The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Controlling the Oxidation State of the Cu Electrode and Reaction Intermediates for Electrochemical CO2 Reduction to Ethylene
Open accessAbstract
Understanding the role of the oxidation state of the Cu surface and surface-adsorbed intermediate species in electrochemical CO 2 reduction is crucial for the development of selective CO 2 -to-fuel electrocatalysts. In this study, the electrochemical CO 2 reduction mechanism over the Cu catalysts with various oxidation states was studied by using in situ surface-enhanced infrared absorption spectroscopy (SEIRAS), in situ soft X-ray absorption spectroscopy (Cu L-edge), and online gas chromatography measurements. The atop-adsorbed CO (CO atop ) intermediate is obtained on the electrodeposited Cu surface which primarily has the oxidation state of Cu(I). CO atop is further reduced, followed by the formation of C 1 product such as CH 4 . The residual bridge-adsorbed CO (CO bridge ) is formed on the as-prepared Cu surface with Cu(0) which inhibits hydrocarbon formation. In contrast, the CV-treated Cu electrode prepared by oxidizing the as-prepared Cu surface contains different amounts of Cu(I) and Cu(0) states. The major theme of this work is that in situ SEIRAS results show the coexistence of CO atop and CO bridge as the reaction intermediates during CO 2 reduction and that the selectivity of CO 2 -to-ethylene conversion is further enhanced in the CV-treated Cu electrode. The Cu catalysts modulated by the electrochemical method exhibit different oxidation states and reaction intermediates as well as electrocatalytic properties.
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CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
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Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
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Grain-Boundary-Dependent CO 2 Electroreduction Activity
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Subsurface Oxygen in Oxide-Derived Copper Electrocatalysts for Carbon Dioxide Reduction
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Cited by
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Boosting electrocatalytic CO2–to–ethanol production via asymmetric C–C coupling
Wang, P., Yang, H., Tang, C., Wu, Y., Zheng, Y., Cheng, T., Davey, K., Huang, X., & Qiao, S.-Z. (2022) · Nature Communications · doi:10.1038/s41467-022-31427-9 · Cited by 574
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Stabilizing Cu2+ Ions by Solid Solutions to Promote CO2 Electroreduction to Methane
Zhou, X., Shan, J., Chen, L., Xia, B. Y., Ling, T., Duan, J., Jiao, Y., Zheng, Y., & Qiao, S.-Z. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c12212 · Cited by 518
Self-citationRole of oxygen-bound reaction intermediates in selective electrochemical CO 2 reduction
Zhi, X., Vasileff, A., Zheng, Y., Jiao, Y., & Qiao, S.-Z. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00740h · Cited by 149
Metadata
- Authors
- Chou, T.-C., Chang, C.-C., Yu, H.-L., Yu, W.-Y., Dong, C.-L., Velasco-Vélez, J.-J., Chuang, C.-H., Chen, L.-C., Lee, J.-F., Chen, J.-M., & Wu, H.-L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-01-20
- Volume
- 142
- Issue
- 6
- Pages
- 2857-2867
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2998895424
- Cited by
- 635
- References
- 8
- FWCI
- 15.18
- Type
- journal article
- Language
- en
- Open access
- green
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- Chou, T.-C., Chang, C.-C., Yu, H.-L., Yu, W.-Y., Dong, C.-L., Velasco-Vélez, J.-J., Chuang, C.-H., Chen, L.-C., Lee, J.-F., Chen, J.-M., & Wu, H.-L. (2020). Controlling the Oxidation State of the Cu Electrode and Reaction Intermediates for Electrochemical CO2 Reduction to Ethylene. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b11126
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