Syntheses of Silica/Polystyrene-block-Poly(ethylene oxide) Films with Regular and Reverse Mesostructures of Large Characteristic Length Scales by Solvent Evaporation-Induced Self-Assembly
Abstract
Silica/diblock films with various mesostructures of large characteristic length scales were synthesized through evaporation-induced self-assembly (EISA). The structure-directing agents used were amphiphilic polystyrene- block -poly(ethylene oxide) (PS- b -PEO) diblock copolymers of high molecular weights. The synthesis process began with a dilute homogeneous solution of a silica precursor and the diblock copolymer in a mixture of tetrahydrofuran (THF) and water. After this dilute solution was cast, THF preferentially evaporated; accordingly, the species in the depositing film increasingly concentrated and the solvent quality for the diblock progressively decreased. At some critical point, cooperative self-assembly of both the PS- b -PEO diblock and the silicate started. Subsequently, liquid-crystalline mesophases were obtained. The present study indicates that silica/diblock films with different mesostructures can be synthesized by using one identical diblock; as the volume ratio of the diblock to silica increases, mesostructures change progressively from regular to inverted (reverse) via lamellar. For the silica/diblock films with regular mesophases, copolymer removal produces mesopores; highly ordered mesoporous silica films with different pore sizes result from using diblocks with different molecular weights. Particularly noteworthy is the ready formation of the silica/diblock multi-bilayer vesicular mesostructures. The present system is believed to be the first to use high glass transition temperature ( T g ≈ 373 K), PS-based amphiphilic diblock copolymers to prepare silica/diblock films with regular and reverse mesophases, as well as multi-bilayer vesicular mesostructures, through solvent evaporation-induced self-assembly.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Using a pore expanding agent in the composite risks unstable mesostructures.
“However, care must be taken when using the pore expanding agent to the composite in order to avoid the risk of unstable mesostructures [160].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [160]
Cites
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
Kresge, C. T., Leonowicz, M. E., Roth, W. J., Vartuli, J. C., & Beck, J. S. (1992) · Nature · doi:10.1038/359710a0 · Cited by 16,283 · see citing works
Zhang, L., & Eisenberg, A. (1995) · Science · doi:10.1126/science.268.5218.1728 · Cited by 2,474 · see citing works
Self-citationGeneralized synthesis of periodic surfactant/inorganic composite materials
Huo, Q., Margolese, D. I., Ciesla, U., Feng, P., Gier, T. E., Sieger, P., León, R., Petroff, P. M., Schüth, F., & Stucky, G. D. (1994) · Nature · doi:10.1038/368317a0 · Cited by 2,088 · see citing works
Evaporation-Induced Self-Assembly: Nanostructures Made Easy
Brinker, C. J., Lu, Y., Sellinger, A., & Fan, H. (1999) · Advanced Materials · doi:10.1002/(sici)1521-4095(199905)11:7 · Cited by 2,078 · see citing works
Self-citationRingsdorf, H., Schlarb, B., & Venzmer, J. (1988) · Angewandte Chemie International Edition in English · doi:10.1002/anie.198801131 · Cited by 1,455 · see citing works
Zhang, L., & Eisenberg, A. (1996) · Journal of the American Chemical Society · doi:10.1021/ja953709s · Cited by 1,262 · see citing works
Self-citationSynthesis of inorganic materials with complex form
