The DOI matches its Crossref record; 28 of the 28 references it cites were found in a registry or an index.
Arrays of Sealed Silicon Nanotubes As Anodes for Lithium Ion Batteries
Abstract
Silicon is a promising candidate for electrodes in lithium ion batteries due to its large theoretical energy density. Poor capacity retention, caused by pulverization of Si during cycling, frustrates its practical application. We have developed a nanostructured form of silicon, consisting of arrays of sealed, tubular geometries that is capable of accommodating large volume changes associated with lithiation in battery applications. Such electrodes exhibit high initial Coulombic efficiencies (i.e., >85%) and stable capacity-retention (>80% after 50 cycles), due to an unusual, underlying mechanics that is dominated by free surfaces. This physics is manifested by a strongly anisotropic expansion in which 400% volumetric increases are accomplished with only relatively small (<35%) changes in the axial dimension. These experimental results and associated theoretical mechanics models demonstrate the extent to which nanoscale engineering of electrode geometry can be used to advantage in the design of rechargeable batteries with highly reversible capacity and long-term cycle stability.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Issues and challenges facing rechargeable lithium batteries
Tarascon, J.-M., & Armand, M. (2001) · Nature · doi:10.1038/35104644 · Cited by 21,130
Nanostructured materials for advanced energy conversion and storage devices
Aricò, A. S., Bruce, P., Scrosati, B., Tarascon, J.-M., & van Schalkwijk, W. (2005) · Nature Materials · doi:10.1038/nmat1368 · Cited by 8,826
High-performance lithium battery anodes using silicon nanowires
Chan, C. K., Peng, H., Liu, G., McIlwrath, K., Zhang, X. F., Huggins, R. A., & Cui, Y. (2008) · Nature Nanotechnology · doi:10.1038/nnano.2007.411 · Cited by 6,683
Nanomaterials for Rechargeable Lithium Batteries
Bruce, P. G., Scrosati, B., & Tarascon, J. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200702505 · Cited by 5,886
Growth of Arrayed Nanorods and Nanowires of ZnO from Aqueous Solutions
Vayssieres, L. (2003) · Advanced Materials · doi:10.1002/adma.200390108 · Cited by 2,706
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries
Kang, K., Meng, Y. S., Bréger, J., Grey, C. P., & Ceder, G. (2006) · Science · doi:10.1126/science.1122152 · Cited by 2,638
Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells
Kasavajjula, U., Wang, C., & Appleby, A. J. (2007) · Journal of Power Sources · doi:10.1016/j.jpowsour.2006.09.084 · Cited by 2,491
Virus-Enabled Synthesis and Assembly of Nanowires for Lithium Ion Battery Electrodes
Nam, K. T., Kim, D.-W., Yoo, P. J., Chiang, C.-Y., Meethong, N., Hammond, P. T., Chiang, Y.-M., & Belcher, A. M. (2006) · Science · doi:10.1126/science.1122716 · Cited by 1,855
Silicon Nanotube Battery Anodes
Park, M.-H., Kim, M. G., Joo, J., Kim, K., Kim, J., Ahn, S., Cui, Y., & Cho, J. (2009) · Nano Letters · doi:10.1021/nl902058c · Cited by 1,493
Single-crystal gallium nitride nanotubes
Goldberger, J., He, R., Zhang, Y., Lee, S., Yan, H., Choi, H.-J., & Yang, P. (2003) · Nature · doi:10.1038/nature01551 · Cited by 1,247
Cited by
Designing nanostructured Si anodes for high energy lithium ion batteries
Wu, H., & Cui, Y. (2012) · Nano Today · doi:10.1016/j.nantod.2012.08.004 · Cited by 2,350
Review on recent progress of nanostructured anode materials for Li-ion batteries
Goriparti, S., Miele, E., De Angelis, F., Di Fabrizio, E., Proietti Zaccaria, R., & Capiglia, C. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2013.11.103 · Cited by 2,092
Interconnected Silicon Hollow Nanospheres for Lithium-Ion Battery Anodes with Long Cycle Life
Yao, Y., McDowell, M. T., Ryu, I., Wu, H., Liu, N., Hu, L., Nix, W. D., & Cui, Y. (2011) · Nano Letters · doi:10.1021/nl201470j · Cited by 1,456
Synthesis, Properties, and Applications of Hollow Micro-/Nanostructures
Wang, X., Feng, J., Bai, Y., Zhang, Q., & Yin, Y. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00731 · Cited by 1,456
Wu, H., Yu, G., Pan, L., Liu, N., McDowell, M. T., Bao, Z., & Cui, Y. (2013) · Nature Communications · doi:10.1038/ncomms2941 · Cited by 1,378
