Thermodynamics and Crystallization of Random Copolymers

Closed-loop recycling of polyethylene-like materials

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From Lactic Acid to Poly(lactic acid) (PLA): Characterization and Analysis of PLA and Its Precursors

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Long-Chain Aliphatic Polymers To Bridge the Gap between Semicrystalline Polyolefins and Traditional Polycondensates

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Solid-State Microstructures, Thermal Properties, and Crystallization of Biodegradable Poly(butylene succinate) (PBS) and Its Copolyesters

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Crystallization of biodegradable and biobased polyesters: Polymorphism, cocrystallization, and structure-property relationship

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Crystallization analysis fractionation: A new technique for the analysis of branching distribution in polyolefins

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Synthesis, Cocrystallization, and Enzymatic Degradation of Novel Poly(butylene-co-propylene succinate) Copolymers

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On the Role of Single Regiodefects and Polydispersity in Regioregular Poly(3-hexylthiophene): Defect Distribution, Synthesis of Defect-Free Chains, and a Simple Model for the Determination of Crystallinity

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Synthesis and Deconstruction of Polyethylene-type Materials

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Influence of composition and molecular mass on the morphology, crystallization and melting behaviour of poly(ethylene oxide)/poly(methyl methacrylate) blends

Martuscelli, E., Pracellà, M., & Wang, P. Y. (1984) · Polymer · doi:10.1016/0032-3861(84)90346-x · Cited by 189 · see citing works

Crystallization and Microstructure of Poly(<scp>l</scp>-lactide-<i>co</i>-<i>meso</i>-lactide) Copolymers

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Isotacticity effect on crystallization and melting in polypropylene fractions: 1. Crystalline structures and thermodynamic property changes

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Melting studies of poly(vinylidene fluoride) and its blends with poly(methyl methacrylate)

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Influence of α′-/α-crystal polymorphism on properties of poly(l-lactic acid)

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Crystallization and Solid-State Structure of Random Polylactide Copolymers:  Poly(<scp>l</scp>-lactide-<i>co</i>-<scp>d</scp>-lactide)s

Baratian, S., Hall, E. S., Lin, J. S., Xu, R., & Runt, J. (2001) · Macromolecules · doi:10.1021/ma001125r · Cited by 148 · see citing works

Influence of Crystallization Conditions on the Microstructure and Electromechanical Properties of Poly(vinylidene fluoride−trifluoroethylene−chlorofluoroethylene) Terpolymers

Klein, R. J., Runt, J. P., & Zhang, Q. (2003) · Macromolecules · doi:10.1021/ma034745b · Cited by 138 · see citing works

Strain crystallization in random copolymers produced by epoxidation of cis 1,4-polyisoprene

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Chemically Recyclable Ester-Linked Polypropylene

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Morphological Partitioning of Ethylene Defects in Random Propylene−Ethylene Copolymers

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Geometrical limits to order in liquid crystalline random copolymers

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Structure and structure formation of a main chain thermotropic polymer

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Poly(ethylene furanoate-co-ethylene terephthalate) biobased copolymers: Synthesis, thermal properties and cocrystallization behavior

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Microstructures and Dielectric Properties of the Ferroelectric Fluoropolymers Synthesized via Reductive Dechlorination of Poly(vinylidene fluoride-co-chlorotrifluoroethylene)s

Lü, Y., Claude, J., Zhang, Q., et al. (2006) · Macromolecules · doi:10.1021/ma061311i · Cited by 113 · see citing works

Control of Crystallization and Melting Behavior in Sequence Specific Polypeptoids

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Long-Spaced Aliphatic Polyesters

Ortmann, P., & Mecking, S. (2013) · Macromolecules · doi:10.1021/ma401305u · Cited by 111 · see citing works

Crystallization and Melting of Model Ethylene−Butene Copolymers

Crist, B., & Howard, P. R. (1999) · Macromolecules · doi:10.1021/ma9816362 · Cited by 110 · see citing works

