Effects of crystallization temperature of poly (vinylidene fluoride) on crystal modification and phase transition of poly (butylene adipate) in their blends: A novel approach for polymorphic control
Abstract
Effects of the isothermal crystallization temperatures of poly(vinylidene fluoride), T(IC,PVDF), on polymorphic crystalline structure, phase transition, fractional crystallization, and enzymatic degradation of poly(butylene adipate) (PBA) in crystalline/crystalline blends have been investigated. The crystal modifications of PBA can be regulated by T(IC,PVDF). Lower T(IC,PVDF) (e.g., 80 °C) facilitates the formation of PBA α crystals in both the isothermal and nonisothermal melt crystallizations and also favors the β-to-α phase transition of PBA upon annealing at elevated temperatures. This might be attributable to the decreased equilibrium melting temperature of PBA when T(IC,PVDF) is decreased. Higher T(IC,PVDF) is favorable for the fractional crystallization of PBA, which tends to segregate in the interlamellar regions of the PVDF matrix under these conditions. PBA shows faster enzymatic degradation in the blends with a lower T(IC,PVDF) than those with a higher T(IC,PVDF), attributable to the preferential formation of α crystals at a lower T(IC,PVDF). This study provides a new method to control the crystal modification and physical properties of polymorphic polymers in their blend systems.
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There are few binary miscible blends showing fractionated crystallization, such as PEO/PBS, PBA/PVDF, PBA/PBS, PEO/PHB, and PEO/PES.
“Compared to immiscible blends, there are just few binary miscible blends showing fractionated crystallization, such as PEO/poly(butylene succinate) (PBS) [69][70][71][72][73] , poly(butylene adipate) (PBA)/poly(vinylidene fluoride) (PVDF) [ 74 , 75 ], PBA/PBS [76] , PEO/poly(3-hydroxybutyrate) (PHB) [77][78][79][80] , PEO/ Poly(ethylene suberate) (PES) [81] .”
From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [74]
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- Authors
- Yang, J., Pan, P., Hua, L., Feng, X., Yue, J., Ge, Y., & Inoue, Y.
- Affiliations
- Tokyo Institute of Technology (JP)
- School of Environmental Science and Safety Engineering, Tianjin University of Technology, Tianjin 300384, China
- Tianjin University of Technology (CN)
- Corresponding author
- Yang, Jinjun
- Pan, Pengju
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-01-24
- Volume
- 116
- Issue
- 4
- Pages
- 1265-1272
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2319784405
- Cited by
- 56
- References
- 40
- Citations by year
- 2026: 2 · 2025: 2 · 2024: 2 · 2023: 3 · 2022: 3 · 2021: 5 · 2020: 6 · 2019: 2 · 2018: 3 · 2017: 7 · 2016: 3 · 2015: 6 · 2014: 6 · 2013: 2 · 2012: 4
- FWCI
- 4.52
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- The Journal of Physical Chemistry B (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Keywords
- polyvinylidene fluoride, poly(butylene adipate), polymer blends, polymorphism control, alpha crystal, beta to alpha phase transition, fractional crystallization, enzymatic degradation, melting point
- MeSH terms
- Butylene Glycols, Crystallization, Fluorocarbon Polymers, Lipase, Polymers, Polyvinyls, Pseudomonas, Temperature, X-Ray Diffraction, Phase Transition, Scattering, Small Angle
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