The DOI matches its Crossref record; 50 of the 50 references it cites were found in a registry or an index.
Pore-Space-Partition-Enabled Exceptional Ethane Uptake and Ethane-Selective Ethane–Ethylene Separation
Open accessAbstract
An ideal material for C 2 H 6 /C 2 H 4 separation would simultaneously have the highest C 2 H 6 uptake capacity and the highest C 2 H 6 /C 2 H 4 selectivity. But such material is elusive. A benchmark material for ethane-selective C 2 H 6 /C 2 H 4 separation is peroxo-functionalized MOF-74-Fe that exhibits the best known separation performance due to its high C 2 H 6 /C 2 H 4 selectivity (4.4), although its C 2 H 6 uptake capacity is moderate (74.3 cm 3 /g). Here, we report a family of pore-space-partitioned crystalline porous materials (CPMs) with exceptional C 2 H 6 uptake capacity and C 2 H 6 /C 2 H 4 separation potential (i.e., C 2 H 4 recovered from the mixture) despite their moderate C 2 H 6 /C 2 H 4 selectivity (up to 1.75). The ethane uptake capacity as high as 166.8 cm 3 /g at 1 atm and 298 K, more than twice that of peroxo-MOF-74-Fe, has been achieved even though the isosteric heat of adsorption (21.9–30.4 kJ/mol) for these CPMs is as low as about one-third of that for peroxo-MOF-74-Fe (66.8 kJ/mol). While the overall C 2 H 6 /C 2 H 4 separation potentials have not yet surpassed peroxo-MOF-74-Fe, these robust CPMs exhibit outstanding properties including high thermal stability (up to 450 °C) and aqueous stability, low regeneration energy, and a high degree of chemical and geometrical tunability within the same isoreticular framework.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Seven chemical separations to change the world
Sholl, D. S., & Lively, R. P. (2016) · Nature · doi:10.1038/532435a · Cited by 4,769
Stable Metal–Organic Frameworks: Design, Synthesis, and Applications
Yuan, S., Feng, L., Wang, K., Pang, J., Bosch, M., Lollar, C., Sun, Y., Qin, J., Yang, X., Zhang, P., et al. (2018) · Advanced Materials · doi:10.1002/adma.201704303 · Cited by 2,981
Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
Nugent, P., Belmabkhout, Y., Burd, S. D., Cairns, A. J., Luebke, R., Forrest, K., Pham, T., Ma, S., Space, B., Wojtas, L., et al. (2013) · Nature · doi:10.1038/nature11893 · Cited by 2,387
Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
Bloch, E. D., Queen, W. L., Krishna, R., Zadrozny, J. M., Brown, C. M., & Long, J. R. (2012) · Science · doi:10.1126/science.1217544 · Cited by 1,928
Self-citationMetal–Organic Frameworks as Platforms for Functional Materials
Cui, Y., Li, B., He, H., Zhou, W., Chen, B., & Qian, G. (2016) · Accounts of Chemical Research · doi:10.1021/acs.accounts.5b00530 · Cited by 1,699
The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion
Trickett, C. A., Helal, A., Al-Maythalony, B. A., Yamani, Z. H., Cordova, K. E., & Yaghi, O. M. (2017) · Nature Reviews Materials · doi:10.1038/natrevmats.2017.45 · Cited by 1,524
Highly controlled acetylene accommodation in a metal–organic microporous material
Matsuda, R., Kitaura, R., Kitagawa, S., Kubota, Y., Belosludov, R. V., Kobayashi, T. C., Sakamoto, H., Chiba, T., Takata, M., Kawazoe, Y., et al. (2005) · Nature · doi:10.1038/nature03852 · Cited by 1,520
Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene
Cui, X., Chen, K., Xing, H., Yang, Q., Krishna, R., Bao, Z., Wu, H., Zhou, W., Dong, X., Han, Y., et al. (2016) · Science · doi:10.1126/science.aaf2458 · Cited by 1,449
Self-citationMetal–organic frameworks: Structures and functional applications
Jiao, L., Seow, J. Y. R., Skinner, W. S., Wang, Z. U., & Jiang, H.-L. (2019) · Materials Today · doi:10.1016/j.mattod.2018.10.038 · Cited by 1,404
Adil, K., Belmabkhout, Y., Pillai, R. S., Cadiau, A., Bhatt, P. M., Assen, A. H., Maurin, G., & Eddaoudi, M. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00153c · Cited by 1,324
Metal–Organic Frameworks for Separation
Zhao, X., Wang, Y., Li, D., Bu, X., & Feng, P. (2018) · Advanced Materials · doi:10.1002/adma.201705189 · Cited by 1,305
Self-citationREN, T., PATEL, M., & BLOK, K. (2006) · Energy · doi:10.1016/j.energy.2005.04.001 · Cited by 1,193
A metal-organic framework–based splitter for separating propylene from propane
Cadiau, A., Adil, K., Bhatt, P. M., Belmabkhout, Y., & Eddaoudi, M. (2016) · Science · doi:10.1126/science.aaf6323 · Cited by 1,193