Crystallization of isodimorphic aliphatic random copolyesters: Pseudo-eutectic behavior and double-crystalline materials

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Structure and melting of perfectly alternating ethylene‐carbon monoxide copolymers

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The influence of chain structure on the equilibrium melting temperature of poly(vinylidene fluoride)

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Modeling the Cloud Curves and the Solubility of Gases in Amorphous and Semicrystalline Polyethylene with the SAFT-VR Approach and Flory Theory of Crystallization

Paricaud, P., Galindo, A., & Jackson, G. (2004) · Industrial & Engineering Chemistry Research · doi:10.1021/ie049592a · Cited by 93 · see citing works

Crystallization Behavior and Mechanical Properties of Regiodefective, Highly Stereoregular Isotactic Polypropylene: Effect of Regiodefects versus Stereodefects and Influence of the Molecular Mass

Rosa, C. D., Auriemma, F., Paolillo, M., Resconi, L., & Camurati, I. (2005) · Macromolecules · doi:10.1021/ma051004x · Cited by 90 · see citing works

Effect of comonomer type on the crystallization kinetics and crystalline structure of random isotactic propylene 1-alkene copolymers

Jeon, K., Palza, H., Quijada, R., et al. (2008) · Polymer · doi:10.1016/j.polymer.2008.10.032 · Cited by 90 · see citing works

Structural Transition of Lamella Crystals in a Isomorphous Copolymer, Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)

Yoshie, N., Saito, M., & Inoue, Y. (2001) · Macromolecules · doi:10.1021/ma0113071 · Cited by 87 · see citing works

Biobased poly(ethylene furanoate-co-ethylene succinate) copolyesters: solid state structure, melting point depression and biodegradability

Terzopoulou, Z. N., Tsanaktsis, V., Bikiaris, D. Ν., Exarhopoulos, S., Papageorgiou, D. G., & Papageorgiou, G. Z. (2016) · RSC Advances · doi:10.1039/c6ra15994j · Cited by 86 · see citing works

Crystallinity in chemically crosslinked low density polyethylenes: 1. Structural and fusion studies

Kao, Y. H., & Phillips, P. J. (1986) · Polymer · doi:10.1016/0032-3861(86)90260-0 · Cited by 86 · see citing works

Polymorphic Transformation in Isotactic 1-Butene/Ethylene Copolymers

Azzurri, F., Alfonso, G. C., Gómez‐Fatou, M. A., et al. (2004) · Macromolecules · doi:10.1021/ma0358327 · Cited by 85 · see citing works

Crystal thickness distributions from melting homopolymers or random copolymers

Crist, B., & Mirabella, F. M. (1999) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/(sici)1099-0488(19991101)37:21 · Cited by 85 · see citing works

Physical properties and hydrolytic degradability of polyethylene-like polyacetals and polycarbonates

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Crystallization, melting and morphology of syndiotactic polypropylene fractions: 1. Thermodynamic properties, overall crystallization and melting

Rodriguez-Arnold, J., Zhang, A., Cheng, S. Z. D., Lovinger, A. J., Hsieh, E. T., Chu, P., Johnson, T. W., Honnell, K. G., Geerts, R. G., Palackal, S. J., et al. (1994) · Polymer · doi:10.1016/0032-3861(94)90978-4 · Cited by 82 · see citing works

Novel Poly(propylene terephthalate-co-succinate) Random Copolymers: Synthesis, Solid Structure, and Enzymatic Degradation Study

Papageorgiou, G. Z., Vassiliou, A. A., Karavelidis, V., Koumbis, A. E., & Bikiaris, D. Ν. (2008) · Macromolecules · doi:10.1021/ma702508m · Cited by 80 · see citing works

Phase Structure and Crystallization Behavior of Polypropylene in-Reactor Alloys: Insights from Both Inter- and Intramolecular Compositional Heterogeneity

