A Novel Ultra-Thin-Walled ZnO Microtube Cavity Supporting Multiple Optical Modes for Bluish-Violet Photoluminescence, Low-Threshold Ultraviolet Lasing and Microfluidic Photodegradation
Open accessAbstract
ZnO optical microcavities have shown great promise as a potential core component material/structure for ultraviolet lasers, light-emitting diodes and photonic sensors because of their outstanding optoelectronic properties. Here, we report a novel ultra-thin-walled ZnO (UTW-ZnO) microtube cavity with a wall thickness of ~750 nm, supporting multiple types of optical modes, including in-tube Fabry–Perot modes, in-wall Fabry–Perot modes and wave-guided whispering gallery modes (WG-WGMs). The free-exciton recombination rate and exciton–exciton collisions are promoted in the cavity. The intensities of near-band edge (ultravoilet (UV) light) and X-band (blue light) emission are therefore increased at least one order of magnitude in the temperature range of 0–500 °C. Meanwhile, the temperature-sensitive multicolor luminescence of the UTW-ZnO microtubes in the visible band from near-white to bluish-violet is demonstrated for the first time. Low-threshold UV lasing is also achieved in the UTW-ZnO microtube by WG-WGMs, where the excitation threshold is down to 5.50 μW. Furthermore, light harvesting in the microtube cavity is beneficial to boosting the ZnO catalytic performance for photodegradation of organic dyes. The UTW-ZnO microtube exhibits compatibility to microfluidic channels for recyclable on-chip degradation. The present work provides new opportunities to design novel tubular wide-bandgap semiconductor devices for a variety of optoelectronic applications in micro/nanophotonics. Microscale semiconductor tubes that emit ultraviolet laser light have been developed by researchers in China and the UK. Lasers employ an optical cavity that boosts light like the body of a guitar amplifies sound. The miniaturization of lasers requires smaller cavities, which can be difficult to fabricate with high precision and reproducibility. Now, Yinzhou Yan from the Beijing University of Technology and colleagues have created microscale semiconductor tubes and have demonstrated their ability to enhance optical emission. They used a method they developed – optical vapor supersaturated precipitation – to make hexagonal zinc oxide tubes that were 50 micrometers in diameter and had walls that were just 750 nanometers thick. The team showed that these structures can trap and enhance light in multiple ways, demonstrating their flexibility for optoelectronic applications. A novel ultra-thin-walled ZnO microtube cavity with a wall thickness of ~750 nm, supporting multiple types of optical modes, including in-tube Fabry–Perot modes, in-wall Fabry–Perot modes and wave-guided whispering gallery modes is fabricated via optical vapor supersaturated precipitation. The intensities of near-band edge and X-band emission are therefore increased at least one order of magnitude in the temperature range of 0–500 °C. The ultra-thin-walled ZnO microtube demonstrates unprecedented applications, for example, temperature-sensitive multicolor luminescence, low-threshold ultravoilet (UV) lasing and high-performance recyclable on-chip photodegradation, within one platform. It provides new opportunities to design multifunctional tailored wide bandgap semiconductor devices for a variety of optoelectronic applications in micro/nanophotonics.
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ZnO has a wide band gap (3.3 eV), optical transparency in the visible range, and a high exciton binding energy at room temperature (60 meV), making it suitable for the development of optical planar microcavities due to strong coupling generating exciton-polaritons at room temperature.
“In addition to a wide band gap (3.3 eV) and optical transparency in the visible range, this semiconductor oxide also benefits from a high exciton binding energy at room temperature (60 meV), making it suitable for the development of optical planar microcavities due to the strong coupling, which generates exciton-polaritons at room temperature [99-102].”
