The DOI matches its Crossref record; 55 of the 55 references it cites were found in a registry or an index.
Selective Ethane/Ethylene Separation in a Robust Microporous Hydrogen-Bonded Organic Framework
Open accessAbstract
The separation of ethane (C 2 H 6 ) from ethylene (C 2 H 4 ) is of prime importance in the production of polymer-grade C 2 H 4 for industrial manufacturing. It is very challenging and still remains unexploited to fully realize efficient C 2 H 6 /C 2 H 4 separation in the emerging hydrogen-bonded organic frameworks (HOFs) due to the weak nature of hydrogen bonds. We herein report the benchmark example of a novel ultrarobust HOF adsorbent (termed as HOF-76a) with a Brunauer–Emmett–Teller surface area exceeding 1100 m 2 g –1, exhibiting the preferential binding of C 2 H 6 over C 2 H 4 and thus highly selective separation of C 2 H 6 /C 2 H 4 . Theoretical calculations indicate the key role of the nonpolar surface and the suitable triangular channel-like pores in HOF-76a to sterically “match” better with the nonplanar C 2 H 6 molecule than the planar C 2 H 4, thus affording overall stronger multipoint van der Waals interactions with C 2 H 6 . The exceptional separation performance of HOF-76a for C 2 H 6 /C 2 H 4 separation was clearly demonstrated by gas adsorption isotherms, ideal adsorbed solution theory calculations, and simulated and experimental breakthrough curves. Breakthrough experiments on HOF-76a reveal that polymer-grade ethylene gas can be straightforwardly produced from 50/50 (v/v) C 2 H 6 /C 2 H 4 mixtures during the first adsorption cycle with a high productivity of 7.2 L/kg at 298 K and 1.01 bar and 18.8 L/kg at 298 K and 5.0 bar, respectively.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials
Giannozzi, P., Baroni, S., Bonini, N., Calandra, M., Car, R., Cavazzoni, C., Ceresoli, D., Chiarotti, G. L., Cococcioni, M., Dabo, I., et al. (2009) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/21/39/395502 · Cited by 29,281
The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
Single-crystal structure validation with the program PLATON
Spek, A. L. (2003) · Journal of Applied Crystallography · doi:10.1107/s0021889802022112 · Cited by 14,084
Selective gas adsorption and separation in metal–organic frameworks
Li, J.-R., Kuppler, R. J., & Zhou, H.-C. (2009) · Chemical Society Reviews · doi:10.1039/b802426j · Cited by 8,932
The path towards sustainable energy
Chu, S., Cui, Y., & Liu, N. (2017) · Nature Materials · doi:10.1038/nmat4834 · Cited by 4,791
Seven chemical separations to change the world
Sholl, D. S., & Lively, R. P. (2016) · Nature · doi:10.1038/532435a · Cited by 4,769
Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
Nugent, P., Belmabkhout, Y., Burd, S. D., Cairns, A. J., Luebke, R., Forrest, K., Pham, T., Ma, S., Space, B., Wojtas, L., et al. (2013) · Nature · doi:10.1038/nature11893 · Cited by 2,387
Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
Bloch, E. D., Queen, W. L., Krishna, R., Zadrozny, J. M., Brown, C. M., & Long, J. R. (2012) · Science · doi:10.1126/science.1217544 · Cited by 1,928
Self-citationPore chemistry and size control in hybrid porous materials for acetylene capture from ethylene
Cui, X., Chen, K., Xing, H., Yang, Q., Krishna, R., Bao, Z., Wu, H., Zhou, W., Dong, X., Han, Y., et al. (2016) · Science · doi:10.1126/science.aaf2458 · Cited by 1,449
Self-citationMultifunctional porous hydrogen-bonded organic framework materials
Lin, R.-B., He, Y., Li, P., Wang, H., Zhou, W., & Chen, B. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00155c · Cited by 1,346