Zhu, H., Monrabal, B., Han, C. C.-C., et al. (2007) · Macromolecules · doi:10.1021/ma702324h · Cited by 79 · see citing works

Crystal nucleation in random l/d-lactide copolymers

Androsch, R., Lorenzo, M. D. D., & Schick, C. (2016) · European Polymer Journal · doi:10.1016/j.eurpolymj.2016.01.020 · Cited by 71 · see citing works

Closed-Loop Recyclable and Nonpersistent Polyethylene-like Polyesters

Eck, M., & Mecking, S. (2024) · Accounts of Chemical Research · doi:10.1021/acs.accounts.3c00811 · Cited by 80 · see citing works

Effect of the Sequence Length Distribution on the Lamellar Crystal Thickness and Thickness Distribution of Polyethylene: Perfectly Equisequential ADMET Polyethylene vs Ethylene/α-Olefin Copolymer.

Hosoda, S., Nozue, Y., Kawashima, Y., et al. (2010) · Macromolecules · doi:10.1021/ma102072p · Cited by 78 · see citing works

A New Model Describing the Cocrystallization Behavior of Random Copolymers

Wendling, J., & Suter, U. W. (1998) · Macromolecules · doi:10.1021/ma971506d · Cited by 78 · see citing works

Biosynthesis and characterization of hydroxybutyrate-hydroxycaproate copolymers

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Linear growth rates of random propylene ethylene copolymers. The changeover from γ dominated growth to mixed (α+γ) polymorphic growth

Alamo, R. G., Ghosal, A., Chatterjee, J., & Thompson, K. L. (2005) · Polymer · doi:10.1016/j.polymer.2005.02.128 · Cited by 73 · see citing works

Effect of titania nanoparticles on the morphology of low density polyethylene

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Crystallinity in chemically crosslinked low density polyethylenes: 2. Crystallization kinetics

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Kinetics of Nucleation and Growth of Crystals of Poly(l-lactic acid)

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Correlation of the melting behavior and copolymer composition distribution of Ziegler–Natta‐catalyst and single‐site‐catalyst polyethylene copolymers

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The melting point of chain polymers

Hu, W. (2000) · The Journal of Chemical Physics · doi:10.1063/1.1288002 · Cited by 65 · see citing works

Effect of Regioregularity on the Semicrystalline Structure of Poly(3-hexylthiophene)

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Cocrystallization Behavior of Poly(butylene terephthalate-co-butylene 2,6-naphthalate) Random Copolymers

Jeong, Y. G., Jo, W. H., & Lee, S. C. (2000) · Macromolecules · doi:10.1021/ma000040n · Cited by 62 · see citing works

Crystallization behaviour of poly(butylene succinate) copolymers

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Crystallization kinetics and melting of caprolactone random copolymers

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Thermodynamics of statistical copolymer melting

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Structural analysis of random propylene-ethylene copolymers

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High‐Density Polyethylene with In‐Chain Photolyzable and Hydrolyzable Groups Enabling Recycling and Degradation

Baur, M., Mast, N. K., Brahm, J. P., Habé, R., Morgen, T. O., & Mecking, S. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202310990 · Cited by 62 · see citing works

Miscibility and competition of cocrystallization behavior of poly(hexamethylene dicarboxylate)s aliphatic copolyesters: Effect of chain length of aliphatic diacids

Yu, Y., Wei, Z., Zhou, C. Y., Zheng, L., Leng, X., & Li, Y. (2017) · European Polymer Journal · doi:10.1016/j.eurpolymj.2017.04.036 · Cited by 58 · see citing works

Modification of the thermal properties and crystallization behaviour of poly(ethylene terephthalate) by copolymerization

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Effect of co-unit type in random propylene copolymers on the kinetics of mesophase formation and crystallization

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Crystallization of Polyethylenes Containing Chlorines: Precise vs Random Placement

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Kinetics of the melt – Form II phase transition in isotactic random butene-1/ethylene copolymers

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Effect of random copolymerization on growth transition and morphology change in polypropylene