From Metal Oxide Thin Films for Advanced Photonic Applications (2026) · cites this paper as [99]
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Cites
Room-Temperature Ultraviolet Nanowire Nanolasers
Huang, M. H., Mao, S. S., Feick, H., Yan, H., Wu, Y., Kind, H., Weber, E. R., Russo, R. E., & Yang, P. (2001) · Science · doi:10.1126/science.1060367 · Cited by 8,922 · see citing works
Vahala, K. J. (2003) · Nature · doi:10.1038/nature01939 · Cited by 4,878 · see citing works
Zinc oxide nanostructures: growth, properties and applications
Wang, Z. L. (2004) · Journal of Physics Condensed Matter · doi:10.1088/0953-8984/16/25/r01 · Cited by 3,694 · see citing works
Optically pumped lasing of ZnO at room temperature
Bagnall, D. M., Chen, Y. F., Zhu, Z. Q., et al. (1997) · Applied Physics Letters · doi:10.1063/1.118824 · Cited by 2,202 · see citing works
Room-temperature ultraviolet laser emission from self-assembled ZnO microcrystallite thin films
Tang, Z., Wong, G. K., Yu, P., Kawasaki, M., Ohtomo, A., Koinuma, H., & Segawa, Y. (1998) · Applied Physics Letters · doi:10.1063/1.121620 · Cited by 1,819 · see citing works
Random Laser Action in Semiconductor Powder
Cao, H., Zhao, Y., Ho, S., Seelig, E. W., Wang, Q. H., & Chang, R. P. H. (1999) · Physical Review Letters · doi:10.1103/physrevlett.82.2278 · Cited by 1,665 · see citing works
Self-citationAll-printable band-edge modulated ZnO nanowire photodetectors with ultra-high detectivity
Liu, X., Gu, L., Zhang, Q., Wu, J., Long, Y., & Fan, Z. (2014) · Nature Communications · doi:10.1038/ncomms5007 · Cited by 621 · see citing works
Self-citationSingle-molecule nucleic acid interactions monitored on a label-free microcavity biosensor platform
Baaske, M. D., Foreman, M. R., & Vollmer, F. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.180 · Cited by 560 · see citing works
Zheng, Y., Chen, C., Zhan, Y., Lin, X., Zheng, Q., Wei, K., Zhu, J., & Zhu, Y. (2007) · Inorganic Chemistry · doi:10.1021/ic062394m · Cited by 557 · see citing works
Broadband ZnO Single-Nanowire Light-Emitting Diode
Bao, J., Zimmler, M. A., Capasso, F., et al. (2006) · Nano Letters · doi:10.1021/nl061080t · Cited by 545 · see citing works
Sol–gel preparation and enhanced photocatalytic performance of Cu-doped ZnO nanoparticles
Fu, M., Li, Y., Wu, S., et al. (2011) · Applied Surface Science · doi:10.1016/j.apsusc.2011.10.003 · Cited by 355 · see citing works
Zhang, L., Cheng, H., Zong, R., et al. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp807778r · Cited by 349 · see citing works
Detection of Single Nanoparticles and Lentiviruses Using Microcavity Resonance Broadening
Shao, L., Jiang, X., Yu, X., Li, B., Clements, W. R., Vollmer, F., Wang, W., Xiao, Y., & Gong, Q. (2013) · Advanced Materials · doi:10.1002/adma201302572 · Cited by 317 · see citing works
Lai, Y., Meng, M., Yu, Y., et al. (2011) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2011.04.028 · Cited by 297 · see citing works
Room Temperature Excitonic Whispering Gallery Mode Lasing from High‐Quality Hexagonal ZnO Microdisks
Chen, R., Ling, B., Sun, X. W., & Sun, H. (2011) · Advanced Materials · doi:10.1002/adma.201100423 · Cited by 272 · see citing works
Whispering Gallery Mode Lasing from Zinc Oxide Hexagonal Nanodisks
Gargas, D. J., Moore, M. C., Ni, A., Chang, S., Zhang, Z., Chuang, S. L., & Yang, P. (2010) · ACS Nano · doi:10.1021/nn9018174 · Cited by 244 · see citing works