Mann, S., & Ozin, G. A. (1996) · Nature · doi:10.1038/382313a0 · Cited by 1,149 · see citing works
Synthesis of Hexagonally Packed Mesoporous TiO2 by a Modified Sol–Gel Method
Antonelli, D. M., & Ying, J. Y. Y. (1995) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199520141 · Cited by 1,111 · see citing works
Aerosol-assisted self-assembly of mesostructured spherical nanoparticles
Lu, Y., Fan, H., Stump, A., Ward, T. L., Rieker, T. P., & Brinker, C. J. (1999) · Nature · doi:10.1038/18410 · Cited by 986 · see citing works
Self-citationIon-Induced Morphological Changes in “Crew-Cut” Aggregates of Amphiphilic Block Copolymers
Zhang, L., Yu, K., & Eisenberg, A. (1996) · Science · doi:10.1126/science.272.5269.1777 · Cited by 914 · see citing works
Self-citationSynthetic Bilayer Membranes: Molecular Design, Self‐Organization, and Application
Kunitake, T. (1992) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199207091 · Cited by 685 · see citing works
Organically modified aluminosilicate mesostructures from block copolymer phases
Templin, M., Franck, A., Du Chesne, A., Leist, H., Zhang, Y., Ulrich, R., Schädler, V., & Wiesner, U. (1997) · Science · doi:10.1126/science.278.5344.1795 · Cited by 668 · see citing works
Large differences in tropical aerosol forcing at the top of the atmosphere and Earth's surface
Satheesh, S. K., & Ramanathan, V. (2000) · Nature · doi:10.1038/35011039 · Cited by 657 · see citing works
Continuous self-assembly of organic–inorganic nanocomposite coatings that mimic nacre
Sellinger, A., Weiss, P. M., Nguyen, A., Lu, Y., Assink, R. A., Gong, W., & Brinker, C. J. (1998) · Nature · doi:10.1038/28354 · Cited by 577 · see citing works
Self-citationBlock and graft copolymer micelles in solution
Tuzar, Z., & Kratochvı́l, P. (1976) · Advances in Colloid and Interface Science · doi:10.1016/0001-8686(76)80009-7 · Cited by 442 · see citing works
Morphogenic Effect of Solvent on Crew-Cut Aggregates of Apmphiphilic Diblock Copolymers
Yu, Y., Zhang, L., & Eisenberg, A. (1998) · Macromolecules · doi:10.1021/ma971254g · Cited by 439 · see citing works
Self-citationDevelopments in block copolymers—1
Lewis, J. E. (1983) · Polymer Photochemistry · doi:10.1016/0144-2880(83)90103-3 · Cited by 414 · see citing works
Extraction of a hydrophilic compound from water into liquid CO2 using dendritic surfactants
Cooper, A. I., Londono, J. D., Wignall, G. D., McClain, J. B., Samulski, E. T., Lin, J. S., Dobrynin, A. V., Rubinstein, M., Burke, A. L. C., Fréchet, J. M. J., et al. (1997) · Nature · doi:10.1038/38706 · Cited by 379 · see citing works
Porter, M. R. (1991) · Springer eBooks · doi:10.1007/978-1-4615-3676-5 · Cited by 377 · see citing works
Yu, K., & Eisenberg, A. (1996) · Macromolecules · doi:10.1021/ma960381u · Cited by 315 · see citing works
Self-citationKrämer, E., Förster, S., Göltner, C. G., & Antonietti, M. (1998) · Langmuir · doi:10.1021/la9712505 · Cited by 215 · see citing works
Kinning, D. J., Winey, K. I., & Thomas, E. L. (1988) · Macromolecules · doi:10.1021/ma00190a027 · Cited by 157 · see citing works
Nano-objects with Controlled Shape, Size, and Composition from Block Copolymer Mesophases
Ulrich, R., Chesne, A. D., Templin, M., & Wiesner, U. B. (1999) · Advanced Materials · doi:10.1002/(sici)1521-4095(199902)11:2 · Cited by 118 · see citing works
Yu, K., Bartels, C., & Eisenberg, A. (1999) · Langmuir · doi:10.1021/la981688k · Cited by 84 · see citing works
Self-citationYu, K., Bartels, C., & Eisenberg, A. (1998) · Macromolecules · doi:10.1021/ma9809785 · Cited by 71 · see citing works
