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Wafer-sized multifunctional polyimine-based two-dimensional conjugated polymers with high mechanical stiffness
Open accessAbstract
One of the key challenges in two-dimensional (2D) materials is to go beyond graphene, a prototype 2D polymer (2DP), and to synthesize its organic analogues with structural control at the atomic- or molecular-level. Here we show the successful preparation of porphyrin-containing monolayer and multilayer 2DPs through Schiff-base polycondensation reaction at an air–water and liquid–liquid interface, respectively. Both the monolayer and multilayer 2DPs have crystalline structures as indicated by selected area electron diffraction. The monolayer 2DP has a thickness of∼0.7 nm with a lateral size of 4-inch wafer, and it has a Young’s modulus of 267±30 GPa. Notably, the monolayer 2DP functions as an active semiconducting layer in a thin film transistor, while the multilayer 2DP from cobalt-porphyrin monomer efficiently catalyses hydrogen generation from water. This work presents an advance in the synthesis of novel 2D materials for electronics and energy-related applications.
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Cites
Electric Field Effect in Atomically Thin Carbon Films
Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Zhang, Y., Dubonos, S. V., Grigorieva, I. V., & Firsov, A. A. (2004) · Science · doi:10.1126/science.1102896 · Cited by 66,834
Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene
Lee, C., Wei, X., Kysar, J. W., & Hone, J. (2008) · Science · doi:10.1126/science.1157996 · Cited by 20,847
Probing Single Molecules and Single Nanoparticles by Surface-Enhanced Raman Scattering
Nie, S., & Emory, S. R. (1997) · Science · doi:10.1126/science.275.5303.1102 · Cited by 10,238
Novoselov, K. S., Fal′ko, V. I., Colombo, L., Gellert, P. R., Schwab, M. G., & Kim, K. (2012) · Nature · doi:10.1038/nature11458 · Cited by 9,251
The structure of suspended graphene sheets
Meyer, J. C., Geim, A. K., Katsnelson, M. I., Novoselov, K. S., Booth, T. J., & Roth, S. (2007) · Nature · doi:10.1038/nature05545 · Cited by 5,032
Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems
Ferrari, A. C., Bonaccorso, F., Fal'ko, V., Novoselov, K. S., Roche, S., Bøggild, P., Borini, S., Koppens, F. H. L., Palermo, V., Pugno, N., et al. (2015) · Nanoscale · doi:10.1039/c4nr01600a · Cited by 3,027
Self-citationA buckling-based metrology for measuring the elastic moduli of polymeric thin films
Stafford, C. M., Harrison, C., Beers, K. L., Karim, A., Amis, E. J., VanLandingham, M. R., Kim, H.-C., Volksen, W., Miller, R. D., & Simonyi, E. E. (2004) · Nature Materials · doi:10.1038/nmat1175 · Cited by 1,360
Belowich, M. E., & Stoddart, J. F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15305j · Cited by 1,358
Mechanical Properties of Monolayer Graphene Oxide
Suk, J. W., Piner, R. D., An, J., & Ruoff, R. S. (2010) · ACS Nano · doi:10.1021/nn101781v · Cited by 1,194
Epitaxial growth of single-domain graphene on hexagonal boron nitride
Yang, W., Chen, G., Shi, Z., Liu, C.-C., Zhang, L., Xie, G., Cheng, M., Wang, D., Yang, R., Shi, D., et al. (2013) · Nature Materials · doi:10.1038/nmat3695 · Cited by 1,012
Two‐Dimensional Polymers: Just a Dream of Synthetic Chemists?
Sakamoto, J., van Heijst, J., Lukin, O., & Schlüter, A. D. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200801863 · Cited by 734
Porous graphenes: two-dimensional polymer synthesis with atomic precision
Bieri, M., Treier, M., Cai, J., Aït-Mansour, K., Ruffieux, P., Gröning, O., Gröning, P., Kastler, M., Rieger, R., Feng, X., et al. (2009) · Chemical Communications · doi:10.1039/b915190g · Cited by 702
Self-citationBowden, N., Huck, W. T. S., Paul, K. E., & Whitesides, G. M. (1999) · Applied Physics Letters · doi:10.1063/1.125076 · Cited by 655
Review of CVD Synthesis of Graphene
Muñoz, R., & Gómez‐Aleixandre, C. (2013) · Chemical Vapor Deposition · doi:10.1002/cvde.201300051 · Cited by 622
Dong, R., Pfeffermann, M., Liang, H., Zheng, Z., Zhu, X., Zhang, J., & Feng, X. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201506048 · Cited by 621
Self-citationControlling on-surface polymerization by hierarchical and substrate-directed growth
Lafferentz, L., Eberhardt, V., Dri, C., Africh, C., Comelli, G., Esch, F., Hecht, S., & Grill, L. (2012) · Nature Chemistry · doi:10.1038/nchem.1242 · Cited by 564
Kandambeth, S., Shinde, D. B., Panda, M. K., Lukose, B., Heine, T., & Banerjee, R. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201306775 · Cited by 558
Sun, Y., Liu, C., Grauer, D. C., Yano, J., Long, J. R., Yang, P., & Chang, C. J. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4094764 · Cited by 556