Binary response Se/ZnO p‐n heterojunction UV photodetector with high on/off ratio and fast speed
Hu, K., Teng, F., Zheng, L., et al. (2016) · Laser & Photonics Review · doi:10.1002/lpor.201600257 · Cited by 214 · see citing works
Whispering gallery mode lasing in zinc oxide microwires
Czekalla, C., Sturm, C., Schmidt‐Grund, R., Cao, B., Lorenz, M., & Grundmann, M. (2008) · Applied Physics Letters · doi:10.1063/1.2946660 · Cited by 201 · see citing works
Growth mechanism of tubular ZnO formed in aqueous solution
Wei, A., Sun, X. W., Xu, C., et al. (2006) · Nanotechnology · doi:10.1088/0957-4484/17/6/033 · Cited by 186 · see citing works
Self-citationDetection of Single Nanoparticles and Lentiviruses Using Microcavity Resonance Broadening
Shao, L., Jiang, X., Yu, X., et al. (2014) · Advanced Materials · doi:10.1002/adma.201400142 · Cited by 186 · see citing works
Zhang, L., Yin, L., Wang, C., et al. (2010) · ACS Applied Materials & Interfaces · doi:10.1021/am100274d · Cited by 162 · see citing works
Zhang, X., Huang, X., Li, C., et al. (2013) · Advanced Materials · doi:10.1002/adma.201301088 · Cited by 150 · see citing works
ZnO microtube ultraviolet detectors
Cheng, J., Zhang, Y., & Guo, R. (2007) · Journal of Crystal Growth · doi:10.1016/j.jcrysgro.2007.08.034 · Cited by 146 · see citing works
Sun, H., Makino, T., Tuan, N. T., et al. (2000) · Applied Physics Letters · doi:10.1063/1.1333687 · Cited by 137 · see citing works
Whispering‐gallery mode lasing in ZnO microcavities
Xu, C., Dai, J., Zhu, G., Zhu, G., Lin, Y., Li, J., & Shi, Z. (2014) · Laser & Photonics Review · doi:10.1002/lpor.201300127 · Cited by 134 · see citing works
Self-citationHighly Unidirectional Emission and Ultralow‐Threshold Lasing from On‐Chip Ultrahigh‐Q Microcavities
Jiang, X., Xiao, Y., Zou, C., He, L., Dong, C., Li, B., Li, Y., Sun, F., Yang, L., & Gong, Q. (2012) · Advanced Materials · doi:10.1002/adma.201201229 · Cited by 134 · see citing works
Cheng, H., Hsu, H., Tseng, Y.-K., et al. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp0442908 · Cited by 112 · see citing works
Whispering gallery-mode lasing in ZnO microrods at room temperature
Dai, J., Xu, C., Zheng, K., Lv, C. G., & Cui, Y. (2009) · Applied Physics Letters · doi:10.1063/1.3276069 · Cited by 110 · see citing works
Self-citationAbiyasa, A. P., Yu, S. F., Lau, S. P., et al. (2007) · Applied Physics Letters · doi:10.1063/1.2746940 · Cited by 94 · see citing works
Nasr, B., Wang, D., Kruk, R., et al. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201202500 · Cited by 93 · see citing works
Single Mode ZnO Whispering-Gallery Submicron Cavity and Graphene Improved Lasing Performance
Li, J., Lin, Y., Lu, J., Xu, C., Wang, Y., Shi, Z., & Dai, J. (2015) · ACS Nano · doi:10.1021/acsnano.5b01319 · Cited by 88 · see citing works
Self-citationWavelength‐Tunable Electroluminescent Light Sources from Individual Ga‐Doped ZnO Microwires
Jiang, M., He, G., Chen, H., et al. (2017) · Small · doi:10.1002/smll.201604034 · Cited by 81 · see citing works
Large Scale Fabrication of Quasi-Aligned ZnO Stacking Nanoplates
Cao, X., Zeng, H., Wang, M., et al. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp800499r · Cited by 76 · see citing works
Ultraviolet Lasing Behavior in ZnO Optical Microcavities
Dong, H., Zhou, B., Li, J., Zhan, J., & Zhang, L. (2017) · Journal of Materiomics · doi:10.1016/j.jmat.2017.06.001 · Cited by 68 · see citing works
