The DOI matches its Crossref record; 17 of the 17 references it cites were found in a registry or an index.
Synthesis of Acrylate and Methacrylate Block Copolymers Using Atom Transfer Radical Polymerization
Abstract
The synthesis of di- and triblock copolymers, involving methyl methacrylate (MMA), butyl acrylate, and methyl acrylate, using copper-based atom transfer radical polymerization (ATRP) is reported. It was found that poly(MMA) macroinitiator is able to initiate the ATRP of acrylic monomers. However, for polyacrylates to effectively initiate the ATRP of MMA, the end group should be a bromine atom and the catalyst CuCl; that is, halogen exchange should take place. ABA-type triblock copolymers, where B = poly(butyl acrylate) and A = poly(methyl methacrylate), were synthesized by growing the center block first using a difunctional initiator and then adding MMA to the ends.
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Self-citationPolymers with Very Low Polydispersities from Atom Transfer Radical Polymerization
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Self-citationThe chemistry of free radical polymerization
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Controlled Radical Polymerization
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Utilizing Halide Exchange To Improve Control of Atom Transfer Radical Polymerization
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Self-citationPercec, V., Barboiu, B., & Kim, H.-J. (1998) · Journal of the American Chemical Society · doi:10.1021/ja9713845 · Cited by 289
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Self-citationSynthesis of Well-Defined Polyacrylonitrile by Atom Transfer Radical Polymerization
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Self-citationKinetic Study of the Homogeneous Atom Transfer Radical Polymerization of Methyl Methacrylate
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Self-citationIntroduction to living polymeriz. Living and/or controlled polymerization
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Cited by
Metal-Catalyzed Living Radical Polymerization
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Controlled/living radical polymerization: Features, developments, and perspectives
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Self-citationControlled/living radical polymerization
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Self-citationSynthesis of Polymer Brushes Using Atom Transfer Radical Polymerization
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Self-citationControlled/Living Radical Polymerization in Dispersed Systems
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Metadata
- Authors
- Shipp, D. A., Wang, J.-L., & Matyjaszewski, K.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 1998-10-21
- Volume
- 31
- Issue
- 23
- Pages
- 8005-8008
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2004727795
- Cited by
- 351
- References
- 17
- FWCI
- 10.32
- Type
- journal article
- Language
- en
- Open access
- closed
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