The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Integration of Enzymes and Photosensitizers in a Hierarchical Mesoporous Metal–Organic Framework for Light-Driven CO2 Reduction
Open accessAbstract
Protection of enzymes with synthetic materials is a viable strategy to stabilize, and hence to retain, the reactivity of these highly active biomolecules in non-native environments. Active synthetic supports, coupled to encapsulated enzymes, can enable efficient cascade reactions which are necessary for processes like light-driven CO 2 reduction, providing a promising pathway for alternative energy generation. Herein, a semi-artificial system—containing an immobilized enzyme, formate dehydrogenase, in a light harvesting scaffold—is reported for the conversion of CO 2 to formic acid using white light. The electron-mediator Cp*Rh(2,2′-bipyridyl-5,5′-dicarboxylic acid)Cl was anchored to the nodes of the metal–organic framework NU-1006 to facilitate ultrafast photo-induced electron transfer when irradiated, leading to the reduction of the coenzyme nicotinamide adenine dinucleotide at a rate of about 28 mM·h –1 . Most importantly, the immobilized enzyme utilizes the reduced coenzyme to generate formic acid selectively from CO 2 at a high turnover frequency of about 865 h –1 in 24 h. The outcome of this research is the demonstration of a feasible pathway for solar-driven carbon fixation.
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Cites
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Self-citationHighly controlled acetylene accommodation in a metal–organic microporous material
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Cited by
Bioinspired Framework Catalysts: From Enzyme Immobilization to Biomimetic Catalysis
Wang, K.-Y., Zhang, J., Hsu, Y.-C., Lin, H., Han, Z., Pang, J., Yang, Z., Liang, R.-R., Shi, W., & Zhou, H.-C. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00879 · Cited by 490
Younas, M., Rezakazemi, M., Daud, M., Wazir, M. B., Ahmad, S., Ullah, N., Inamuddin, & Ramakrishna, S. (2020) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2020.100849 · Cited by 421
MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
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Self-citationOpportunities and Challenges of Metal–Organic Framework Micro/Nano Reactors for Cascade Reactions
Wu, P., Zhao, Y., Zhang, X., Fan, Y., Zhang, S., Zhang, W., & Huo, F. (2023) · JACS Au · doi:10.1021/jacsau.3c00344 · Cited by 48
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Metadata
- Authors
- Chen, Y., Li, P., Zhou, J., Buru, C. T., Đorđević, L., Li, P., Zhang, X., Cetin, M. M., Stoddart, J. F., Stupp, S. I., Wasielewski, M. R., & Farha, O. K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-01-13
- Volume
- 142
- Issue
- 4
- Pages
- 1768-1773
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2999527125
- Cited by
- 304
- References
- 34
- FWCI
- 10.86
- Type
- journal article
- Language
- en
- Open access
- green
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- Chen, Y., Li, P., Zhou, J., Buru, C. T., Đorđević, L., Li, P., Zhang, X., Cetin, M. M., Stoddart, J. F., Stupp, S. I., Wasielewski, M. R., & Farha, O. K. (2020). Integration of Enzymes and Photosensitizers in a Hierarchical Mesoporous Metal–Organic Framework for Light-Driven CO2 Reduction. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b12828
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