Self-citationMetal–Organic Frameworks for Separation
Zhao, X., Wang, Y., Li, D., Bu, X., & Feng, P. (2018) · Advanced Materials · doi:10.1002/adma.201705189 · Cited by 1,305
Adsorbents: fundamentals and applications
(2004) · Focus on Catalysts · doi:10.1016/s1351-4180(04)00383-6 · Cited by 1,256
A metal-organic framework–based splitter for separating propylene from propane
Cadiau, A., Adil, K., Bhatt, P. M., Belmabkhout, Y., & Eddaoudi, M. (2016) · Science · doi:10.1126/science.aaf6323 · Cited by 1,193
Adsorbents: Fundamentals and Applications
Yang, R. T. (2003) · doi:10.1002/047144409x · Cited by 1,182
Ethane/ethylene separation in a metal-organic framework with iron-peroxo sites
Li, L., Lin, R.-B., Krishna, R., Li, H., Xiang, S., Wu, H., Li, J., Zhou, W., & Chen, B. (2018) · Science · doi:10.1126/science.aat0586 · Cited by 1,149
Self-citationCommensurate Adsorption of Hydrocarbons and Alcohols in Microporous Metal Organic Frameworks
Wu, H., Gong, Q., Olson, D. H., & Li, J. (2012) · Chemical Reviews · doi:10.1021/cr200216x · Cited by 1,035
Self-citationGas Adsorption Sites in a Large-Pore Metal-Organic Framework
Rowsell, J. L. C., Spencer, E. C., Eckert, J., Howard, J. A. K., & Yaghi, O. M. (2005) · Science · doi:10.1126/science.1113247 · Cited by 895
He, Y., Xiang, S., & Chen, B. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2066016 · Cited by 812
Self-citationBarone, V., Casarin, M., Forrer, D., Pavone, M., Sambi, M., & Vittadini, A. (2009) · Journal of Computational Chemistry · doi:10.1002/jcc.21112 · Cited by 805
Molecular sieving of ethylene from ethane using a rigid metal–organic framework
Lin, R.-B., Li, L., Zhou, H.-L., Wu, H., He, C., Li, S., Krishna, R., Li, J., Zhou, W., & Chen, B. (2018) · Nature Materials · doi:10.1038/s41563-018-0206-2 · Cited by 761
Self-citationControlling guest conformation for efficient purification of butadiene
Liao, P.-Q., Huang, N.-Y., Zhang, W.-X., Zhang, J.-P., & Chen, X.-M. (2017) · Science · doi:10.1126/science.aam7232 · Cited by 751
Olefin/paraffin separation technology: a review
Eldridge, R. B. (1993) · Industrial & Engineering Chemistry Research · doi:10.1021/ie00022a002 · Cited by 746
Gücüyener, C., van den Bergh, J., Gascon, J., & Kapteijn, F. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1089765 · Cited by 737
Yang, S., Ramirez-Cuesta, A. J., Newby, R., Garcia-Sakai, V., Manuel, P., Callear, S. K., Campbell, S. I., Tang, C. C., & Schröder, M. (2015) · Nature Chemistry · doi:10.1038/nchem.2114 · Cited by 665
Metal–Organic Framework Materials for the Separation and Purification of Light Hydrocarbons
Cui, W., Hu, T., & Bu, X. (2020) · Advanced Materials · doi:10.1002/adma.201806445 · Cited by 661
Efficient purification of ethene by an ethane-trapping metal-organic framework
Liao, P.-Q., Zhang, W.-X., Zhang, J.-P., & Chen, X.-M. (2015) · Nature Communications · doi:10.1038/ncomms9697 · Cited by 660
Mastalerz, M., & Oppel, I. M. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201201174 · Cited by 540
Functional materials discovery using energy–structure–function maps
Pulido, A., Chen, L., Kaczorowski, T., Holden, D., Little, M. A., Chong, S. Y., Slater, B. J., McMahon, D. P., Bonillo, B., Stackhouse, C. J., et al. (2017) · Nature · doi:10.1038/nature21419 · Cited by 506
Robust Ultramicroporous Metal–Organic Frameworks with Benchmark Affinity for Acetylene
Peng, Y., Pham, T., Li, P., Wang, T., Chen, Y., Chen, K., Forrest, K. A., Space, B., Cheng, P., Zaworotko, M. J., et al. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201806732 · Cited by 490