Self-citationOzin, G. A., Chomski, E., Khushalani, D., & MacLachlan, M. J. (1998) · Current Opinion in Colloid & Interface Science · doi:10.1016/s1359-0294(98)80012-5 · Cited by 60 · see citing works
Hruška, Z., Hurtrez, G., Walter, S., & Riess, G. (1992) · Polymer · doi:10.1016/0032-3861(92)90544-7 · Cited by 35 · see citing works
Morphology of block copolymers in a selective environment
Siqueira, D. F., & Nunes, S. P. (1994) · Polymer · doi:10.1016/0032-3861(94)90501-0 · Cited by 15 · see citing works
Yu, K., Brinker, C. J., Hurd, A. J., & Eisenberg, A. (2000) · University of North Texas Digital Library (University of North Texas) · Cited by 3 · see citing works
Self-citation
Flagged first, then by citations
Cited by
Sorted by citations
On the controllable soft-templating approach to mesoporous silicates
Wan, Y., & Zhao (2007) · Chemical Reviews · doi:10.1021/cr068020s · Cited by 2,371 · see citing works
Directing the self-assembly of block copolymers
Darling, S. B. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2007.05.004 · Cited by 1,023 · see citing works
Nanostructure fabrication using block copolymers
Hamley, I. W. (2003) · Nanotechnology · doi:10.1088/0957-4484/14/10/201 · Cited by 773 · see citing works
Templated Synthesis for Nanoarchitectured Porous Materials
Malgras, V., Ji, Q., Kamachi, Y., Mori, T., Shieh, F., Wu, K. C. ‐., Ariga, K., & Yamauchi, Y. (2015) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.20150143 · Cited by 545 · see citing works
Block Copolymers: Synthesis, Self-Assembly, and Applications
Feng, H., Lu, X., Wang, W., Kang, N.-G., & Mays, J. (2017) · Polymers · doi:10.3390/polym9100494 · Cited by 467 · see citing works
“However, care must be taken when using the pore expanding agent to the composite in order to avoid the risk of unstable mesostructures [160].”
BackgroundLarge-pore ordered mesoporous materials templated from non-pluronic amphiphilic block copolymers
Deng, Y., Wei, J., Sun, Z., & Zhao, D. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35426h · Cited by 447 · see citing works
Deng, Y., Yu, T., Wan, Y., Shi, Y., Meng, Y., Gu, D., Zhang, L., Huang, Y., Liu, C., Wu, X., et al. (2007) · Journal of the American Chemical Society · doi:10.1021/ja067379v · Cited by 402 · see citing works
Kim, T., Ryoo, R., Kruk, M., Gierszal, K. P., Jaroniec, M., Kamiya, S., & Terasaki, O. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp048582k · Cited by 339 · see citing works
New insight into the synthesis of large-pore ordered mesoporous materials
Wei, J., Sun, Z., Luo, W., Li, Y., Elzatahry, A. A., Al-Enizi, A. M., Deng, Y., & Zhao, D. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11411 · Cited by 336 · see citing works
Designed synthesis of mesoporous solids via nonionic-surfactant-templating approach
Wan, Y., Shi, Y., & Zhao, D. (2006) · Chemical Communications · doi:10.1039/b610570j · Cited by 327 · see citing works
Maleki, A., Kettiger, H., Schoubben, A., Rosenholm, J. M., Ambrogi, V., & Hamidi, M. (2017) · Journal of Controlled Release · doi:10.1016/j.jconrel.2017.07.047 · Cited by 285 · see citing works
Yang, H. S., Xu, R., Xue, X., Li, F., & Li, G. (2007) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2007.07.060 · Cited by 198 · see citing works
Nanostructured hybrid materials from aqueous polymer dispersions
Castelvetro, V., & Vita, C. D. (2003) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2003.10.017 · Cited by 169 · see citing works
