The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Synthetic and Structural Studies of (NHC)Pd(allyl)Cl Complexes (NHC =N-heterocyclic carbene)
Abstract
The synthesis and structural characterization of a series of palladium complexes bearing N -heterocyclic carbenes (NHC) as supporting ligands are described. The reaction of commercially available [Pd(allyl)Cl] 2 and isolated or in situ generated NHC leads to monomeric palladium complexes where one NHC is bound to the metal center, as indicated by spectroscopic and single-crystal X-ray diffraction studies. The relative reactivity trend for these complexes as catalysts in aryl amination is discussed in terms of ligand steric properties, which vary as a function of imidazole-nitrogen substituents and perturbation resulting in modulation of ring planarity. The concept of buried volume is used to quantify the steric demand of each NHC in the corresponding complexes.
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Cites
Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis
Tolman, C. A. (1977) · Chemical Reviews · doi:10.1021/cr60307a002 · Cited by 4,824
The Development of L2X2RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story
Trnka, T. M., & Grubbs, R. H. (2001) · Accounts of Chemical Research · doi:10.1021/ar000114f · Cited by 3,561
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The organometallic chemistry of the transition metals
(2001) · Choice Reviews Online · doi:10.5860/choice.38-6192 · Cited by 1,719
Hillier, A. C., Sommer, W. J., Yong, B. S., Petersen, J. L., Cavallo, L., & Nolan, S. P. (2003) · Organometallics · doi:10.1021/om034016k · Cited by 480
Self-citationPoppe, L., & Van Halbeek, H. (1991) · Journal of the American Chemical Society · doi:10.1021/ja00001a055 · Cited by 200
Dorta, R., Stevens, E. D., Hoff, C. D., & Nolan, S. P. (2003) · Journal of the American Chemical Society · doi:10.1021/ja0362151 · Cited by 184
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Cited by
Phan, N. T. S., Van Der Sluys, M., & Jones, C. W. (2006) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.200505473 · Cited by 1,905
Kantchev, E. A. B., O'Brien, C. J., & Organ, M. G. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200601663 · Cited by 1,616
The Measure of All Rings—N‐Heterocyclic Carbenes
Dröge, T., & Glorius, F. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201001865 · Cited by 1,240
Díez-González, S., & Nolan, S. P. (2007) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2006.10.004 · Cited by 939
Self-citationN-Heterocyclic Carbenes in Materials Chemistry
Smith, C. A., Narouz, M. R., Lummis, P. A., Singh, I., Nazemi, A., Li, C.-H., & Crudden, C. M. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00514 · Cited by 695
Metadata
- Authors
- Viciu, M. S., Navarro, O., Germaneau, R. F., Kelly, R. A., Sommer, W., Marion, N., Stevens, E. D., Cavallo, L., & Nolan, S. P.
- Venue
- Organometallics
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-02-25
- Volume
- 23
- Issue
- 7
- Pages
- 1629-1635
- ISSN
- 0276-7333 (ISSN-L)
- 1520-6041
- OpenAlex
- W2000263995
- Cited by
- 321
- References
- 7
- FWCI
- 12.92
- Type
- journal article
- Language
- en
- Open access
- closed
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- Viciu, M. S., Navarro, O., Germaneau, R. F., Kelly, R. A., Sommer, W., Marion, N., Stevens, E. D., Cavallo, L., & Nolan, S. P. (2004). Synthetic and Structural Studies of (NHC)Pd(allyl)Cl Complexes (NHC =N-heterocyclic carbene). Organometallics. https://doi.org/10.1021/om034319e
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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