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Maximum Rate of Crystallization and Morphology of Random Propylene Ethylene Copolymers as a Function of Comonomer Content up to 21 mol %

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Effect of Sequence Distribution on the Morphology, Crystallization, Melting, and Biodegradation of Poly(ε-caprolactone-co-ε-caprolactam) Copolymers

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Unique isodimorphism and isomorphism behaviors of even-odd poly(hexamethylene dicarboxylate) aliphatic copolyesters

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Effect of comonomer partitioning on the kinetics of mesophase formation in random copolymers of propene and higher α-olefins

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Long-Spaced Polyketones from ADMET Copolymerizations as Ideal Models for Ethylene/CO Copolymers

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Effect of crystallization temperature on the cocrystallization of hydroxybutyrate/hydroxyvalerate copolymers

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Upcycling polyethylene into closed-loop recyclable polymers through titanosilicate catalyzed C-H oxidation and in-chain heteroatom insertion

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Study on the crystallization of poly(butylene azelate-co-butylene succinate) copolymers

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Structure formation of random isotactic copolymers of propylene and 1-hexene or 1-octene at rapid cooling

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Density and crystallinity of poly (3-hydroxybutyrate/3-hydroxyvalerate) copolymers

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Novel eco-friendly random copolyesters of poly(butylene succinate) containing ether-linkages

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Structural changes of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) fractionated with acetone-water solution

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Phase Transitions of Bulk Statistical Copolymers Studied by Dynamic Monte Carlo Simulations

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Tensile properties of random copolymers of propylene with ethylene and 1-butene: effect of crystallinity and crystal habit

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Stress-Induced Polymorphic Transformations and Mechanical Properties of Isotactic Propylene-Hexene Copolymers

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Enzymatic Synthesis and Structural and Thermal Properties of Poly(ω-pentadecalactone-co-butylene-co-succinate)

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Effect of cooling rate on melt-crystallization of random propylene-ethylene and propylene-1-butene copolymers

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Crystalline Phase of Isomorphic Poly(hexamethylene sebacate-co-hexamethylene adipate) Copolyester: Effects of Comonomer Composition and Crystallization Temperature

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Isothermal and non-isothermal crystallization kinetics of hydroxyl-functionalized polypropylene

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Fully Aliphatic Copolyesters Based on Poly(butylene 1,4-cyclohexanedicarboxylate) with Promising Mechanical and Barrier Properties for Food Packaging Applications

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Isomorphic crystallization of aliphatic copolyesters derived from 1,6-hexanediol: Effect of the chemical structure of comonomer units on the extent of cocrystallization

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Synthesis and Properties of Novel Biodegradable/Biocompatible Poly[propylene‐co‐(ethylene succinate)] Random Copolyesters

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Predicting the Cocrystallization Behavior of Random Copolymers via Free Energy Calculations

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Tailoring the isothermal crystallization kinetics of isodimorphic poly (butylene succinate-ran-butylene azelate) random copolymers by changing composition

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Propylene–Butene Copolymers: Tailoring Mechanical Properties from Isotactic Polypropylene to Polybutene

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Effect of thermal and solution history on the Curie point of VF2-TrFE random copolymers

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Degradable high-molecular-weight random copolymers, based on ε-caprolactone and 1,5-dioxepan-2-one, with non-crystallizable units inserted in the crystalline structure

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Co-crystallization of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)

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Crystallization of poly(butylene-2,6-naphthalate-co-butylene adipate) copolymers: regulating crystal modification of the polymorphic parent homopolymers and biodegradation

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Crystallization and Melting of Model Ethylene-Butene Random Copolymers: Thermal Studies

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Effect of the Crystallization Conditions on the Exclusion/Inclusion Balance in Biodegradable Poly(butylene succinate-ran-butylene adipate) Copolymers

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Cocrystallization behavior of poly(hexamethylene terephthalate-co-hexamethylene 2,6-naphthalate) random copolymers

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