Huang, R., Shen, Y., Guan, Y., Jiang, Y., Wu, Y., Rahman, K., Zhang, L., Liu, H., & Luan, X. (2020) · Acta Biomaterialia · doi:10.1016/j.actbio.2020.09.009 · Cited by 159 · see citing works
Synthesis of ordered mesoporous materials using surfactant liquid crystals or micellar solutions
Palmqvist, A. E. C. (2003) · Current Opinion in Colloid & Interface Science · doi:10.1016/s1359-0294(03)00020-7 · Cited by 153 · see citing works
Supramolecular Organization of Polymeric Materials in Nanoporous Hard Templates
Steinhart, M. (2008) · Springer eBooks · doi:10.1007/12_2008_142 · Cited by 136 · see citing works
Nisticò, R., Scalarone, D., & Magnacca, G. (2017) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2017.04.017 · Cited by 135 · see citing works
Kim, K., Yun, T. Y., You, S., Tang, X., Lee, J. Y., Seo, Y., Kim, Y., Kim, S. H., Moon, H. C., & Kim, J. K. (2020) · NPG Asia Materials · doi:10.1038/s41427-020-00257-w · Cited by 123 · see citing works
Ma, G., Yan, X., Li, Y., Xiao, L., Huang, Z., Lu, Y., & Fan, J. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1027524 · Cited by 119 · see citing works
Inorganic Nanodots from Thin Films of Block Copolymers
Kim, D. H., Kim, S. H., Lavery, K. A., & Russell, T. P. (2004) · Nano Letters · doi:10.1021/nl049063w · Cited by 112 · see citing works
Ortel, E., Fischer, A., Chuenchom, L., Polte, J., Emmerling, F., Smarsly, B. M., & Kraehnert, R. (2011) · Small · doi:10.1002/smll.201101520 · Cited by 105 · see citing works
Yu, K., Smarsly, B. M., & Brinker, C. J. (2003) · Advanced Functional Materials · doi:10.1002/adfm.200390005 · Cited by 100 · see citing works
Self-citationOrganic–Inorganic Nanohybridization by Block Copolymer Thin Films
Kim, D. H., Sun, Z., Russell, T. P., Knoll, W., & Gutmann, J. S. (2005) · Advanced Functional Materials · doi:10.1002/adfm.200400462 · Cited by 81 · see citing works
Synthesis of Ultralarge-Pore FDU-12 Silica with Face-Centered Cubic Structure
Huang, L., Yan, X., & Kruk, M. (2010) · Langmuir · doi:10.1021/la102228u · Cited by 80 · see citing works
Kim, K., Park, B., Kim, J., Jo, C., & Kim, J. K. (2023) · Journal of Materials Chemistry A · doi:10.1039/d2ta09353g · Cited by 71 · see citing works
Smarsly, B. M., Xomeritakis, G., Yu, K., Liu, N., Fan, H., Assink, R. A., Drewien, C. A., Ruland, W., & Brinker, C. J. (2003) · Langmuir · doi:10.1021/la034798m · Cited by 69 · see citing works
Self-citationLokupitiya, H. N., Jones, A., Reid, B., Guldin, S., & Stefik, M. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b04407 · Cited by 69 · see citing works
Ma, T., Cao, J., Shao, G.-S., Zhang, X., & Yuan, Z. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp906187g · Cited by 66 · see citing works
Synthesis and characterization of large-pore FDU-12 silica
Kruk, M., & Hui, C. M. (2007) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2007.12.015 · Cited by 63 · see citing works
Facile Synthesis of Zr-Based Functional Materials with Highly Ordered Mesoporous Structures
Yuan, Q., Li, L., Lu, S.-L., Duan, H., Li, Z., Zhu, Y., & Yan, C. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp806467c · Cited by 60 · see citing works
Han, L., Xu, D., Liu, Y., Ohsuna, T., Yao, Y. X., Jiang, C., Mai, Y., Cao, Y., Duan, Y., & Che, S. (2014) · Chemistry of Materials · doi:10.1021/cm5033139 · Cited by 54 · see citing works
Bloch, E., Phan, T. N. T., Bertin, D., Llewellyn, P. L., & Hornebecq, V. (2007) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2007.10.051 · Cited by 53 · see citing works
