Hou, Y., Wang, H., Qi, S., Liu, Q., Hu, J., & Ma, J. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202013993 · Cited by 373
Critical effects of electrolyte recipes for Li and Na metal batteries
Zheng, X., Huang, L., Ye, X., Zhang, J., Min, F., Luo, W., & Huang, Y. (2021) · Chem · doi:10.1016/j.chempr.2021.02.025 · Cited by 367
Guo, W., Zhang, W., Si, Y., Wang, D., Fu, Y., & Manthiram, A. (2021) · Nature Communications · doi:10.1038/s41467-021-23155-3 · Cited by 268
Metadata
- Authors
- Dai, H., Xi, K., Liu, X., Lai, C., & Zhang, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-11-29
- Volume
- 140
- Issue
- 50
- Pages
- 17515-17521
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2902023406
- Cited by
- 283
- References
- 35
- FWCI
- 11.01
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