Bae, Y., Lee, C. Y., Kim, K. C., Farha, O. K., Nickias, P., Hupp, J. T., Nguyen, S. T., & Snurr, R. Q. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201107534 · Cited by 461
Control of zeolite framework flexibility and pore topology for separation of ethane and ethylene
Bereciartua, P. J., Cantín, Á., Corma, A., Jordá, J. L., Palomino, M., Rey, F., Valencia, S., Corcoran, E. W., Kortunov, P., Ravikovitch, P. I., et al. (2017) · Science · doi:10.1126/science.aao0092 · Cited by 460
Li, B., Zhang, Y., Krishna, R., Yao, K., Han, Y., Wu, Z., Ma, D., Shi, Z., Pham, T., Space, B., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja502119z · Cited by 455
Self-citationBoosting Ethane/Ethylene Separation within Isoreticular Ultramicroporous Metal–Organic Frameworks
Lin, R.-B., Wu, H., Li, L., Tang, X.-L., Li, Z., Gao, J., Cui, H., Zhou, W., & Chen, B. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b07563 · Cited by 452
Self-citationA Robust Ethane-Trapping Metal–Organic Framework with a High Capacity for Ethylene Purification
Qazvini, O. T., Babarao, R., Shi, Z.-L., Zhang, Y.-B., & Telfer, S. G. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b00913 · Cited by 387
Luo, X.-Z., Jia, X.-J., Deng, J.-H., Zhong, J.-L., Liu, H.-J., Wang, K.-J., & Zhong, D.-C. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403002m · Cited by 381
Crude oil to chemicals: light olefins from crude oil
Corma, A., Corresa, E., Mathieu, Y., Sauvanaud, L., Al-Bogami, S., Al-Ghrami, M. S., & Bourane, A. (2017) · Catalysis Science & Technology · doi:10.1039/c6cy01886f · Cited by 365
Böhme, U., Barth, B., Paula, C., Kuhnt, A., Schwieger, W., Mundstock, A., Caro, J., & Hartmann, M. (2013) · Langmuir · doi:10.1021/la401471g · Cited by 362
Olefin/Paraffin Separations by Reactive Absorption: A Review
Safarik, D. J., & Eldridge, R. B. (1998) · Industrial & Engineering Chemistry Research · doi:10.1021/ie970897h · Cited by 352
Wang, H., Dong, X., Colombo, V., Wang, Q., Liu, Y., Liu, W., Wang, X., Huang, X., Proserpio, D. M., Sironi, A., et al. (2018) · Advanced Materials · doi:10.1002/adma.201805088 · Cited by 352
Zeng, H., Xie, X.-J., Xie, M., Huang, Y.-L., Luo, D., Wang, T., Zhao, Y., Lu, W., & Li, D. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b10923 · Cited by 334
Induced Fit of C2H2 in a Flexible MOF Through Cooperative Action of Open Metal Sites
Zeng, H., Xie, M., Huang, Y., Zhao, Y., Xie, X., Bai, J., Wan, M., Krishna, R., Lu, W., & Li, D. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201904160 · Cited by 306
Self-citationBao, Z., Xie, D., Chang, G., Wu, H., Li, L., Zhou, W., Wang, H., Zhang, Z., Xing, H., Yang, Q., et al. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b13706 · Cited by 274
Self-citationAn ethane-trapping MOF PCN-250 for highly selective adsorption of ethane over ethylene
Chen, Y., Qiao, Z., Wu, H., Lv, D., Shi, R., Xia, Q., Zhou, J., & Li, Z. (2018) · Chemical Engineering Science · doi:10.1016/j.ces.2017.09.032 · Cited by 242
Self-citationAbsolute Molecular Sieve Separation of Ethylene/Ethane Mixtures with Silver Zeolite A
Aguado, S., Bergeret, G., Daniel, C., & Farrusseng, D. (2012) · Journal of the American Chemical Society · doi:10.1021/ja305663k · Cited by 240
Olefin/paraffin separations by adsorption: π‐Complexation vs. kinetic separation
Rege, S. U., Padin, J., & Yang, R. T. (1998) · AIChE Journal · doi:10.1002/aic.690440405 · Cited by 225
