Stress relaxation in the lamellar copolymer mesophase
Abstract
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStress relaxation in the lamellar copolymer mesophaseT. A. Witten, L. Leibler, and P. A. PincusCite this: Macromolecules 1990, 23, 3, 824–829Publication Date (Print):February 1, 1990Publication History Published online1 May 2002Published inissue 1 February 1990https://pubs.acs.org/doi/10.1021/ma00205a022https://doi.org/10.1021/ma00205a022research-articleACS PublicationsRequest reuse permissionsArticle Views762Altmetric-Citations186LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
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It is energetically favourable for two swollen brushes on initial compression to become less swollen and denser than to interpenetrate each other.
“This occurs because, as a result of entropic factors, the opposing brush molecules interpenetrate only very weakly when compressed [20, 26, 27]: It is energetically favourable for two swollen brushes on initial compression to become less swollen and denser than to interpenetrate each other.”
From Hydration lubrication (2013) · cites this paper as [27]
At highest compressions (D < ca. Rg), the entropic effect suppressing interpenetration becomes negligible.
“At the highest compressions, however, when the surface separation becomes comparable with or smaller than the radius of gyration of the polymer chains ( D < ca. R g ), one expects the entropic effect suppressing the interpenetration to become negligible [20, 27].”
From Hydration lubrication (2013) · cites this paper as [27]
The thickness d of the overlapped region of two brushes in the moderate compression regime varies only very weakly with compression.
“It may be shown [20, 27] that the thickness d of the overlapped region of the two brushes in the moderate compression regime varies only very weakly with the compression:”
From Hydration lubrication (2013) · cites this paper as [27]
Opposing brush molecules interpenetrate only very weakly when compressed, due to entropic factors.
“This occurs because, as a result of entropic factors, the opposing brush molecules interpenetrate only very weakly when compressed [20, 26, 27]: It is energetically favourable for two swollen brushes on initial compression to become less swollen and denser than to interpenetrate each other.”
From Hydration lubrication (2013) · cites this paper as [27]
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- Authors
- Witten, T. A., Leibler, L., & Pincus, P. A.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 1990-02
- Volume
- 23
- Issue
- 3
- Pages
- 824-829
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W1969284695
- Cited by
- 202
- References
- 0
- Citations by year
- 2026: 2 · 2025: 3 · 2023: 2 · 2022: 3 · 2021: 4 · 2020: 4 · 2019: 4 · 2018: 7 · 2017: 5 · 2016: 6 · 2015: 3 · 2014: 2 · 2013: 9 · 2012: 7
- FWCI
- 3.94
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecules (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Liquid Crystal Research Advancements
- Physical Sciences › Materials Science › Materials Chemistry › Material Dynamics and Properties
- Keywords
- stress relaxation, block copolymers, lamellar phase, polymer blends, viscoelasticity, order-disorder transition
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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