Polymorphic crystallization and phase transition of poly (butylene adipate) in its miscible crystalline/crystalline blend with poly (vinylidene fluoride)
Abstract
The effects of poly(vinylidene fluoride) (PVDF) component on the crystallization kinetics, crystalline structure, phase transition, and morphology of polymorphic poly(butylene adipate) (PBA) in their miscible PVDF/PBA binary blends have been investigated. The polymorphism of PBA can be regulated upon blending with PVDF. The incorporated PVDF faciliates the formation of PBA α-crystal, which is probably attributed to the thermodynamic and kinetic contributions. From the crystallization kinetics, it was found that a small amount of PVDF acts as a nucleating agent and can accelerate the crystallization of PBA, while a large amount of PVDF hinders the crystallization of PBA due to the confinement effect. In addition, the addition of PVDF greatly accelerates the β- to α-form phase transition of PBA upon annealing the PBA β-form at higher tmeperataure (48 °C). However, the large amount of PVDF decelerates the phase transition to a certain extent. The possible reasons for these phenomena were also proposed.
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There are few binary miscible blends showing fractionated crystallization, such as PEO/PBS, PBA/PVDF, PBA/PBS, PEO/PHB, and PEO/PES.
“Compared to immiscible blends, there are just few binary miscible blends showing fractionated crystallization, such as PEO/poly(butylene succinate) (PBS) [69][70][71][72][73] , poly(butylene adipate) (PBA)/poly(vinylidene fluoride) (PVDF) [ 74 , 75 ], PBA/PBS [76] , PEO/poly(3-hydroxybutyrate) (PHB) [77][78][79][80] , PEO/ Poly(ethylene suberate) (PES) [81] .”
From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [75]
Cites
Melting process and the equilibrium melting temperature of polychlorotrifluoroethylene
Hoffman, J., & Weeks, J. J. (1962) · Journal of Research of the National Bureau of Standards Section A Physics and Chemistry · doi:10.6028/jres.066a.003 · Cited by 1,494 · see citing works
Crystal Structures of Three Crystalline Forms of Poly(vinylidene fluoride)
Hasegawa, R., Takahashi, Y., Chatani, Y., & Tadokoro, H. (1972) · Polymer Journal · doi:10.1295/polymj.3.600 · Cited by 940 · see citing works
Polymorphism and isomorphism in biodegradable polyesters
Pan, P., & Inoue, Y. (2009) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2009.01.003 · Cited by 611 · see citing works
Self-citationThe role of metastability in polymer phase transitions
Keller, A., & Cheng, S. Z. D. (1998) · Polymer · doi:10.1016/s0032-3861(97)10320-2 · Cited by 316 · see citing works
Ren, J., Fu, H., Ren, T., & Yuan, W. (2009) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2009.01.024 · Cited by 280 · see citing works
The morphology and thermal response of high-temperature–crystallized poly(vinylidene fluoride)
Prest, W. M., & Luca, D. J. (1975) · Journal of Applied Physics · doi:10.1063/1.321438 · Cited by 230 · see citing works
Nanocomposites of poly(vinylidene fluoride) with organically modified silicate
Buckley, J., Cebe, P., Cherdack, D., Crawford, J., Ince, B. S., Jenkins, M., Pan, J., Reveley, M., Washington, N., & Wolchover, N. (2006) · Polymer · doi:10.1016/j.polymer.2006.02.012 · Cited by 221 · see citing works
Pan, P., Liang, Z., 曹阿民, & Inoue, Y. (2009) · ACS Applied Materials & Interfaces · doi:10.1021/am800106f · Cited by 204 · see citing works
Self-citationCrystallization and morphology of melt‐solidified poly(vinylidene fluoride)
Lovinger, A. J. (1980) · Journal of Polymer Science Polymer Physics Edition · doi:10.1002/pol.1980.180180412 · Cited by 176 · see citing works