Ethane Selective IRMOF-8 and Its Significance in Ethane–Ethylene Separation by Adsorption
Pires, J., Pinto, M. L., & Saini, V. K. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am502686g · Cited by 198
Recent Progress Towards Light Hydrocarbon Separations Using Metal–Organic Frameworks
Barnett, B. R., Gonzalez, M. I., & Long, J. R. (2019) · Trends in Chemistry · doi:10.1016/j.trechm.2019.02.012 · Cited by 180
Hisaki, I., Nakagawa, S., Tohnai, N., & Miyata, M. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201411438 · Cited by 160
Adsorptive Separation of Olefin/Paraffin Mixtures with ZIF-4
Hartmann, M., Böhme, U., Hovestadt, M., & Paula, C. (2015) · Langmuir · doi:10.1021/acs.langmuir.5b02907 · Cited by 146
Selective Adsorption of Ethane over Ethylene in PCN-245: Impacts of Interpenetrated Adsorbent
Lv, D., Shi, R., Chen, Y., Wu, Y., Wu, H., Xi, H., Xia, Q., & Li, Z. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b19414 · Cited by 145
Self-citationPires, J., Fernandes, J., Dedecker, K., Gomes, J. R. B., Pérez‐Sánchez, G., Nouar, F., Serre, C., & Pinto, M. L. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b07115 · Cited by 107
Efficient separation of C 2 hydrocarbons in a permanently porous hydrogen-bonded organic framework
Yoon, T.-U., Baek, S. B., Kim, D., Kim, E., Lee, W., Singh, B. K., Lah, M. S., Bae, Y., & Kim, K. S. (2018) · Chemical Communications · doi:10.1039/c8cc04139c · Cited by 95
Understanding Gas Adsorption Selectivity in IRMOF-8 Using Molecular Simulation
Pillai, R. S., Pinto, M. L., Pires, J., Jorge, M., & Gomes, J. R. B. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am506793b · Cited by 90
Ribeiro, R. P. P. L., Camacho, B. C. R., Lyubchyk, A., Esteves, I. A. A. C., Cruz, F. J. A. L., & Mota, J. P. B. (2016) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2016.05.006 · Cited by 61
Effect of Light Gases in the Ethane/Ethylene Separation Using Zeolitic Imidazolate Frameworks
Lahoz-Martín, F. D., Martín-Calvo, A., Gutiérrez‐Sevillano, J. J., & Calero, S. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b01305 · Cited by 11
Cited by
Hydrogen-Bonded Organic Frameworks as a Tunable Platform for Functional Materials
Wang, B., Lin, R.-B., Zhang, Z., Xiang, S., & Chen, B. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c06473 · Cited by 852
Self-citationEthylene/ethane separation in a stable hydrogen-bonded organic framework through a gating mechanism
Yang, Y., Li, L., Lin, R.-B., Ye, Y., Yao, Z., Yang, L., Xiang, F., Chen, S., Zhang, Z., Xiang, S., et al. (2021) · Nature Chemistry · doi:10.1038/s41557-021-00740-z · Cited by 489
Self-citationHydrogen-bonded organic frameworks: Chemistry and functions
Lin, R.-B., & Chen, B. (2022) · Chem · doi:10.1016/j.chempr.2022.06.015 · Cited by 485
Self-citationHydrogen-Bonded Organic Frameworks: A Rising Class of Porous Molecular Materials
Li, P., Ryder, M. R., & Stoddart, J. F. (2020) · Accounts of Materials Research · doi:10.1021/accountsmr.0c00019 · Cited by 455
Separation and Purification of Hydrocarbons with Porous Materials
Wu, Y., & Weckhuysen, B. M. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202104318 · Cited by 284
Metadata
- Authors
- Zhang, X., Li, L., Wang, J.-X., Wen, H.-M., Krishna, R., Wu, H., Zhou, W., Chen, Z.-N., Li, B., Qian, G., & Chen, B.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-12-14
- Volume
- 142
- Issue
- 1
- Pages
- 633-640
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2995856058
- Cited by
- 331
- References
- 55
- FWCI
- 10.59
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
