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Enhanced Hydrogen Storage Kinetics of LiBH4in Nanoporous Carbon Scaffolds
Abstract
Enhanced kinetics for hydrogen exchange in LiBH 4 incorporated within nanoporous carbon scaffolds are described. Dehydrogenation rates up to 50 times faster than those in the bulk material are measured at 300 °C in a nanostructured hydride formed by filling a porous carbon aerogel host with LiBH 4 . Furthermore, the activation energy for hydrogen desorption, measured using the approach developed by Ozawa, is reduced from 146 kJ/mol for bulk LiBH 4 to 103 kJ/mol for nanostructured LiBH 4, and the faster kinetics result in desorption temperatures that are reduced by up to 75 °C. In addition, nanostructured hydrides exhibit increased cycling capacity over multiple sorption cycles. This work demonstrates that confinement within a porous scaffold host is a promising approach for enhancing hydrogen uptake and release in reversible light-metal complex hydrides.
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Metadata
- Authors
- Gross, A. F., Vajo, J. J., Van Atta, S. L., & Olson, G. L.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-03-18
- Volume
- 112
- Issue
- 14
- Pages
- 5651-5657
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2071038343
- Cited by
- 438
- References
- 16
- FWCI
- 21.89
- Type
- journal article
- Language
- en
- Open access
- closed
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