Lu, J., Qiu, Z., & Yang, W. (2007) · Polymer · doi:10.1016/j.polymer.2007.05.035 · Cited by 170 · see citing works
Metastability and Transformation of Polymorphic Crystals in Biodegradable Poly(butylene adipate)
Gan, Z., Kuwabara, K., Abe, H., Iwata, T., & Doi, Y. (2004) · Biomacromolecules · doi:10.1021/bm0343850 · Cited by 169 · see citing works
Penning, J. P., & Manley, R. S. J. (1996) · Macromolecules · doi:10.1021/ma950651t · Cited by 158 · see citing works
Blending Effects on Polymorphic Crystallization of Poly( l -lactide)
Pan, P., Liang, Z., Zhu, B., Dong, T., & Inoue, Y. (2009) · Macromolecules · doi:10.1021/ma8024943 · Cited by 154 · see citing works
Self-citationTemperature‐Induced Polymorphic Crystals of Poly(butylene adipate)
Gan, Z., Abe, H., & Doi, Y. (2002) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200290007 · Cited by 141 · see citing works
Penning, J. P., & Manley, R. S. J. (1996) · Macromolecules · doi:10.1021/ma950652l · Cited by 132 · see citing works
Polymorphic structures of poly(tetramethylene adipate)
Minke, R., & Blackwell, J. (1979) · Journal of Macromolecular Science Part B · doi:10.1080/00222347908212305 · Cited by 122 · see citing works
Gan, Z., Kuwabara, K., Abe, H., Iwata, T., & Doi, Y. (2004) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2004.08.007 · Cited by 116 · see citing works
Single crystals of poly(tetramethylene adipate)
Minke, R., & Blackwell, J. (1980) · Journal of Macromolecular Science Part B · doi:10.1080/00222348008241380 · Cited by 103 · see citing works
Liu, L., Chu, B., Penning, J. P., et al. (1997) · Macromolecules · doi:10.1021/ma961719n · Cited by 102 · see citing works
Electron Diffraction Investigation of a High-Temperature Form of Poly(vinylidene fluoride)
Lovinger, A. J., & Keith, H. D. (1979) · Macromolecules · doi:10.1021/ma60071a026 · Cited by 102 · see citing works
Pan, P., Liang, Z., Nakamura, N., Miyagawa, T., & Inoue, Y. (2009) · Macromolecular Bioscience · doi:10.1002/mabi.200800294 · Cited by 85 · see citing works
Self-citationWang, H., Gan, Z., Schultz, J. M., & Yan, S. (2008) · Polymer · doi:10.1016/j.polymer.2008.02.050 · Cited by 84 · see citing works
Yuan, H., Liu, Z., & Ren, J. (2009) · Polymer Engineering and Science · doi:10.1002/pen.21287 · Cited by 84 · see citing works
Epitaxial Crystallization of Poly(butylene adipate) on Highly Oriented Polyethylene Thin Film
Sun, Y., Li, H., Huang, Y. H., Chen, E., Zhao, L., Gan, Z., & Yan, S. (2005) · Macromolecules · doi:10.1021/ma0474269 · Cited by 77 · see citing works
He, Y., Zhu, B., Kai, W., & Inoue, Y. (2004) · Macromolecules · doi:10.1021/ma049482f · Cited by 67 · see citing works
Self-citationSun, Y., Li, H., Huang, Y. H., Chen, E., Gan, Z., & Yan, S. (2006) · Polymer · doi:10.1016/j.polymer.2006.02.002 · Cited by 67 · see citing works
Dong, T., He, Y. Q., Shin, K., et al. (2004) · Macromolecular Bioscience · doi:10.1002/mabi.200400054 · Cited by 61 · see citing works
Self-citationSelf-nucleation and enhanced nucleation of polyvinylidene fluoride (α-phase)
Schneider, S., Drujon, X., Lotz, B., & Wittmann, J. C. (2001) · Polymer · doi:10.1016/s0032-3861(01)00361-5 · Cited by 59 · see citing works
Woo, E. M., Wu, P. L., Wu, M. C., & Yan, K. C. (2006) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200600379 · Cited by 56 · see citing works
Crystallization kinetics and crystalline structure of biodegradable Poly(ethylene adipate)
Yang, J., Pan, P., Dong, T., & Inoue, Y. (2009) · Polymer · doi:10.1016/j.polymer.2009.11.065 · Cited by 54 · see citing works
Self-citationJiang, N., Zhao, L., & Gan, Z. (2010) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2010.03.004 · Cited by 53 · see citing works
Crystallization of poly(butylene adipate) in the presence of nucleating agents
