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A two-dimensional π–d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour
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Currently, studies on organic two-dimensional (2D) materials with special optic-electronic properties are attracting great research interest. However, 2D organic systems possessing promising electrical transport properties are still rare. Here a highly crystalline thin film of a copper coordination polymer, Cu-BHT (BHT=benzenehexathiol), is prepared via a liquid–liquid interface reaction between BHT/dichloromethane and copper(II) nitrate/H 2 O. The morphology and structure characterization reveal that this film is piled up by nanosheets of 2D lattice of [Cu 3(C 6 S 6)]n, which is further verified by quantum simulation. Four-probe measurements show that the room temperature conductivity of this material can reach up to 1,580 S cm−1, which is the highest value ever reported for coordination polymers. Meanwhile, it displays ambipolar charge transport behaviour and extremely high electron and hole mobilities (99 cm 2 V−1 s−1 for holes and 116 cm 2 V−1 s−1 for electrons) under field-effect modulation.
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Metadata
- Authors
- Huang, X., Sheng, P., Tu, Z., Zhang, F., Wang, J., Geng, H., Zou, Y., Di, C.-A., Yi, Y., Sun, Y., Xu, W., & Zhu, D.
- Venue
- Nature Communications
- Published
- 2015-06-15
- Volume
- 6
- Issue
- 1
- Pages
- 7408-7408
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2267990318
- Cited by
- 855
- References
- 40
- FWCI
- 19.41
- Type
- journal article
- Language
- en
- Open access
- gold
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