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The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.

Polytriazoles with Aggregation-Induced Emission Characteristics: Synthesis by Click Polymerization and Application as Explosive Chemosensors

Qin, Anjun, Lam, Jacky W. Y., Tang, Li, Jim, Cathy K. W., Zhao, Hui, Sun, Jingzhi, Tang, Ben Zhong·2009·Macromolecules

Abstract

Tetraphenylethene (TPE)-containing polytriazoles (P3) with high molecular weights in high yields was synthesized by the Cu(I)-catalyzed click polymerization of diyne with diazides. The diyne and diazide monomers, namely 1,4-bis(propargyloxy) benzene (1), 1,2-bis[4-(azidohexyloxy)phenyl]-1,2- diphenylethene (2a), and 1,2-bis[(4-azidomethyl)phenyl]-1,2-diphenylethene (2b), were synthesized. The monomer structures were confirmed by spectroscopic analyses. The click polymerization in organic media using an organosoluble catalyst of Cu(PPh3)3Br. Utilizing the novel AIE effect, the polytriazoles are used as chemosensors for the detection of explosives in the aggregate and solid states. The emission quenching is observed at a concentration as low as 0.1 μg/mL or 0.1 ppm. The changes in the φF values of P3 in the aqueous mixtures with different water fractions further confirm the AIE characteristics of the polymers.

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Metadata

Authors
Qin, A., Lam, J. W. Y., Tang, L., Jim, C. K. W., Zhao, H., Sun, J., & Tang, B. Z.
Venue
Macromolecules
Published
2009-02-04
Volume
42
Issue
5
Pages
1421-1424
ISSN
  • 0024-9297 (ISSN-L)
  • 1520-5835
OpenAlex
W2062933471
Cited by
245
References
4
FWCI
11.48
Type
journal article
Language
en
Open access
closed

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