Ambient Temperature Vapor Pressure and Adsorption Capacity for (Perfluorooctyl) Ethylene, 3-(Perfluorobutyl)Propanol, Perfluorohexanoic Acid, Ethyl Perfluorooctanoate, and Perfluoro-3,6-Dioxaheptanoic Acid

Schindler, Bryan J.; Buchanan, James H.; Mahle, John J.; Peterson, Gregory W.; Glover, T. Grant

doi:10.1021/je400205g

Cited by 9Per- and polyfluoroalkyl substances researchPhase Equilibria and ThermodynamicsChemical Thermodynamics and Molecular Structure

Ambient Temperature Vapor Pressure and Adsorption Capacity for (Perfluorooctyl) Ethylene, 3-(Perfluorobutyl)Propanol, Perfluorohexanoic Acid, Ethyl Perfluorooctanoate, and Perfluoro-3,6-Dioxaheptanoic Acid

Schindler, Bryan J., Buchanan, James H., Mahle, John J., Peterson, Gregory W., Glover, T. Grant·2013·Journal of Chemical & Engineering Data

DOI 10.1021/je400205g

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Abstract

With increased use of highly fluorinated compounds has come an increased need for knowledge of the fundamental properties of these chemicals, such as vapor pressure, to determine how they will behave in the environment and how to remove them. A modified vapor saturation method was used to measure the ambient temperature vapor pressure of 3-(perfluorobutyl)propanol, (perfluorooctyl)ethylene, perfluorohexanoic acid, ethyl perfluorooctanoate, and perfluoro-3,6-dioxaheptanoic acid between (254.15 and 309.15) K. The freezing point for perfluorohexanoic acid was determined to be between (291.15 and 293.15) K. The vapor pressures, which ranged from (0.87 to 978) Pa, were used to generate saturated vapor streams of the compound so that adsorption capacities on BPL activated carbon could be determined. Adsorption equilibrium data for three of the chemicals, measured at a feed concentration of 139 μL·L –1 at high and low relative humidity, are presented and discussed.

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Highly volatile compounds have a greater potential for long-range transport, whereas chemicals with low vapor pressures are more likely to remain in solid and liquid forms and are generally transported through soil, surface and groundwater with reduced transport potential.
“Highly volatile compounds have a greater potential for long-range transport because they are easily converted to the gas phase and can travel long distances in the atmosphere, whereas chemicals with low vapor pressures are more likely to remain in the solid and liquid forms and are generally transported through the soil, surface and groundwater, with reduced transport potential [22].”
From The EU’s Per- and Polyfluoroalkyl Substances (PFAS) Ban: A Case of Policy over Science (2023) · cites this paper as [22]

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Authors: Schindler, B. J., Buchanan, J. H., Mahle, J. J., Peterson, G. W., & Glover, T. G.
Affiliations: Science Applications International Corporation (United States) (US)
U.S. Army Combat Capabilities Development Command Chemical Biological Center (US)
Corresponding author: Schindler, Bryan J.
ORCID: Schindler, Bryan J.
Peterson, Gregory W.
Glover, T. Grant
Venue: Journal of Chemical & Engineering Data
Publisher: American Chemical Society (ACS)
Published: 2013-05-24
Volume: 58
Issue: 6
Pages: 1806-1812
ISSN: 0021-9568 (ISSN-L)
1520-5134
DOI: 10.1021/je400205g
OpenAlex: W2329761554
Cited by: 9
References: 40
Citations by year: 2024: 1 · 2023: 1 · 2022: 2 · 2021: 1 · 2020: 1 · 2017: 2 · 2016: 1
FWCI: 0.26
Type: journal article
Language: en
Open access: closed
Locations: Journal of Chemical & Engineering Data (publishedVersion)
Topics: Physical Sciences › Environmental Science › Environmental Chemistry › Per- and polyfluoroalkyl substances research
Physical Sciences › Engineering › Biomedical Engineering › Phase Equilibria and Thermodynamics
Physical Sciences › Chemistry › Organic Chemistry › Chemical Thermodynamics and Molecular Structure
Keywords: perfluorinated compounds, vapor pressure, adsorption capacity, activated carbon, perfluorohexanoic acid, freezing point, relative humidity, adsorption equilibrium

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Ambient Temperature Vapor Pressure and Adsorption Capacity for (Perfluorooctyl) Ethylene, 3-(Perfluorobutyl)Propanol, Perfluorohexanoic Acid, Ethyl Perfluorooctanoate, and Perfluoro-3,6-Dioxaheptanoic Acid

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