Kai, W., Zhu, B., He, Y. Q., & Inoue, Y. (2005) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/polb.20523 · Cited by 47 · see citing works
Self-citationEffects of α‐form or β‐form nuclei on polymorphic crystalline morphology of poly(butylene adipate)
Wu, M. C., & Woo, E. (2005) · Polymer International · doi:10.1002/pi.1922 · Cited by 46 · see citing works
Yang, J., Li, Z., Pan, P., Zhu, B., Dong, T., & Inoue, Y. (2009) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/polb.21798 · Cited by 41 · see citing works
Self-citationRegulation of Polymorphic Behavior of Poly(butylene adipate) upon Complexation with α-Cyclodextrin
Dong, T., Kai, W., & Inoue, Y. (2007) · Macromolecules · doi:10.1021/ma071776o · Cited by 35 · see citing works
Self-citationNoguchi, K., Kondo, H., Ichikawa, Y., Okuyama, K., & Washiyama, J. (2005) · Polymer · doi:10.1016/j.polymer.2005.09.010 · Cited by 35 · see citing works
Isayeva, I. S., Kyu, T., & Manley, R. S. J. (1998) · Polymer · doi:10.1016/s0032-3861(97)10138-0 · Cited by 26 · see citing works
Liu, L., Chu, B., Penning, J. P., et al. (2000) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/1099-0488(20000901)38:17 · Cited by 23 · see citing works
Physical properties of poly(ethylene adipate)/low-density polyethylene blends
Im, S., Kim, T. J., Han, S.-M., et al. (1997) · Journal of Applied Polymer Science · doi:10.1002/(sici)1097-4628(19970829)65:9 · Cited by 13 · see citing works
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Zheng, Y., & Pan, P. (2020) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2020.101291 · Cited by 229 · see citing works
Self-citationFractionated crystallization in semicrystalline polymers
Sangroniz, L., Wang, B., Su, Y., Liu, G., Cavallo, D., Wang, D., & Müller, A. J. (2021) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2021.101376 · Cited by 102 · see citing works
Yang, J., Pan, P., Hua, L., Xie, Y., Dong, T., Zhu, B., Inoue, Y., & Feng, X. (2011) · Polymer · doi:10.1016/j.polymer.2011.05.041 · Cited by 90 · see citing works
Self-citationYang, J., Pan, P., Hua, L., Feng, X., Yue, J., Ge, Y., & Inoue, Y. (2012) · The Journal of Physical Chemistry B · doi:10.1021/jp209626x · Cited by 56 · see citing works
Self-citationWeng, M., & Qiu, Z. (2014) · Macromolecules · doi:10.1021/ma502019x · Cited by 38 · see citing works
He, Z., Liang, Y., & Han, C. C. (2013) · Macromolecules · doi:10.1021/ma4015214 · Cited by 37 · see citing works
Pan, P., Zhao, L., Yang, J., & Inoue, Y. (2013) · Macromolecular Materials and Engineering · doi:10.1002/mame.201200006 · Cited by 30 · see citing works
Ye, H.-M., Song, Y.-Y., Meng, X., & Zhou, Q. (2016) · RSC Advances · doi:10.1039/c6ra09117b · Cited by 19 · see citing works
- Authors
- Yang, J., Pan, P., Hua, L., Zhu, B., Dong, T., & Inoue, Y.
- Affiliations
- Tokyo Institute of Technology (JP)
- Corresponding author
- Inoue, Yoshio
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-09-21
- Volume
- 43
- Issue
- 20
- Pages
- 8610-8618
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W1975837348
- Cited by
- 102
- References
- 39
- Citations by year
- 2026: 2 · 2025: 4 · 2024: 1 · 2023: 7 · 2022: 8 · 2021: 4 · 2020: 8 · 2019: 2 · 2018: 7 · 2017: 9 · 2016: 9 · 2015: 12 · 2014: 13 · 2013: 5 · 2012: 8
- FWCI
- 4.24
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecules (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Materials Chemistry › Crystallization and Solubility Studies
- Keywords
- poly(butylene adipate), polyvinylidene fluoride, miscible polymer blends, polymorphism, crystallization kinetics, nucleation, confinement effects, beta to alpha phase transition, annealing, crystal morphology, crystal structure
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