The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Impact of Anionic Br– Substitution on Open Circuit Voltage in Lead Free Perovskite (CsSnI3-xBrx) Solar Cells
Abstract
Replacement of lead in the hybrid organic–inorganic perovskite solar cells invokes the need for non-toxic materials such as Sn. Although solution processed CsSnI 3 has been demonstrated as a lead-free halide perovskite which can function as a light absorber with high photocurrent densities, the power conversion efficiencies were bottlenecked by low open circuit voltages. In this work, the open circuit voltages are modulated by chemical doping of CsSnI 3 with Br leading to formation of CsSnI 3- x Br x (0 ≤ x ≤ 3) perovskites. The beneficial effect of Br incorporation for V oc improvement is evident for CsSnI 3 system even without the addition of SnF 2 . There is an evolution of the crystal structure of CsSnI 3 from orthorhombic to cubic for CsSnBr 3 accompanied by changes in its optical properties with a blue shift of the absorption and IPCE onset, as the Br – doping is increased. The V oc enhancement is attributed to the decrease in Sn vacancies which is reflected by the lower charge carrier densities of 10 15 cm –3 and a high resistance to charge recombination in case of Br rich CsSnI 3- x Br x perovskite. By the addition of SnF 2 to CsSnI 3- x Br x perovskite, the current densities are improved significantly.
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Cites
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
Jeon, N. J., Noh, J. H., Kim, Y. C., Yang, W. S., Ryu, S., & Seok, S. I. (2014) · Nature Materials · doi:10.1038/nmat4014 · Cited by 6,723
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Synthetic Approaches for Halide Perovskite Thin Films
Dunlap-Shohl, W. A., Zhou, Y., Padture, N. P., & Mitzi, D. B. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00318 · Cited by 631
A critical review on tin halide perovskite solar cells
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Lyu, M., Yun, J., Chen, P., Hao, M., & Wang, L. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201602512 · Cited by 432
Lead-Free Perovskite Materials for Solar Cells
Wang, M., Wang, W., Ma, B., Shen, W., Liu, L., Cao, K., Chen, S., & Huang, W. (2021) · Nano-Micro Letters · doi:10.1007/s40820-020-00578-z · Cited by 423
Optoelectronic Properties of (CH3NH3)3Sb2I9 Thin Films for Photovoltaic Applications
Hebig, J.-C., Kühn, I., Flohre, J., & Kirchartz, T. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00170 · Cited by 375
Chen, L.-J., Lee, C.-R., Chuang, Y.-J., Wu, Z.-H., & Chen, C. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b02344 · Cited by 361
Yokoyama, T., Cao, D. H., Stoumpos, C. C., Song, T.-B., Sato, Y., Aramaki, S., & Kanatzidis, M. G. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00118 · Cited by 353
Perovskite Solar Cells: Can We Go Organic‐Free, Lead‐Free, and Dopant‐Free?
Miyasaka, T., Kulkarni, A., Kim, G. M., Öz, S., & Jena, A. K. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201902500 · Cited by 293
Tong, J., Jiang, Q., Ferguson, A. J., Palmstrom, A. F., Wang, X., Hao, J., Dunfield, S. P., Louks, A. E., Harvey, S. P., Li, C., et al. (2022) · Nature Energy · doi:10.1038/s41560-022-01046-1 · Cited by 284
Tin-Based Defects and Passivation Strategies in Tin-Related Perovskite Solar Cells
Li, B., Chang, B., Pan, L., Li, Z., Fu, L., He, Z., & Yin, L. (2020) · ACS Energy Letters · doi:10.1021/acsenergylett.0c01796 · Cited by 258
Metadata
- Authors
- Sabba, D., Mulmudi, H. K., Prabhakar, R. R., Krishnamoorthy, T., Baikie, T., Boix, P. P., Mhaisalkar, S., & Mathews, N.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-01-20
- Volume
- 119
- Issue
- 4
- Pages
- 1763-1767
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2321209071
- Cited by
- 421
- References
- 1
- FWCI
- 17.32
- Type
- journal article
- Language
- en
- Open access
- closed
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