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Oxygen isotope behavior in the Sulfate-Water System
Abstract
Fundamental data on oxygen isotope behavior in the sulfate-water system are given. Oxygen exchange rates between sulfate ions and water are very slow and show a marked pH dependence. Of the order of 10/sup +3/ to 10/sup +5/ years are required to closely approach isotopic equilibrium at earth surface conditions. Oxygen isotope fractionation experiments yielded the following relationships: Ln alpha = 3878/(t+2) -0.0034 anhydrite water (and) Ln alpha = 3251/(t+2) -0.0056 dissolved sulfate water. During progressive evaporation of saturated CaSO/sub 4/ solution the gypsum formed tends to concentrate oxygen-18 relative to dissolved sulfate by 2%. Sulfate reducing bacteria preferentially metabolize oxygen-16 by about 4.6% in both pure and natural cultures. Oxidation of sulfide to sulfate in natural environments is a complex process making use of both water oxygen and molecular oxygen.
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“This is consistent with the hydrothermal experiments of Lloyd (1968), Kusakabe and Robinson (1977) and Chiba et al. (1981).”
From Oxygen isotope fractionation in carbonate and sulfate minerals. (1999) · cites this paper as Lloyd (1968)
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Metadata
- Authors
- Lloyd, R. M.
- Corresponding author
- Lloyd, R. M.
- Venue
- Journal of Geophysical Research
- Publisher
- American Geophysical Union (AGU)
- Published
- 1968-09-15
- Volume
- 73
- Issue
- 18
- Pages
- 6099-6110
- ISSN
- 0148-0227 (ISSN-L)
- OpenAlex
- W2112478326
- Cited by
- 499
- References
- 13
- Citations by year
- 2026: 8 · 2025: 18 · 2024: 10 · 2023: 8 · 2022: 8 · 2021: 27 · 2020: 14 · 2019: 15 · 2018: 11 · 2017: 17 · 2016: 19 · 2015: 16 · 2014: 16 · 2013: 15 · 2012: 15
- FWCI
- 12.57
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Geophysical Research Atmospheres (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- oxygen isotopes, oxygen exchange kinetics, isotope fractionation, anhydrite, gypsum, evaporation, pH dependence, sulfate-reducing bacteria, oxygen-16, sulfide oxidation, molecular oxygen, dissolved sulfate
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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