The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Supramolecular metal-organic frameworks that display high homogeneous and heterogeneous photocatalytic activity for H2 production
Open accessAbstract
Self-assembly has a unique presence when it comes to creating complicated, ordered supramolecular architectures from simple components under mild conditions. Here, we describe a self-assembly strategy for the generation of the first homogeneous supramolecular metal-organic framework (SMOF-1) in water at room temperature from a hexaarmed [Ru(bpy)3]2+-based precursor and cucurbit[8]uril (CB[8]). The solution-phase periodicity of this cubic transition metal-cored supramolecular organic framework (MSOF) is confirmed by small-angle X-ray scattering and diffraction experiments, which, as supported by TEM imaging, is commensurate with the periodicity in the solid state. We further demonstrate that SMOF-1 adsorbs anionic Wells−Dawson-type polyoxometalates (WD-POMs) in a one-cage-one-guest manner to give WD-POM@SMOF-1 hybrid assemblies. Upon visible-light (500 nm) irradiation, such hybrids enable fast multi-electron injection from photosensitive [Ru(bpy)3]2+ units to redox-active WD-POM units, leading to efficient hydrogen production in aqueous media and in organic media. The demonstrated strategy opens the door for the development of new classes of liquid-phase and solid-phase ordered porous materials.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Horike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
Characterization of supramolecular gels
Yu, G., Yan, X., Han, C., & Huang, F. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60080g · Cited by 626
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Metal-Organic Frameworks for Energy Applications
Wang, H., Zhu, Q.-L., Zou, R., & Xu, Q. (2017) · Chem · doi:10.1016/j.chempr.2016.12.002 · Cited by 1,200
Self-citationSurveying macrocyclic chemistry: from flexible crown ethers to rigid cyclophanes
Liu, Z., Nalluri, S. K. M., & Stoddart, J. F. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00185a · Cited by 909
Bioinspired Framework Catalysts: From Enzyme Immobilization to Biomimetic Catalysis
Wang, K.-Y., Zhang, J., Hsu, Y.-C., Lin, H., Han, Z., Pang, J., Yang, Z., Liang, R.-R., Shi, W., & Zhou, H.-C. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00879 · Cited by 490
Lu, M., Zhang, M., Liu, J., Yu, T.-Y., Chang, J.-N., Shang, L.-J., Li, S.-L., & Lan, Y.-Q. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c11987 · Cited by 477
Polyoxometalate@Metal–Organic Framework Composites as Effective Photocatalysts
Liu, Y., Tang, C., Cheng, M., Chen, M., Chen, S., Lei, L., Chen, Y., Yi, H., Fu, Y., & Li, L. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c03866 · Cited by 253
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Metadata
- Authors
- Tian, J., Xu, Z.-Y., Zhang, D.-W., Wang, H., Xie, S.-H., Xu, D.-W., Ren, Y.-H., Wang, H., Liu, Y., & Li, Z.-T.
- Venue
- Nature Communications
- Published
- 2016-05-10
- Volume
- 7
- Issue
- 1
- Pages
- 11580-11580
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2386172027
- Cited by
- 245
- References
- 3
- FWCI
- 11.29
- Type
- journal article
- Language
- en
- Open access
- gold
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