The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Efficient Electrocatalytic Proton Reduction with Carbon Nanotube-Supported Metal–Organic Frameworks
Abstract
Hydrogen production from Earth-abundant catalysts remains an important but difficult challenge. Here we report the growth of Hf 12 -porphyrin metal–organic frameworks (MOFs) on carbon nanotubes (CNTs) for electrocatalytic proton reduction. Covalent attachment of MOF nanoplates to conductive CNTs improves electron transfer from the electrode to Co-porphyrin active sites, which leads to effective proton reduction via protonation of a Co I –H intermediate. The Hf 12 –CoDBP/CNT assembly afforded a turnover number of 32 000 in 30 min with a turnover frequency of 17.7 S –1, placing it among the most active Co-based molecular electrocatalysts.
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Zou, X., Huang, X., Goswami, A., Silva, R., Sathe, B. R., Mikmeková, E., & Asefa, T. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201311111 · Cited by 979
Xing, Z., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Advanced Materials · doi:10.1002/adma.201401692 · Cited by 835
Hod, I., Deria, P., Bury, W., Mondloch, J. E., Kung, C.-W., So, M., Sampson, M. D., Peters, A. W., Kubiak, C. P., Farha, O. K., et al. (2015) · Nature Communications · doi:10.1038/ncomms9304 · Cited by 290
Cited by
Metal–Organic Framework-Based Catalysts with Single Metal Sites
Wei, Y.-S., Zhang, M., Zou, R., & Xu, Q. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00757 · Cited by 1,233
Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide
Liang, Z., Wang, H.-Y., Zheng, H., Zhang, W., & Cao, R. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01482f · Cited by 506
Programmable Logic in Metal–Organic Frameworks for Catalysis
Shen, Y., Pan, T., Wang, L., Ren, Z., Zhang, W., & Huo, F. (2021) · Advanced Materials · doi:10.1002/adma.202007442 · Cited by 316
A historical perspective on porphyrin-based metal–organic frameworks and their applications
Zhang, X., Wasson, M. C., Shayan, M., Berdichevsky, E. K., Ricardo-Noordberg, J., Singh, Z., Papazyan, E. K., Castro, A. J., Marino, P., Ajoyan, Z., et al. (2021) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2020.213615 · Cited by 300
Multifunctional metal–organic framework heterostructures for enhanced cancer therapy
Liu, J., Huang, J., Zhang, L., & Lei, J. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00178c · Cited by 285
Metadata
- Authors
- Micheroni, D., Lan, G., & Lin, W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-11-03
- Volume
- 140
- Issue
- 46
- Pages
- 15591-15595
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2898856659
- Cited by
- 182
- References
- 3
- FWCI
- 4.64
- Type
- journal article
- Language
- en
- Open access
- closed
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