Garcia, C. B. W., Zhang, Y., Mahajan, S., DiSalvo, F. J., & Wiesner, U. B. (2003) · Journal of the American Chemical Society · doi:10.1021/ja037116q · Cited by 53 · see citing works
A novel technique for preparation of monodisperse giant liposomes
Taylor, P., Xu, C., Fletcher, P. D. I., & Paunov, V. N. (2003) · Chemical Communications · doi:10.1039/b304059c · Cited by 50 · see citing works
Ivanchikova, I. D., Maksimchuk, N. V., Skobelev, I. Y., Kaichev, V. V., & Kholdeeva, O. A. (2015) · Journal of Catalysis · doi:10.1016/j.jcat.2015.10.003 · Cited by 49 · see citing works
Bloch, E., Llewellyn, P. L., Phan, T. N. T., Bertin, D., & Hornebecq, V. (2008) · Chemistry of Materials · doi:10.1021/cm801978w · Cited by 48 · see citing works
Cho, B., Jain, A., Nieberle, J., Mahajan, S., Wiesner, U. B., Gruner, S. M., Türk, S., & Räder, H. J. (2004) · Macromolecules · doi:10.1021/ma035745e · Cited by 48 · see citing works
Mahajan, S., Renker, S., Simon, P. F. W., Gutmann, J. S., Jain, A., Gruner, S. M., Fetters, L. J., Coates, G. W., & Wiesner, U. B. (2003) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200390084 · Cited by 47 · see citing works
In Situ Loading of Drugs into Mesoporous Silica SBA‐15
Wan, M. M., Li, Y. Y., Yang, T., Zhang, T., Sun, X. D., & Zhu, J. H. (2016) · Chemistry - A European Journal · doi:10.1002/chem.201504532 · Cited by 46 · see citing works
Jiang, X., Suzuki, N., Bastakoti, B. P., Wu, K. C. ‐., & Yamauchi, Y. (2012) · Chemistry - An Asian Journal · doi:10.1002/asia.201200256 · Cited by 46 · see citing works
Ivanchikova, I. D., Kovalev, M., Mel’gunov, M. S., Шмаков, А. Н., & Kholdeeva, O. A. (2013) · Catalysis Science & Technology · doi:10.1039/c3cy00615h · Cited by 45 · see citing works
Dinakaran, K., Kochuveedu, S. T., Jang, Y. H., Jang, Y. J., Lee, J. Y., Lee, J.-E., Lee, J., Kim, J., & Kim, D. H. (2010) · Polymers · doi:10.3390/polym2040490 · Cited by 44 · see citing works
Colloidal CdSe 0-Dimension Nanocrystals and Their Self-Assembled 2-Dimension Structures
Liu, Y., Zhang, B., Fan, H., Rowell, N. L., Willis, M. A. C., Zheng, X., Che, R., Han, S., & Yu, K. (2018) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b04645 · Cited by 42 · see citing works
Self-citationLi, Y., Wei, J., Luo, W. H., Wang, C., Li, W., Feng, S., Yue, Q., Wang, M., Elzatahry, A. A. F., Deng, Y., et al. (2014) · Chemistry of Materials · doi:10.1021/cm403921u · Cited by 41 · see citing works
Fabrication of 2D arrays of giant liposomes on solid substrates by microcontact printing
Taylor, P., Xu, C., Fletcher, P. D. I., & Paunov, V. N. (2003) · Physical Chemistry Chemical Physics · doi:10.1039/b308082j · Cited by 40 · see citing works
Kirmayer, S., Dovgolevsky, E., Kalina, M., Lakin, E. E., Cadars, S., Epping, J. D., Fernández‐Arteaga, A., Rodríguez‐Abreu, C., Chmelka, B. F., & Frey, G. L. (2008) · Chemistry of Materials · doi:10.1021/cm703478g · Cited by 37 · see citing works
Sakai, K., Smith, E. G., Webber, G. B., Schatz, C., Wanless, E. J., Bütün, V., Armes, S. P., & Biggs, S. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp062830q · Cited by 37 · see citing works
Facile Synthesis of Highly Ordered Mesoporous ZnTiO3 with Crystalline Walls by Self-Adjusting Method
Li, Z., Shi, F.-B., Ding, Y., Zhang, T., & Yan, C. (2011) · Langmuir · doi:10.1021/la2034615 · Cited by 36 · see citing works
Wang, C., Wei, J., Yue, Q., Luo, W. H., Li, Y., Wang, M., Deng, Y., & Zhao, D. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201305527 · Cited by 34 · see citing works
