An Approach to Understanding the Electrocatalytic Activity Enhancement by Superexchange Interaction toward OER in Alkaline Media of Ni–Fe LDH

Abstract

In the present work, the hydrotalcite-like materials known as layered double hydroxides (LDHs) were synthesized. The Ni–Al and Ni–Fe materials with different Ni/Fe ratio were obtained by coprecipitation method at variable pH. The LDH structure was verified by X-ray diffraction, Fourier transform infrared, and Raman spectroscopy. No secondary extra phases were observed for any material. The electronic properties were evaluated by UV–vis spectroscopy, while the magnetic ones were followed by electron paramagnetic resonance (EPR). The results suggested that sample H/Ni–Fe2 (Ni/Fe = 2) has a ferrimagnetic behavior as a result of the combined action of Ni II –OH–Ni II, Fe III –OH–Ni II, and Fe III –OH–Fe III pairs across the layers and ferromagnetic interactions operating between layers. Furthermore, the material H/Ni–Fe1 (Ni/Fe = 1.5) showed a combination of paramagnetic and ferromagnetic interactions which favors a superexchange interaction among metal centers through the OH bridges across the cationic sheets; the superexchange interaction enhances the electrocatalytic activity on the oxygen evolution reaction (OER) in alkaline media. On the other hand, XPS experiments showed that the H/Ni–Fe1 did not exhibit structural changes after electrochemical processes. The activity toward the OER was in the order H/Ni–Fe1 > H/Ni–Fe2 > H/Ni–Al, as was confirmed using in situ linear sweep voltammetry (LSV) coupled with mass spectrometry (differential electrochemical mass spectrometry).