Free-Standing Undoped ZnO Microtubes with Rich and Stable Shallow Acceptors
Wang, Q., Yan, Y., Zeng, Y., Lu, Y., Chen, L., & Jiang, Y. (2016) · Scientific Reports · doi:10.1038/srep27341 · Cited by 40 · see citing works
Self-citationFacile Synthesis and Ultraviolet Lasing Properties of ZnO Microtubes
Dong, H., Sun, L., Xie, W., Zhou, W., Shen, X., & Chen, Z. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp1047908 · Cited by 27 · see citing works
Single-crystalline hexagonal ZnO microtube optical resonators
Dong, H., Chen, Z., Sun, L., et al. (2010) · Journal of Materials Chemistry · doi:10.1039/c0jm00172d · Cited by 26 · see citing works
Fabrication of ZnO microtube arrays via vapor phase growth
Sun, T., & Qiu, J. (2007) · Materials Letters · doi:10.1016/j.matlet.2007.09.015 · Cited by 22 · see citing works
Geometry Dependent Evolution of the Resonant Mode in ZnO Elongated Hexagonal Microcavity
Dong, H., Liu, Y., Sun, S., Li, J., Zhan, J., Chen, Z., & Zhang, L. (2016) · Scientific Reports · doi:10.1038/srep19273 · Cited by 21 · see citing works
Wang, Q., Yan, Y., Zeng, Y., & Jiang, Y. (2016) · Journal of Crystal Growth · doi:10.1016/j.jcrysgro.2016.12.020 · Cited by 21 · see citing works
Self-citationMapping cavity modes of ZnO nanobelts
Xu, X., Brossard, F. S. F., Williams, D. A., Collins, D. P., Holmes, M., Taylor, R. A., & Zhang, X. (2009) · Applied Physics Letters · doi:10.1063/1.3151866 · Cited by 20 · see citing works
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Metal Oxide Thin Films for Advanced Photonic Applications
Stîngescu, M.-L., Șopronyi, M.-A., Antohe, Ș., & Scărișoreanu, N.-D. (2026) · Crystals · doi:10.3390/cryst16030164 · Cited by 2 · see citing works
“…in the visible range, this semiconductor oxide also benefits from a high exciton binding energy at room temperature (60 meV), making it suitable for the development of optical planar microcavities due to the strong coupling, which generates exciton–polaritons at room temperature [99–102].”
- Authors
- Wang, Q., Yan, Y., Qin, F., Xu, C., Liu, X., Tan, P., Shi, N., Hu, S., Li, L., Zeng, Y., Zhao, Y., & Jiang, Y.
- Affiliations
- Beijing University of Technology (CN)
- State Key Laboratory of Digital Medical Engineering (CN)
- University of Manchester (GB)
- Corresponding author
- Yan, Yinzhou
- Venue
- NPG Asia Materials
- Published
- 2017-10
- Volume
- 9
- Issue
- 10
- Pages
- e442-e442
- ISSN
- 1884-4049 (ISSN-L)
- 1884-4057
- OpenAlex
- W2765771062
- Cited by
- 37
- References
- 41
- Citations by year
- 2026: 2 · 2025: 2 · 2024: 1 · 2023: 5 · 2022: 3 · 2021: 4 · 2020: 6 · 2019: 8 · 2018: 6
- FWCI
- 2.31
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- NPG Asia Materials (publishedVersion, cc-by)
- Research Explorer (The University of Manchester) (publishedVersion, other-oa)
- SEMI-IR (submittedVersion)
- Funders
- National Natural Science Foundation of China (11504012, 11674018)
- Beijing Nova Program (Z171100001117101)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › ZnO doping and properties
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Photonic and Optical Devices
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Strong Light-Matter Interactions
- Keywords
- optical microcavities, whispering gallery modes, Fabry-Perot modes, ultraviolet lasing, low-threshold lasing, wide bandgap semiconductors, nanophotonics
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