The DOI matches its Crossref record; 72 of the 72 references it cites were found in a registry or an index.
Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex
Abstract
The PNP-ligated iridium(III) trihydride complex 1 exhibited the highest catalytic activity for hydrogenation of carbon dioxide in aqueous KOH. The catalytic hydrogenation can be tuned to be a reversible process with the same catalyst at the expense of the activity, when triethanolamine was used as a base. Theoretical studies on the hydrogenation of carbon dioxide using DFT calculations suggested two competing reaction pathways: either the deprotonative dearomatization step or the hydrogenolysis step as the rate-determining step. The results nicely explain our experimental observations that the catalytic cycle is dependent on both the strength of the base and hydrogen pressure.
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Cites
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Cited by
Wang, W.-H., Himeda, Y., Muckerman, J. T., Manbeck, G. F., & Fujita, E. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00197 · Cited by 1,507
Bond Activation and Catalysis by Ruthenium Pincer Complexes
Gunanathan, C., & Milstein, D. (2014) · Chemical Reviews · doi:10.1021/cr5002782 · Cited by 958
Mellmann, D., Sponholz, P., Junge, H., & Beller, M. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00618j · Cited by 872
Hydrogen energy future with formic acid: a renewable chemical hydrogen storage system
Singh, A. K., Singh, S., & Kumar, A. (2016) · Catalysis Science & Technology · doi:10.1039/c5cy01276g · Cited by 543
Kang, P., Cheng, C., Chen, Z., Schauer, C. K., Meyer, T. J., & Brookhart, M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja300543s · Cited by 330
Metadata
- Authors
- Tanaka, R., Yamashita, M., Chung, L. W., Morokuma, K., & Nozaki, K.
- Venue
- Organometallics
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-11-30
- Volume
- 30
- Issue
- 24
- Pages
- 6742-6750
- ISSN
- 0276-7333 (ISSN-L)
- 1520-6041
- OpenAlex
- W2324462072
- Cited by
- 317
- References
- 72
- FWCI
- 10.37
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tanaka, R., Yamashita, M., Chung, L. W., Morokuma, K., & Nozaki, K. (2011). Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex. Organometallics. https://doi.org/10.1021/om2010172
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
