The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Probing the Reaction Kinetics of the Charge Reactions of Nonaqueous Li–O2 Batteries
Abstract
Understanding the reaction mechanism of nonaqueous oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is key to increase the low round-trip efficiency and power capability of rechargeable Li-air batteries. Here we show that the ORR kinetics are much faster than OER kinetics and OER occurs in two distinct stages upon Li-air battery charging. The first OER stage occurs at low overpotentials (<400 mV) with a slopping voltage profile, whose kinetics are relatively insensitive to charge rates and catalysts. This OER stage could be attributed to the delithiation of the outer part of Li2O2 forming lithium-deficient Li2-xO2, which is chemically disproportionate to evolve O2. The second stage takes place at high overpotentials (400-1200 mV), whose kinetics are sensitive to discharge/charge rates and catalysts, which can be attributed to the oxidation of bulk Li2O2 particles. Our study provides insights into bridging current two schools of thought on the OER mechanism.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
CRC Handbook of Chemistry and Physics
(2014) · doi:10.1201/b17118 · Cited by 57,706
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Cited by
Carbon-based electrocatalysts for advanced energy conversion and storage
Zhang, J., Xia, Z., & Dai, L. (2015) · Science Advances · doi:10.1126/sciadv.1500564 · Cited by 735
Current density dependence of peroxide formation in the Li–O2 battery and its effect on charge
Adams, B. D., Radtke, C., Black, R., Trudeau, M. L., Zaghib, K., & Nazar, L. F. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40697k · Cited by 678
Sun, B., Huang, X., Chen, S., Munroe, P., & Wang, G. (2014) · Nano Letters · doi:10.1021/nl500397y · Cited by 344
Metadata
- Authors
- Lu, Y.-C., & Shao-Horn, Y.
- Venue
- The Journal of Physical Chemistry Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-12-18
- Volume
- 4
- Issue
- 1
- Pages
- 93-99
- ISSN
- 1948-7185 (ISSN-L)
- OpenAlex
- W2004811317
- Cited by
- 346
- References
- 2
- FWCI
- 22.18
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Probing the Reaction Kinetics of the Charge Reactions of Nonaqueous Li–O2 Batteries. https://app.cochat.ai/papers/10.1021/jz3018368
- The paper
- Lu, Y.-C., & Shao-Horn, Y. (2013). Probing the Reaction Kinetics of the Charge Reactions of Nonaqueous Li–O2 Batteries. The Journal of Physical Chemistry Letters. https://doi.org/10.1021/jz3018368
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
