The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Determination of urban volatile organic compound emission ratios and comparison with an emissions database
Open accessAbstract
During the NEAQS‐ITCT2k4 campaign in New England, anthropogenic VOCs and CO were measured downwind from New York City and Boston. The emission ratios of VOCs relative to CO and acetylene were calculated using a method in which the ratio of a VOC with acetylene is plotted versus the photochemical age. The intercept at the photochemical age of zero gives the emission ratio. The so determined emission ratios were compared to other measurement sets, including data from the same location in 2002, canister samples collected inside New York City and Boston, aircraft measurements from Los Angeles in 2002, and the average urban composition of 39 U.S. cities. All the measurements generally agree within a factor of two. The measured emission ratios also agree for most compounds within a factor of two with vehicle exhaust data indicating that a major source of VOCs in urban areas is automobiles. A comparison with an anthropogenic emission database shows less agreement. Especially large discrepancies were found for the C 2‐C 4 alkanes and most oxygenated species. As an example, the database overestimated toluene by almost a factor of three, which caused an air quality forecast model (WRF‐CHEM) using this database to overpredict the toluene mixing ratio by a factor of 2.5 as well. On the other hand, the overall reactivity of the measured species and the reactivity of the same compounds in the emission database were found to agree within 30%.
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Cites
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Cited by
Volatile chemical products emerging as largest petrochemical source of urban organic emissions
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Self-citationProton-Transfer Reaction Mass Spectrometry
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Hydrocarbon emissions characterization in the Colorado Front Range: A pilot study
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Self-citationNon-methane hydrocarbon (C 2 –C 8 ) sources and sinks around the Arabian Peninsula
Bourtsoukidis, E., Ernle, L., Crowley, J. N., Lelieveld, J., Paris, J.-D., Pozzer, A., Walter, D., & Williams, J. (2019) · Atmospheric Chemistry and Physics · doi:10.5194/acp-19-7209-2019 · Cited by 85
Metadata
- Authors
- Warneke, C., McKeen, S. A., de Gouw, J. A., Goldan, P. D., Kuster, W. C., Holloway, J. S., Williams, E. J., Lerner, B. M., Parrish, D. D., Trainer, M., Fehsenfeld, F. C., Kato, S., Atlas, E. L., Baker, A., & Blake, D. R.
- Venue
- Journal of Geophysical Research: Atmospheres
- Publisher
- American Geophysical Union (AGU)
- Published
- 2007-05-15
- Volume
- 112
- Issue
- D10
- ISSN
- 0148-0227 (ISSN-L)
- OpenAlex
- W1983862566
- Cited by
- 297
- References
- 35
- FWCI
- 11.11
- Type
- journal article
- Language
- en
- Open access
- green
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- Warneke, C., McKeen, S. A., de Gouw, J. A., Goldan, P. D., Kuster, W. C., Holloway, J. S., Williams, E. J., Lerner, B. M., Parrish, D. D., Trainer, M., Fehsenfeld, F. C., Kato, S., Atlas, E. L., Baker, A., & Blake, D. R. (2007). Determination of urban volatile organic compound emission ratios and comparison with an emissions database. Journal of Geophysical Research: Atmospheres. https://doi.org/10.1029/2006jd007930
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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