The DOI matches its Crossref record; 24 of the 24 references it cites were found in a registry or an index.
Chemical and Morphological Changes of Li–O2 Battery Electrodes upon Cycling
Abstract
We report considerable chemical and morphological changes of reaction products in binder-free, vertically aligned carbon nanotube (VACNT) electrodes during Li–O 2 battery cycling with a 1,2-dimethoxyethane (DME)-based electrolyte. X-ray absorption near edge structure (XANES) of discharged oxygen electrodes shows direct evidence for the formation of Li 2 CO 3 -like species at the interface between VACNTs and Li 2 O 2 but not significantly on the Li 2 O 2 surfaces exposed to the electrolyte. Although Li 2 O 2 and Li 2 CO 3 -like species were largely removed upon first charge, the oxidation kinetics became increasingly difficult during Li–O 2 cycling, which is accompanied by the accumulation of Li 2 CO 3 in the discharged and charged electrodes as evidenced by selected area electron diffraction (SAED) and transmission electron microscopy (TEM). Together, these results indicate that the irreversibility during Li–O 2 cycling in DME can be attributed largely to the growth of Li 2 CO 3 -like species associated with the reactivity between carbon and Li 2 O 2 or other reaction intermediates.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction
Liang, Y., Li, Y., Wang, H., Zhou, J., Wang, J., Regier, T., & Dai, H. (2011) · Nature Materials · doi:10.1038/nmat3087 · Cited by 5,494
Self-citationLithium−Air Battery: Promise and Challenges
Girishkumar, G., McCloskey, B., Luntz, A. C., Swanson, S., & Wilcke, W. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz1005384 · Cited by 2,528
A Polymer Electrolyte‐Based Rechargeable Lithium/Oxygen Battery
Abraham, K. M., & Jiang, Z. (1996) · Journal of The Electrochemical Society · doi:10.1149/1.1836378 · Cited by 2,092
A Reversible and Higher-Rate Li-O 2 Battery
Peng, Z., Freunberger, S. A., Chen, Y., & Bruce, P. G. (2012) · Science · doi:10.1126/science.1223985 · Cited by 1,915
Liang, Y., Wang, H., Zhou, J., Li, Y., Wang, J., Regier, T., & Dai, H. (2012) · Journal of the American Chemical Society · doi:10.1021/ja210924t · Cited by 1,374
Self-citationReactions in the Rechargeable Lithium–O2 Battery with Alkyl Carbonate Electrolytes
Freunberger, S. A., Chen, Y., Peng, Z., Griffin, J. M., Hardwick, L. J., Bardé, F., Novák, P., & Bruce, P. G. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2021747 · Cited by 1,270
The Lithium–Oxygen Battery with Ether‐Based Electrolytes
Freunberger, S. A., Chen, Y., Drewett, N. E., Hardwick, L. J., Bardé, F., & Bruce, P. G. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201102357 · Cited by 1,099
An improved high-performance lithium–air battery
Jung, H.-G., Hassoun, J., Park, J.-B., Sun, Y.-K., & Scrosati, B. (2012) · Nature Chemistry · doi:10.1038/nchem.1376 · Cited by 1,089
Twin Problems of Interfacial Carbonate Formation in Nonaqueous Li–O2 Batteries
McCloskey, B. D., Speidel, A., Scheffler, R., Miller, D. C., Viswanathan, V., Hummelshøj, J. S., Nørskov, J. K., & Luntz, A. C. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz300243r · Cited by 1,073
Cited by
Metal-Free Catalysts for Oxygen Reduction Reaction
Dai, L., Xue, Y., Qu, L., Choi, H.-J., & Baek, J.-B. (2015) · Chemical Reviews · doi:10.1021/cr5003563 · Cited by 2,380
Metadata
- Authors
- Gallant, B. M., Mitchell, R. R., Kwabi, D. G., Zhou, J., Zuin, L., Thompson, C. V., & Shao-Horn, Y.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-09-25
- Volume
- 116
- Issue
- 39
- Pages
- 20800-20805
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2316519985
- Cited by
- 382
- References
- 24
- FWCI
- 37.44
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Chemical and Morphological Changes of Li–O2 Battery Electrodes upon Cycling. https://app.cochat.ai/papers/10.1021/jp308093b
- The paper
- Gallant, B. M., Mitchell, R. R., Kwabi, D. G., Zhou, J., Zuin, L., Thompson, C. V., & Shao-Horn, Y. (2012). Chemical and Morphological Changes of Li–O2 Battery Electrodes upon Cycling. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp308093b
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