Two‐Dimensional Soft Nanomaterials: A Fascinating World of Materials
Zhuang, X., Mai, Y., Wu, D., Zhang, F., & Feng, X. (2015) · Advanced Materials · doi:10.1002/adma.201401857 · Cited by 514
Self-citationA nanoporous two-dimensional polymer by single-crystal-to-single-crystal photopolymerization
Kissel, P., Murray, D. J., Wulftange, W. J., Catalano, V. J., & King, B. T. (2014) · Nature Chemistry · doi:10.1038/nchem.2008 · Cited by 513
Bunck, D. N., & Dichtel, W. R. (2013) · Journal of the American Chemical Society · doi:10.1021/ja408243n · Cited by 507
Kory, M. J., Wörle, M., Weber, T., Payamyar, P., van de Poll, S. W., Dshemuchadse, J., Trapp, N., & Schlüter, A. D. (2014) · Nature Chemistry · doi:10.1038/nchem.2007 · Cited by 430
A two-dimensional polymer prepared by organic synthesis
Kissel, P., Erni, R., Schweizer, W. B., Rossell, M. D., King, B. T., Bauer, T., Götzinger, S., Schlüter, A. D., & Sakamoto, J. (2012) · Nature Chemistry · doi:10.1038/nchem.1265 · Cited by 423
Andreiadis, E. S., Jacques, P.-A., Tran, P. D., Leyris, A., Chavarot-Kerlidou, M., Jousselme, B., Matheron, M., Pécaut, J., Palacin, S., Fontecave, M., et al. (2013) · Nature Chemistry · doi:10.1038/nchem.1481 · Cited by 397
Dai, W., Shao, F., Szczerbiński, J., McCaffrey, R., Zenobi, R., Jin, Y., Schlüter, A. D., & Zhang, W. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201508473 · Cited by 336
Hydrogen Evolution Catalyzed by Cobalt Diimine–Dioxime Complexes
Kaeffer, N., Chavarot‐Kerlidou, M., & Artero, V. (2015) · Accounts of Chemical Research · doi:10.1021/acs.accounts.5b00058 · Cited by 286
Twinning and Twisting of Tri- and Bilayer Graphene
Brown, L., Hovden, R., Huang, P., Wojcik, M., Muller, D. A., & Park, J. (2012) · Nano Letters · doi:10.1021/nl204547v · Cited by 256
Large Area Synthesis of a Nanoporous Two-Dimensional Polymer at the Air/Water Interface
Murray, D. J., Patterson, D. D., Payamyar, P., Bhola, R., Song, W., Lackinger, M., Schlüter, A. D., & King, B. T. (2015) · Journal of the American Chemical Society · doi:10.1021/ja512018j · Cited by 230
Free-Standing Monolayer Two-Dimensional Supramolecular Organic Framework with Good Internal Order
Pfeffermann, M., Dong, R., Graf, R., Zajaczkowski, W., Gorelik, T., Pisula, W., Narita, A., Müllen, K., & Feng, X. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b09638 · Cited by 202
Self-citationPayamyar, P., Kaja, K., Ruiz‐Vargas, C., Stemmer, A., Murray, D. J., Johnson, C. J., King, B. T., Schiffmann, F., VandeVondele, J., Renn, A., et al. (2014) · Advanced Materials · doi:10.1002/adma.201304705 · Cited by 160
Self-citationHuang, D., Lu, J., Li, S., Luo, Y., Chen, Z., Hu, B., Wang, M., & Shen, Y. F. (2014) · Langmuir · doi:10.1021/la501052m · Cited by 81
Zheng, Z., Ruiz‐Vargas, C., Bauer, T., Rossi, A. M., Payamyar, P., Schütz, A., Stemmer, A., Sakamoto, J., & Schlüter, A. D. (2013) · Macromolecular Rapid Communications · doi:10.1002/marc.201300624 · Cited by 77
Self-citationHierarchical line-defect patterns in wrinkled surfaces
Glatz, B. A., Tebbe, M., Kaoui, B., Aichele, R., Kuttner, C., Schedl, A. E., Schmidt, H., Zimmermann, W., & Fery, A. (2015) · Soft Matter · doi:10.1039/c5sm00318k · Cited by 56
Self-citationOpilik, L., Payamyar, P., Szczerbiński, J., Schütz, A., Servalli, M., Hungerland, T., Schlüter, A. D., & Zenobi, R. (2015) · ACS Nano · doi:10.1021/acsnano.5b00629 · Cited by 43
Cited by
Interface-Assisted Synthesis of 2D Materials: Trend and Challenges
Dong, R., Zhang, T., & Feng, X. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00056 · Cited by 710
Self-citationInterfacial Polymerization: From Chemistry to Functional Materials
Zhang, F., Fan, J., & Wang, S. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201916473 · Cited by 478
Recent advances of multi-dimensional porphyrin-based functional materials in photodynamic therapy
Tian, J., Huang, B., Nawaz, M. H., & Zhang, W. (2020) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2020.213410 · Cited by 369
Toward a molecular design of porous carbon materials
Borchardt, L., Zhu, Q.-L., Casco, M. E., Berger, R., Zhuang, X., Kaskel, S., Feng, X., & Xu, Q. (2017) · Materials Today · doi:10.1016/j.mattod.2017.06.002 · Cited by 266
Self-citation(2021) · doi:10.1038/s41467-021-26817-4 · Cited by 222
Metadata
- Authors
- Sahabudeen, H., Qi, H., Glatz, B. A., Tranca, D., Dong, R., Hou, Y., Zhang, T., Kuttner, C., Lehnert, T., Seifert, G., Kaiser, U., Fery, A., Zheng, Z., & Feng, X.
- Venue
- Nature Communications
- Published
- 2016-11-16
- Volume
- 7
- Issue
- 1
- Pages
- 13461-13461
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2550509429
- Cited by
- 371
- References
- 34
- FWCI
- 15.13
- Type
- journal article
- Language
- en
- Open access
- gold
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