Tunable diblock copolymer micelles–adapting behaviour via subtle chemical modifications
Webber, G. B., Wanless, E. J., Armes, S. P., & Biggs, S. (2004) · Faraday Discussions · doi:10.1039/b403180f · Cited by 31 · see citing works
Analytical Understanding of the Materials Design with Well‐Described Shrinkages on Multiscale
Ma, Q., Dutta, S., Wu, K. C. ‐., & Kimura, T. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201704198 · Cited by 30 · see citing works
Li, J., & Kuo, S. (2011) · RSC Advances · doi:10.1039/c1ra00349f · Cited by 30 · see citing works
Coalescence-Driven Verticality in Mesoporous TiO2 Thin Films with Long-Range Ordering
Malgras, V., Shirai, Y., Takei, T., & Yamauchi, Y. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c05708 · Cited by 30 · see citing works
Ah, M., Shin, C., Dinakaran, K., Jang, Y. H., Kochuveedu, S. T., Ryu, D. Y., & Kim, D. H. (2009) · Journal of Materials Chemistry · doi:10.1039/b907922j · Cited by 29 · see citing works
Periodic Mesoporous Benzene−Silicas Prepared Using Boric Acid as Catalyst
Cho, E., Mandal, M., & Jaroniec, M. (2011) · Chemistry of Materials · doi:10.1021/cm200166f · Cited by 29 · see citing works
Synthesis of Amphiphilic ABC Triblock Copolymers with PEO as the Middle Block
Mahajan, S., Cho, B., Allgaier, J., Fetters, L. J., Coates, G. W., & Wiesner, U. B. (2004) · Macromolecular Rapid Communications · doi:10.1002/marc.200400383 · Cited by 29 · see citing works
Torad, N. L., Lian, H., Wu, K. C. ‐., Zakaria, M. B., Suzuki, N., Ishihara, S., Ji, Q., Matsuura, M., Maekawa, K., Ariga, K., et al. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm33510g · Cited by 28 · see citing works
Mao, W., Cao, X., Sheng, Q., Han, L., & Che, S. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201704639 · Cited by 28 · see citing works
Chen, X., Knez, M., Berger, A., Nielsch, K., Gösele, U., & Steinhart, M. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200700923 · Cited by 28 · see citing works
Surfactant-Templated Synthesis of Ordered Silicas with Closed Cylindrical Mesopores
Mandal, M., & Kruk, M. (2011) · Chemistry of Materials · doi:10.1021/cm202577g · Cited by 28 · see citing works
Uchiyama, H., Matsui, T., & Kozuka, H. (2015) · Langmuir · doi:10.1021/acs.langmuir.5b02929 · Cited by 28 · see citing works
In Situ Growth of Mesoporous Silica with Drugs on Titanium Surface and Its Biomedical Applications
Wan, M., Zhang, J. C., Wang, Q., Zhan, S., Chen, X., Mao, C., Liu, Y., & Shen, J. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b05163 · Cited by 27 · see citing works
Peng, J., Li, X., Kim, D. H., & Knoll, W. (2007) · Macromolecular Rapid Communications · doi:10.1002/marc.200700430 · Cited by 26 · see citing works
Wang, C., Wei, J., Yue, Q., Luo, W. H., Li, Y., Wang, M., Deng, Y., & Zhao, D. (2013) · Angewandte Chemie · doi:10.1002/ange.201305527 · Cited by 26 · see citing works
Magbitang, T., Lee, V. Y., Cha, J. N., Wang, H. V., Chung, W. R., Miller, R. D., Dubois, G., Volksen, W., Kim, H., & Hedrick, J. L. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200501577 · Cited by 26 · see citing works
Yu, K., Wu, X., Brinker, C. J., & Ripmeester, J. A. (2003) · Langmuir · doi:10.1021/la034310h · Cited by 26 · see citing works
Self-citationGarcia, C. B. W., Lovell, C. S., Curry, C., Faught, M., Zhang, Y., & Wiesner, U. B. (2003) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/polb.10705 · Cited by 25 · see citing works
A Shifted Double‐Diamond Titania Scaffold
