The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
An Approach to Understanding the Electrocatalytic Activity Enhancement by Superexchange Interaction toward OER in Alkaline Media of Ni–Fe LDH
Abstract
In the present work, the hydrotalcite-like materials known as layered double hydroxides (LDHs) were synthesized. The Ni–Al and Ni–Fe materials with different Ni/Fe ratio were obtained by coprecipitation method at variable pH. The LDH structure was verified by X-ray diffraction, Fourier transform infrared, and Raman spectroscopy. No secondary extra phases were observed for any material. The electronic properties were evaluated by UV–vis spectroscopy, while the magnetic ones were followed by electron paramagnetic resonance (EPR). The results suggested that sample H/Ni–Fe2 (Ni/Fe = 2) has a ferrimagnetic behavior as a result of the combined action of Ni II –OH–Ni II, Fe III –OH–Ni II, and Fe III –OH–Fe III pairs across the layers and ferromagnetic interactions operating between layers. Furthermore, the material H/Ni–Fe1 (Ni/Fe = 1.5) showed a combination of paramagnetic and ferromagnetic interactions which favors a superexchange interaction among metal centers through the OH bridges across the cationic sheets; the superexchange interaction enhances the electrocatalytic activity on the oxygen evolution reaction (OER) in alkaline media. On the other hand, XPS experiments showed that the H/Ni–Fe1 did not exhibit structural changes after electrochemical processes. The activity toward the OER was in the order H/Ni–Fe1 > H/Ni–Fe2 > H/Ni–Al, as was confirmed using in situ linear sweep voltammetry (LSV) coupled with mass spectrometry (differential electrochemical mass spectrometry).
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Walter, M. G., Warren, E. L., McKone, J. R., Boettcher, S. W., Mi, Q., Santori, E. A., & Lewis, N. S. (2010) · Chemical Reviews · doi:10.1021/cr1002326 · Cited by 9,388
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
Cover Picture: Recoding the Genetic Code with Selenocysteine (Angew. Chem. Int. Ed. 1/2014)
Bröcker, M. J., Ho, J. M. L., Church, G. M., Söll, D., & O'Donoghue, P. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201310509 · Cited by 911
Cited by
Transition‐Metal (Co, Ni, and Fe)‐Based Electrocatalysts for the Water Oxidation Reaction
Han, L., Dong, S., & Wang, E. (2016) · Advanced Materials · doi:10.1002/adma.201602270 · Cited by 1,769
Liang, H., Meng, F., Cabán-Acevedo, M., Li, L., Forticaux, A., Xiu, L., Wang, Z., & Jin, S. (2015) · Nano Letters · doi:10.1021/nl504872s · Cited by 987
Anantharaj, S., Kundu, S., & Noda, S. (2021) · Nano Energy · doi:10.1016/j.nanoen.2020.105514 · Cited by 932
Oxygen Evolution Reaction in Alkaline Environment: Material Challenges and Solutions
Xie, X., Du, L., Yan, L., Park, S., Qiu, Y., Sokolowski, J., Wang, W., & Shao, Y. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202110036 · Cited by 792
Yang, Y., Dang, L., Shearer, M. J., Sheng, H., Li, W., Chen, J., Xiao, P., Zhang, Y., Hamers, R. J., & Jin, S. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201703189 · Cited by 708
Tang, C., Wang, H., Wang, H., Zhang, Q., Tian, G., Nie, J., & Wei, F. (2015) · Advanced Materials · doi:10.1002/adma.201501901 · Cited by 691
Transition metal based layered double hydroxides tailored for energy conversion and storage
Long, X., Wang, Z., Xiao, S., An, Y., & Yang, S. (2016) · Materials Today · doi:10.1016/j.mattod.2015.10.006 · Cited by 572
Ďurovič, M., Hnát, J., & Bouzek, K. (2021) · Journal of Power Sources · doi:10.1016/j.jpowsour.2021.229708 · Cited by 436
Liu, G., Li, P., Zhao, G., Wang, X., Kong, J., Liu, H., Zhang, H., Chang, K., Meng, X., Kako, T., et al. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b05190 · Cited by 420
Developments of Metal Phosphides as Efficient OER Precatalysts
Dutta, A., & Pradhan, N. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b02249 · Cited by 367
Plevová, M., Hnát, J., & Bouzek, K. (2021) · Journal of Power Sources · doi:10.1016/j.jpowsour.2021.230072 · Cited by 278
Dong, C., Yuan, X., Wang, X., Liu, X., Dong, W., Wang, R., Duan, Y., & Huang, F. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta04052g · Cited by 264
Magnetic Nanostructures: Rational Design and Fabrication Strategies toward Diverse Applications
Wang, S., Xu, J., Li, W., Sun, S., Gao, S., & Hou, Y. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00370 · Cited by 129
Sun, C., Wang, Y., Xu, L., Wang, Y., Wang, T., Sun, C., & Li, F. (2022) · ACS Applied Energy Materials · doi:10.1021/acsaem.2c00381 · Cited by 17
Metadata
- Authors
- Oliver-Tolentino, M. A., Vázquez-Samperio, J., Manzo-Robledo, A., González-Huerta, R. D. G., Flores-Moreno, J. L., Ramírez-Rosales, D., & Guzmán-Vargas, A.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-09-19
- Volume
- 118
- Issue
- 39
- Pages
- 22432-22438
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2078995981
- Cited by
- 245
- References
- 3
- FWCI
- 6.33
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