Silicon‐Based Anodes for Lithium‐Ion Batteries: From Fundamentals to Practical Applications
Feng, K., Li, M., Liu, W., Kashkooli, A. G., Xiao, X., Cai, M., & Chen, Z. (2018) · Small · doi:10.1002/smll.201702737 · Cited by 1,042
Nanomaterials for renewable energy production and storage
Chen, X., Li, C., Grätzel, M., Kostecki, R., & Mao, S. S. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35230c · Cited by 1,015
In Situ TEM of Two-Phase Lithiation of Amorphous Silicon Nanospheres
McDowell, M. T., Lee, S. W., Harris, J. T., Korgel, B. A., Wang, C., Nix, W. D., & Cui, Y. (2013) · Nano Letters · doi:10.1021/nl3044508 · Cited by 869
Liu, J., Zhang, J., Yang, Z., Lemmon, J. P., Imhoff, C., Graff, G. L., Li, L., Hu, J., Wang, C., Xiao, J., et al. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201200690 · Cited by 696
Electrospun Core–Shell Fibers for Robust Silicon Nanoparticle-Based Lithium Ion Battery Anodes
Hwang, T. H., Lee, Y. M., Kong, B.-S., Seo, J.-S., & Choi, J. W. (2012) · Nano Letters · doi:10.1021/nl203817r · Cited by 658
Self-citationRyou, M., Kim, J., Lee, I., Kim, S., Jeong, Y. K., Hong, S., Ryu, J. H., Kim, T., Park, J., Lee, H., et al. (2013) · Advanced Materials · doi:10.1002/adma.201203981 · Cited by 622
Self-citationProspective materials and applications for Li secondary batteries
Jeong, G., Kim, Y.-U., Kim, H., Kim, Y.-J., & Sohn, H.-J. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00831a · Cited by 616
Self-citationThe emerging era of supramolecular polymeric binders in silicon anodes
Kwon, T.-W., Choi, J. W., & Coskun, A. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00858a · Cited by 560
Self-citationN‐Doped Graphene‐SnO2 Sandwich Paper for High‐Performance Lithium‐Ion Batteries
Wang, X., Cao, X., Bourgeois, L., Guan, H., Chen, S., Zhong, Y., Tang, D., Li, H., Zhai, T., Li, L., et al. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201103110 · Cited by 537
Fracture of crystalline silicon nanopillars during electrochemical lithium insertion
Lee, S. W., McDowell, M. T., Berla, L. A., Nix, W. D., & Cui, Y. (2012) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1201088109 · Cited by 432
Toward an Ideal Polymer Binder Design for High-Capacity Battery Anodes
Wu, M., Xiao, X., Vukmirovic, N., Xun, S., Das, P. K., Song, X., Olalde-Velasco, P., Wang, D., Weber, A. Z., Wang, L.-W., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4054465 · Cited by 398
Toward Practical High-Energy and High-Power Lithium Battery Anodes: Present and Future
Wang, C., Yang, C., & Zheng, Z. (2022) · Advanced Science · doi:10.1002/advs.202105213 · Cited by 337
Li, W., Sun, X., & Yu, Y. (2017) · Small Methods · doi:10.1002/smtd.201600037 · Cited by 308
Zhu, J., Yan, C., Zhang, X., Yang, C., Jiang, M., & Zhang, X. (2020) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2019.100788 · Cited by 303
Cu‐Si Nanocable Arrays as High‐Rate Anode Materials for Lithium‐Ion Batteries
Cao, F., Deng, J., Xin, S., Ji, H., Schmidt, O. G., Wan, L., & Guo, Y. (2011) · Advanced Materials · doi:10.1002/adma.201102062 · Cited by 301
Bhatt, M. D., & O'Dwyer, C. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp05552g · Cited by 300
Silicon Anode Design for Lithium-Ion Batteries: Progress and Perspectives
Franco Gonzalez, A., Yang, N.-H., & Liu, R.-S. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b07793 · Cited by 284
Wang, C.-M., Li, X., Wang, Z., Xu, W., Liu, J., Gao, F., Kovarik, L., Zhang, J.-G., Howe, J., Burton, D. J., et al. (2012) · Nano Letters · doi:10.1021/nl204559u · Cited by 277
Li, X., Wu, Y., Hang, L., Men, D., Cai, W., & Li, Y. (2015) · Journal of Materials Chemistry C · doi:10.1039/c4tc02228a · Cited by 19
Metadata
- Authors
- Song, T., Xia, J., Lee, J.-H., Lee, D. H., Kwon, M.-S., Choi, J.-M., Wu, J., Doo, S. K., Chang, H., Park, W. I., Zang, D. S., Kim, H., Huang, Y., Hwang, K.-C., Rogers, J. A., & Paik, U.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-04-06
- Volume
- 10
- Issue
- 5
- Pages
- 1710-1716
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2119608471
- Cited by
- 894
- References
- 28
- FWCI
- 54.07
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