Ethane/ethylene separation in a metal-organic framework with iron-peroxo sites
Li, L., Lin, R.-B., Krishna, R., Li, H., Xiang, S., Wu, H., Li, J., Zhou, W., & Chen, B. (2018) · Science · doi:10.1126/science.aat0586 · Cited by 1,149
Self-citationRole of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks
Serre, C., Mellot-Draznieks, C., Surblé, S., Audebrand, N., Filinchuk, Y., & Férey, G. (2007) · Science · doi:10.1126/science.1137975 · Cited by 1,095
Molecular sieving of ethylene from ethane using a rigid metal–organic framework
Lin, R.-B., Li, L., Zhou, H.-L., Wu, H., He, C., Li, S., Krishna, R., Li, J., Zhou, W., & Chen, B. (2018) · Nature Materials · doi:10.1038/s41563-018-0206-2 · Cited by 761
Self-citationGücüyener, C., van den Bergh, J., Gascon, J., & Kapteijn, F. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1089765 · Cited by 737
Exploration of porous metal–organic frameworks for gas separation and purification
Lin, R.-B., Xiang, S., Xing, H., Zhou, W., & Chen, B. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.09.027 · Cited by 726
He, Y., Krishna, R., & Chen, B. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22858k · Cited by 674
Self-citationYang, S., Ramirez-Cuesta, A. J., Newby, R., Garcia-Sakai, V., Manuel, P., Callear, S. K., Campbell, S. I., Tang, C. C., & Schröder, M. (2015) · Nature Chemistry · doi:10.1038/nchem.2114 · Cited by 665
Efficient purification of ethene by an ethane-trapping metal-organic framework
Liao, P.-Q., Zhang, W.-X., Zhang, J.-P., & Chen, X.-M. (2015) · Nature Communications · doi:10.1038/ncomms9697 · Cited by 660
Synergistic sorbent separation for one-step ethylene purification from a four-component mixture
Chen, K.-J., Madden, D. G., Mukherjee, S., Pham, T., Forrest, K. A., Kumar, A., Space, B., Kong, J., Zhang, Q.-Y., & Zaworotko, M. J. (2019) · Science · doi:10.1126/science.aax8666 · Cited by 636
Pore Space Partition in Metal–Organic Frameworks
Zhai, Q.-G., Bu, X., Zhao, X., Li, D.-S., & Feng, P. (2017) · Accounts of Chemical Research · doi:10.1021/acs.accounts.6b00526 · Cited by 571
Self-citationBloch, E. D., Murray, L. J., Queen, W. L., Chavan, S., Maximoff, S. N., Bigi, J. P., Krishna, R., Peterson, V. K., Grandjean, F., Long, G. J., et al. (2011) · Journal of the American Chemical Society · doi:10.1021/ja205976v · Cited by 531
Self-citationHorcajada, P., Salles, F., Wuttke, S., Devic, T., Heurtaux, D., Maurin, G., Vimont, A., Daturi, M., David, O., Magnier, E., et al. (2011) · Journal of the American Chemical Society · doi:10.1021/ja206936e · Cited by 504
Li, B., Zhang, Y., Krishna, R., Yao, K., Han, Y., Wu, Z., Ma, D., Shi, Z., Pham, T., Space, B., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja502119z · Cited by 455
Self-citationBoosting Ethane/Ethylene Separation within Isoreticular Ultramicroporous Metal–Organic Frameworks
Lin, R.-B., Wu, H., Li, L., Tang, X.-L., Li, Z., Gao, J., Cui, H., Zhou, W., & Chen, B. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b07563 · Cited by 452
Grand Challenges and Future Opportunities for Metal–Organic Frameworks
Hendon, C. H., Rieth, A. J., Korzyński, M. D., & Dincă, M. (2017) · ACS Central Science · doi:10.1021/acscentsci.7b00197 · Cited by 434
A Robust Ethane-Trapping Metal–Organic Framework with a High Capacity for Ethylene Purification
Qazvini, O. T., Babarao, R., Shi, Z.-L., Zhang, Y.-B., & Telfer, S. G. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b00913 · Cited by 387
Zheng, S.-T., Bu, J. T., Li, Y., Wu, T., Zuo, F., Feng, P., & Bu, X. (2010) · Journal of the American Chemical Society · doi:10.1021/ja106903p · Cited by 373
Self-citationZhao, X., Bu, X., Zhai, Q.-G., Tran, H., & Feng, P. (2015) · Journal of the American Chemical Society · doi:10.1021/ja512137t · Cited by 355
Self-citationWang, H., Dong, X., Colombo, V., Wang, Q., Liu, Y., Liu, W., Wang, X., Huang, X., Proserpio, D. M., Sironi, A., et al. (2018) · Advanced Materials · doi:10.1002/adma.201805088 · Cited by 352
Titanium-based metal–organic frameworks for photocatalytic applications
Zhu, J., Li, P.-Z., Guo, W., Zhao, Y., & Zou, R. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.12.013 · Cited by 347
Bimetallic Metal–Organic Frameworks for Gas Storage and Separation