Li, H., Liu, Y., Cao, X., Han, L., Jiang, C., & Che, S. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201611012 · Cited by 25 · see citing works
The Synthesis of Mesoporous Molecular Sieves
(2007) · Studies in surface science and catalysis · doi:10.1016/s0167-2991(07)80796-8 · Cited by 25 · see citing works
Renker, S., Mahajan, S., Babski, D. T., Schnell, I., Jain, A., Gutmann, J. S., Zhang, Y., Gruner, S. M., Spiess, H. W., & Wiesner, U. B. (2004) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200300249 · Cited by 24 · see citing works
Magbitang, T., Lee, V. Y., Cha, J. N., Wang, H. V., Chung, W. R., Miller, R. D., Dubois, G., Volksen, W., Kim, H., & Hedrick, J. L. (2005) · Angewandte Chemie · doi:10.1002/ange.200501577 · Cited by 24 · see citing works
Betulin Self‐Assembly: From High Axial Aspect Crystals to Hedgehog Suprastructures
Niu, X., Foster, E. J., Patrick, B. O., & Rojas, O. J. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202206058 · Cited by 23 · see citing works
Sol–gel derived mesoporous silica films using amphiphilic triblock copolymers
Kitazawa, N., Namba, H., Aono, M., & Watanabe, Y. (2003) · Journal of Non-Crystalline Solids · doi:10.1016/j.jnoncrysol.2003.09.007 · Cited by 23 · see citing works
Sakai, K., Smith, E. G., Webber, G. B., Baker, M. V., Wanless, E. J., Bütün, V., Armes, S. P., & Biggs, S. (2007) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2007.06.018 · Cited by 22 · see citing works
Krins, N., Bass, J. D., Grosso, D., Henrist, C., Delaigle, R., Gaigneaux, É. M., Cloots, R., Vertruyen, B., & Sánchez, C. (2011) · Chemistry of Materials · doi:10.1021/cm103481n · Cited by 21 · see citing works
Chu, W., Chiang, S.-F., Li, J., & Kuo, S. (2013) · RSC Advances · doi:10.1039/c3ra45348k · Cited by 21 · see citing works
Han, T., Choi, Y., Na, K. M., Kim, M. H., & Jo, H. (2021) · International Journal of Heat and Mass Transfer · doi:10.1016/j.ijheatmasstransfer.2021.121710 · Cited by 20 · see citing works
Kang, H., Sui, L., Wang, Y.-T., Zhang, S., Dong, H., Yu, L., & Dong, L. (2017) · Journal of The Electrochemical Society · doi:10.1149/2.0641712jes · Cited by 20 · see citing works
Preparation of aqueous gel beads coated by lipid bilayers
Campbell, A. L., Taylor, P., Cayre, O. J., & Paunov, V. N. (2004) · Chemical Communications · doi:10.1039/b406941b · Cited by 19 · see citing works
Kimura, T. (2011) · Chemistry – An Asian Journal · doi:10.1002/asia.201100173 · Cited by 17 · see citing works
Li, J., Chang, Y.-H., Lin, Y., & Kuo, S. (2012) · RSC Advances · doi:10.1039/c2ra22048b · Cited by 17 · see citing works
Ordered Hydrophobic Organosilicates Templated by Block Copolymers
Shu, Y., Horibe, Y., Chen, C., Mirau, P. A., Tatry, T., Evans, P. G., Grazul, J. L., & Đufresne, E. M. (2002) · Chemistry of Materials · doi:10.1021/cm0207503 · Cited by 17 · see citing works
Wu, J., Li, H., Wu, S., Huang, G., Xing, W., Tang, M., & Fu, Q. (2014) · The Journal of Physical Chemistry B · doi:10.1021/jp410604a · Cited by 15 · see citing works
Hybrid Titania Microspheres of Novel Superstructures Templated by Block Copolymers
Zhang, Y., Tan, H., Li, H., Liu, Y., Kartawidjaja, F. C., Yang, Z., & Wang, J. (2011) · Chemistry of Materials · doi:10.1021/cm103236d · Cited by 15 · see citing works
Yu, R., & Zheng, S. (2015) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.5b01435 · Cited by 15 · see citing works
Liu, C., Deng, Y., Jia Liu, B., Wu, H., & Zhao, D. (2008) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2008.05.043 · Cited by 15 · see citing works
