The DOI matches its Crossref record; 30 of the 30 references it cites were found in a registry or an index.
Selective Electrocatalytic Reduction of CO2 to Formate by Water-Stable Iridium Dihydride Pincer Complexes
Abstract
Iridium dihydride complexes supported by PCP-type pincer ligands rapidly insert CO(2) to yield κ(2)-formate monohydride products in THF. In acetonitrile/water mixtures, these complexes become efficient and selective catalysts for electrocatalytic reduction of CO(2) to formate. Electrochemical and NMR spectroscopic studies have provided mechanistic details and structures of key intermediates.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
The teraton challenge. A review of fixation and transformation of carbon dioxide
Mikkelsen, M., Jørgensen, M., & Krebs, F. C. (2010) · Energy Environ. Sci. · doi:10.1039/b912904a · Cited by 2,157
Electrocatalytic and homogeneous approaches to conversion of CO2to liquid fuels
Benson, E. E., Kubiak, C. P., Sathrum, A. J., & Smieja, J. M. (2009) · Chem. Soc. Rev. · doi:10.1039/b804323j · Cited by 2,059
Chemical approaches to artificial photosynthesis
Meyer, T. J. (1989) · Accounts of Chemical Research · doi:10.1021/ar00161a001 · Cited by 1,360
Self-citationCatalytic Hydrogenation of Carbon Dioxide Using Ir(III)−Pincer Complexes
Tanaka, R., Yamashita, M., & Nozaki, K. (2009) · Journal of the American Chemical Society · doi:10.1021/ja903574e · Cited by 902
Rice, C., Ha, S., Masel, R. I., Waszczuk, P., Wieckowski, A., & Barnard, T. (2002) · Journal of Power Sources · doi:10.1016/s0378-7753(02)00271-9 · Cited by 824
Carbon Dioxide as a Raw Material: The Synthesis of Formic Acid and Its Derivatives from CO2
Leitner, W. (1995) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199522071 · Cited by 797
Recent advances in the homogeneous hydrogenation of carbon dioxide
Jessop, P. G., Joó, F., & Tai, C.-C. (2004) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2004.05.019 · Cited by 741
Homogeneous catalytic hydrogenation of supercritical carbon dioxide
Jessop, P. G., Ikariya, T., & Noyori, R. (1994) · Nature · doi:10.1038/368231a0 · Cited by 720
Hydrogen generation from formic acid and alcohols using homogeneous catalysts
Johnson, T. C., Morris, D. J., & Wills, M. (2010) · Chem. Soc. Rev. · doi:10.1039/b904495g · Cited by 660
Bourrez, M., Molton, F., Chardon‐Noblat, S., & Deronzier, A. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201103616 · Cited by 590
Cited by
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
Cocatalysts for Selective Photoreduction of CO2into Solar Fuels
Li, X., Yu, J., Jaroniec, M., & Chen, X. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00400 · Cited by 2,304
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Wang, W.-H., Himeda, Y., Muckerman, J. T., Manbeck, G. F., & Fujita, E. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00197 · Cited by 1,507
Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide
Kornienko, N., Zhao, Y., Kley, C. S., Zhu, C., Kim, D., Lin, S., Chang, C. J., Yaghi, O. M., & Yang, P. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08212 · Cited by 1,158
Metadata
- Authors
- Kang, P., Cheng, C., Chen, Z., Schauer, C. K., Meyer, T. J., & Brookhart, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-03-14
- Volume
- 134
- Issue
- 12
- Pages
- 5500-5503
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1965587829
- Cited by
- 330
- References
- 30
- FWCI
- 9.60
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Selective Electrocatalytic Reduction of CO2 to Formate by Water-Stable Iridium Dihydride Pincer Complexes. https://app.cochat.ai/papers/10.1021/ja300543s
- The paper
- Kang, P., Cheng, C., Chen, Z., Schauer, C. K., Meyer, T. J., & Brookhart, M. (2012). Selective Electrocatalytic Reduction of CO2 to Formate by Water-Stable Iridium Dihydride Pincer Complexes. Journal of the American Chemical Society. https://doi.org/10.1021/ja300543s
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