Yang, X., & Xü, Q. (2017) · Crystal Growth & Design · doi:10.1021/acs.cgd.7b00166 · Cited by 330
Titanium coordination compounds: from discrete metal complexes to metal–organic frameworks
Assi, H., Mouchaham, G., Steunou, N., Devic, T., & Serre, C. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00001d · Cited by 310
Nguyen, N. T. T., Furukawa, H., Gándara, F., Nguyen, H. T., Cordova, K. E., & Yaghi, O. M. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201403980 · Cited by 280
An ethane-trapping MOF PCN-250 for highly selective adsorption of ethane over ethylene
Chen, Y., Qiao, Z., Wu, H., Lv, D., Shi, R., Xia, Q., Zhou, J., & Li, Z. (2018) · Chemical Engineering Science · doi:10.1016/j.ces.2017.09.032 · Cited by 242
Molecular sieves for gas separation
Lin, Y. S. (2016) · Science · doi:10.1126/science.aag2267 · Cited by 238
A phase transformable ultrastable titanium-carboxylate framework for photoconduction
Wang, S., Kitao, T., Guillou, N., Wahiduzzaman, M., Martineau-Corcos, C., Nouar, F., Tissot, A., Binet, L., Ramsahye, N., Devautour-Vinot, S., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-04034-w · Cited by 208
Ethane Selective IRMOF-8 and Its Significance in Ethane–Ethylene Separation by Adsorption
Pires, J., Pinto, M. L., & Saini, V. K. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am502686g · Cited by 198
Krishna, R. (2017) · RSC Advances · doi:10.1039/c7ra07363a · Cited by 186
Self-citationLiang, W., Xu, F., Zhou, X., Xiao, J., Xia, Q., Li, Y., & Li, Z. (2016) · Chemical Engineering Science · doi:10.1016/j.ces.2016.04.016 · Cited by 169
Pore environment engineering in metal–organic frameworks for efficient ethane/ethylene separation
Wang, X., Niu, Z., Al‐Enizi, A. M., Nafady, A., Wu, Y., Aguila, B., Verma, G., Wojtas, Ł., Chen, Y., Li, Z., et al. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta02822f · Cited by 130
Krishna, R. (2017) · Separation and Purification Technology · doi:10.1016/j.seppur.2017.11.056 · Cited by 124
Self-citationHighly Adsorptive Separation of Ethane/Ethylene by An Ethane-Selective MOF MIL-142A
Chen, Y., Wu, H., Lv, D., Shi, R., Yang, C., Xia, Q., & Li, Z. (2018) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.7b05260 · Cited by 110
Pires, J., Fernandes, J., Dedecker, K., Gomes, J. R. B., Pérez‐Sánchez, G., Nouar, F., Serre, C., & Pinto, M. L. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b07115 · Cited by 107
Hao, H., Zhao, Y., Chen, D., Yu, J., Tan, K., Ma, S., Chabal, Y. J., Zhang, Z., Dou, J., Xiao, Z., et al. (2018) · Angewandte Chemie · doi:10.1002/ange.201809884 · Cited by 85
Hydrogen adsorption in the metal–organic frameworks Fe2(dobdc) and Fe2(O2)(dobdc)
Queen, W. L., Bloch, E. D., Brown, C. M., Hudson, M. R., Mason, J. A., Murray, L. J., Ramirez-Cuesta, A. J., Peterson, V. K., & Long, J. R. (2012) · Dalton Transactions · doi:10.1039/c2dt12138g · Cited by 83
Cited by
Yang, L., Qian, S., Wang, X., Cui, X., Chen, B., & Xing, H. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00756c · Cited by 746
Isoreticular chemistry within metal–organic frameworks for gas storage and separation
Fan, W., Zhang, X., Kang, Z., Liu, X., & Sun, D. (2021) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2021.213968 · Cited by 584
Ethylene/ethane separation in a stable hydrogen-bonded organic framework through a gating mechanism
Yang, Y., Li, L., Lin, R.-B., Ye, Y., Yao, Z., Yang, L., Xiang, F., Chen, S., Zhang, Z., Xiang, S., et al. (2021) · Nature Chemistry · doi:10.1038/s41557-021-00740-z · Cited by 489
Separation and Purification of Hydrocarbons with Porous Materials
Wu, Y., & Weckhuysen, B. M. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202104318 · Cited by 284
Jin, F., Lin, E., Wang, T., Geng, S., Wang, T., Liu, W., Xiong, F., Wang, Z., Chen, Y., Cheng, P., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c01058 · Cited by 281
Metadata
- Authors
- Yang, H., Wang, Y., Krishna, R., Jia, X., Wang, Y., Hong, A. N., Dang, C., Castillo, H. E., Bu, X., & Feng, P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-01-27
- Volume
- 142
- Issue
- 5
- Pages
- 2222-2227
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W3004356871
- Cited by
- 328
- References
- 50
- FWCI
- 28.76
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
