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Oxygen isotope behavior in the Sulfate-Water System
Abstract
Fundamental data on oxygen isotope behavior in the sulfate-water system are given. Oxygen exchange rates between sulfate ions and water are very slow and show a marked pH dependence. Of the order of 10/sup +3/ to 10/sup +5/ years are required to closely approach isotopic equilibrium at earth surface conditions. Oxygen isotope fractionation experiments yielded the following relationships: Ln alpha = 3878/(t+2) -0.0034 anhydrite water (and) Ln alpha = 3251/(t+2) -0.0056 dissolved sulfate water. During progressive evaporation of saturated CaSO/sub 4/ solution the gypsum formed tends to concentrate oxygen-18 relative to dissolved sulfate by 2%. Sulfate reducing bacteria preferentially metabolize oxygen-16 by about 4.6% in both pure and natural cultures. Oxidation of sulfide to sulfate in natural environments is a complex process making use of both water oxygen and molecular oxygen.
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“This is consistent with the hydrothermal experiments of Lloyd (1968), Kusakabe and Robinson (1977) and Chiba et al. (1981).”
From Oxygen isotope fractionation in carbonate and sulfate minerals. (1999) · cites this paper as Lloyd (1968)
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Metadata
- Authors
- Lloyd, R. M.
- Corresponding author
- Lloyd, R. M.
- Venue
- Journal of Geophysical Research
- Publisher
- American Geophysical Union (AGU)
- Published
- 1968-09-15
- Volume
- 73
- Issue
- 18
- Pages
- 6099-6110
- ISSN
- 0148-0227 (ISSN-L)
- OpenAlex
- W2112478326
- Cited by
- 499
- References
- 13
- Citations by year
- 2026: 8 · 2025: 18 · 2024: 10 · 2023: 8 · 2022: 8 · 2021: 27 · 2020: 14 · 2019: 15 · 2018: 11 · 2017: 17 · 2016: 19 · 2015: 16 · 2014: 16 · 2013: 15 · 2012: 15
- FWCI
- 12.57
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Geophysical Research Atmospheres (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- oxygen isotopes, oxygen exchange kinetics, isotope fractionation, anhydrite, gypsum, evaporation, pH dependence, sulfate-reducing bacteria, oxygen-16, sulfide oxidation, molecular oxygen, dissolved sulfate
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