Sakai, K., Smith, E. G., Webber, G. B., Wanless, E. J., Bütün, V., Armes, S. P., & Biggs, S. (2006) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2006.07.077 · Cited by 14 · see citing works
Nguyen, T. T. T., Kundan, A., Wayner, P., Plawsky, J. L., Chao, D. F., & Sicker, R. J. (2016) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2016.10.082 · Cited by 13 · see citing works
Li, X., Wang, Z., Hong, C., Feng, F., Yu, K., & Liu, H. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c01535 · Cited by 12 · see citing works
Self-citationNitrocellulose templated hierarchical pore structure in mesoporous thin films
Li, X. S., Fryxell, G. E., Wang, C., & Young, J. (2005) · Inorganic Chemistry Communications · doi:10.1016/j.inoche.2005.09.014 · Cited by 12 · see citing works
Formation of Single-Digit Nanometer Scale Silica Nanoparticles by Evaporation-Induced Self-Assembly
Sakamoto, S., Yoshikawa, M., Ozawa, K., Kuroda, Y., Shimojima, A., & Kuroda, K. (2017) · Langmuir · doi:10.1021/acs.langmuir.7b04042 · Cited by 12 · see citing works
General Synthesis and Physico-chemical Properties of Mesoporous Materials
Ha, C., & Park, S. S. (2018) · Springer series in materials science · doi:10.1007/978-981-13-2959-3_2 · Cited by 12 · see citing works
Cao, L., Dong, H., Huang, L., Matyjaszewski, K. A., & Kruk, M. (2009) · Adsorption · doi:10.1007/s10450-009-9165-x · Cited by 12 · see citing works
Li, X. S., Fryxell, G. E., Wang, C., & Young, J. S. (2006) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2006.09.037 · Cited by 10 · see citing works
Wu, X., Yu, K., Brinker, C. J., & Ripmeester, J. A. (2003) · Langmuir · doi:10.1021/la034309i · Cited by 10 · see citing works
Self-citationChu, W., Lin, C.-X., & Kuo, S. (2014) · RSC Advances · doi:10.1039/c4ra11569d · Cited by 9 · see citing works
Huang, M., Li, L., & Zheng, S. (2015) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2015.12.008 · Cited by 9 · see citing works
He, G., Wang, P., Feng, K. M., Dong, H., Zhao, H., Sun, F., Yin, H., Li, W., & Li, G. (2021) · Macromolecules · doi:10.1021/acs.macromol.0c02435 · Cited by 9 · see citing works
Mao, W., Cao, X., Sheng, Q., Han, L., & Che, S. (2017) · Angewandte Chemie · doi:10.1002/ange.201704639 · Cited by 8 · see citing works
Controlling the Periodically Ordered Nanostructures in Ceramics: A Macromolecule‐Guided Strategy
Guo, Q., Zhang, B., Feng, X., Yan, X., Su, Z., Cheng, S. Z. D., & Yue, K. (2019) · Macromolecular Rapid Communications · doi:10.1002/marc.201900534 · Cited by 8 · see citing works
- Authors
- Yu, K., Hurd, A. J., Eisenberg, A., & Brinker, C. J.
- Affiliations
- Los Alamos National Laboratory (US)
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-12-01
- Volume
- 17
- Issue
- 26
- Pages
- 7961-7965
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2063902646
- Cited by
- 129
- References
- 29
- Citations by year
- 2023: 1 · 2022: 3 · 2021: 2 · 2020: 3 · 2019: 2 · 2018: 2 · 2017: 11 · 2016: 6 · 2015: 5 · 2014: 5 · 2013: 14 · 2012: 5
- FWCI
- 6.47
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Langmuir (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- evaporation-induced self-assembly, amphiphilic diblock copolymers, polystyrene-block-poly(ethylene oxide), mesoporous silica, liquid crystalline mesophases, lamellar mesophase, mesopore formation, high glass transition temperature, block copolymer self-assembly
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
