The DOI matches its Crossref record; 16 of the 16 references it cites were found in a registry or an index.
Enhanced Hydrogen Storage Kinetics of LiBH4in Nanoporous Carbon Scaffolds
Abstract
Enhanced kinetics for hydrogen exchange in LiBH 4 incorporated within nanoporous carbon scaffolds are described. Dehydrogenation rates up to 50 times faster than those in the bulk material are measured at 300 °C in a nanostructured hydride formed by filling a porous carbon aerogel host with LiBH 4 . Furthermore, the activation energy for hydrogen desorption, measured using the approach developed by Ozawa, is reduced from 146 kJ/mol for bulk LiBH 4 to 103 kJ/mol for nanostructured LiBH 4, and the faster kinetics result in desorption temperatures that are reduced by up to 75 °C. In addition, nanostructured hydrides exhibit increased cycling capacity over multiple sorption cycles. This work demonstrates that confinement within a porous scaffold host is a promising approach for enhancing hydrogen uptake and release in reversible light-metal complex hydrides.
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Citations
Cites
A New Method of Analyzing Thermogravimetric Data
Ozawa, T. (1965) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.38.1881 · Cited by 6,911
KAJI, K. (1975) · Sen'i Gakkaishi · doi:10.2115/fiber.31.7_p204 · Cited by 2,462
Kinetic analysis of derivative curves in thermal analysis
Ozawa, T. (1970) · Journal of Thermal Analysis · doi:10.1007/bf01911411 · Cited by 2,285
Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density
Lowell, S., Shields, J. E., Thomas, M. A., & Thommes, M. (2004) · Particle Technology Series · doi:10.1007/978-1-4020-2303-3 · Cited by 1,824
Thermal Decomposition of the Non-Interstitial Hydrides for the Storage and Production of Hydrogen
Grochala, W., & Edwards, P. P. (2004) · Chemical Reviews · doi:10.1021/cr030691s · Cited by 1,571
Preparation and Properties of Resorcinol–Formaldehyde Organic and Carbon Gels
Al‐Muhtaseb, S. A., & Ritter, J. A. (2003) · Advanced Materials · doi:10.1002/adma.200390020 · Cited by 1,023
Nanoscaffold Mediates Hydrogen Release and the Reactivity of Ammonia Borane
Gutowska, A., Li, L., Shin, Y., Wang, C. M., Li, X. S., Linehan, J. C., Smith, R. S., Kay, B. D., Schmid, B., Shaw, W., et al. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200462602 · Cited by 793
Light metal hydrides and complex hydrides for hydrogen storage
Schüth, F., Bogdanović, B., & Felderhoff, M. (2004) · Chem. Commun. · doi:10.1039/b406522k · Cited by 707
Hydrogen storage properties of LiBH4
Züttel, A., Rentsch, S., Fischer, P., Wenger, P., Sudan, P., Mauron, P., & Emmenegger, C. (2003) · Journal of Alloys and Compounds · doi:10.1016/s0925-8388(02)01253-7 · Cited by 688
Vajo, J. J., Mertens, F., Ahn, C. C., Bowman, R. C., & Fultz, B. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp040060h · Cited by 477
Self-citationTetrahydroborates as new hydrogen storage materials
Züttel, A., Borgschulte, A., & Orimo, S.-I. (2007) · Scripta Materialia · doi:10.1016/j.scriptamat.2007.01.010 · Cited by 339
Hydrogen Desorption Exceeding Ten Weight Percent from the New Quaternary Hydride Li3BN2H8
Pinkerton, F. E., Meisner, G. P., Meyer, M. S., Balogh, M. P., & Kundrat, M. D. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp0455475 · Cited by 322
Hard-Templating Pathway To Create Mesoporous Magnesium Oxide
Li, W.-C., Lu, A.-H., Weidenthaler, C., & Schüth, F. (2004) · Chemistry of Materials · doi:10.1021/cm048759n · Cited by 244
Facilitated Hydrogen Storage in NaAlH4 Supported on Carbon Nanofibers
Baldé, K., Hereijgers, B. P. C., Bitter, J. H., & de Jong, K. P. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200504202 · Cited by 175
Adsorption and catalysis: The effect of confinement on chemical reactions
Santiso, E. E., George, A. M., Turner, C. H., Kostov, M. K., Gubbins, K. E., Nardelli, M. B., & Śliwińska-Bartkowiak, M. (2005) · Applied Surface Science · doi:10.1016/j.apsusc.2005.02.101 · Cited by 94
Metal–N–H systems for the hydrogen storage
Chen, P., Xiong, Z., Wu, G., Liu, Y., Hu, J., & Luo, W. (2007) · Scripta Materialia · doi:10.1016/j.scriptamat.2007.01.001 · Cited by 93
Cited by
Nanostructured carbon for energy storage and conversion
Candelaria, S. L., Shao, Y., Zhou, W., Li, X., Xiao, J., Zhang, J.-G., Wang, Y., Liu, J., Li, J., & Cao, G. (2012) · Nano Energy · doi:10.1016/j.nanoen.2011.11.006 · Cited by 975
Yu, X., Tang, Z., Sun, D., Ouyang, L., & Zhu, M. (2017) · Progress in Materials Science · doi:10.1016/j.pmatsci.2017.03.001 · Cited by 716
Advanced carbon aerogels for energy applications
Biener, J., Stadermann, M., Suss, M., Worsley, M. A., Biener, M. M., Rose, K. A., & Baumann, T. F. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00627k · Cited by 651
Improved Hydrogen Storage Kinetics of Nanoconfined NaAlH4 Catalyzed with TiCl3 Nanoparticles
Nielsen, T. K., Polanski, M., Zasada, D., Javadian, P., Besenbacher, F., Bystrzycki, J., Skibsted, J., & Jensen, T. R. (2011) · ACS Nano · doi:10.1021/nn200643b · Cited by 117
Yu, S., Song, S., Li, R., & Fang, B. (2020) · Nanoscale · doi:10.1039/d0nr05050d · Cited by 63
Metadata
- Authors
- Gross, A. F., Vajo, J. J., Van Atta, S. L., & Olson, G. L.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-03-18
- Volume
- 112
- Issue
- 14
- Pages
- 5651-5657
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2071038343
- Cited by
- 438
- References
- 16
- FWCI
- 21.89
- Type
- journal article
- Language
- en
- Open access
- closed
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