Fast-charging high-energy lithium-ion batteries via implantation of amorphous silicon nanolayer in edge-plane activated graphite anodes
Open accessAbstract
As fast-charging lithium-ion batteries turn into increasingly important components in forthcoming applications, various strategies have been devoted to the development of high-rate anodes. However, despite vigorous efforts, the low initial Coulombic efficiency and poor volumetric energy density with insufficient electrode conditions remain critical challenges that have to be addressed. Herein, we demonstrate a hybrid anode via incorporation of a uniformly implanted amorphous silicon nanolayer and edge-site-activated graphite. This architecture succeeds in improving lithium ion transport and minimizing initial capacity losses even with increase in energy density. As a result, the hybrid anode exhibits an exceptional initial Coulombic efficiency (93.8%) and predominant fast-charging behavior with industrial electrode conditions. As a result, a full-cell demonstrates a higher energy density (≥1060 Wh l −1 ) without any trace of lithium plating at a harsh charging current density (10.2 mA cm −2 ) and 1.5 times faster charging than that of conventional graphite.
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Surface coating with amorphous silicon nanolayer or doping with nanometal particles can improve initial Coulombic efficiency and Li+ diffusion kinetics.
“Typically, surface coating with amorphous silicon nanolayer or doping with nanometal particles can improve initial Coulombic efficiency and Li + diffusion kinetics [168,169].”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [168]
The Introduction and Results (pages not provided) say the amorphous Si nanolayer enables fast Li-ion diffusion, and the composite has high initial Coulombic efficiency. They attribute that efficiency chiefly to activated graphite edge sites and minimized surface area, however, not to the Si coating; they describe the remaining Ni nanoparticles as improving electrical conductivity, not as metal-particle doping that improves both claimed properties. (LLM, conf=0.86)
Experimental — accuracy not yet measured
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Cites
Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells
Kasavajjula, U. S., Wang, C.-S., & Appleby, A. (2007) · Journal of Power Sources · doi:10.1016/j.jpowsour.2006.09.084 · Cited by 2,400 · see citing works
A pomegranate-inspired nanoscale design for large-volume-change lithium battery anodes.
Liu, N., Lu, Z.-D., Zhao, J., Mcdowell, M., Lee, H.-W., Zhao, W.-T., & Cui, Y. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.6 · Cited by 2,294 · see citing works
Alloy Negative Electrodes for Li-Ion Batteries
Obrovac, M. N., & Chevrier, V. L. (2014) · Chemical Reviews · doi:10.1021/cr500207g · Cited by 2,188 · see citing works
A review of the electrochemical performance of alloy anodes for lithium-ion batteries
Zhang, W.-J. (2011) · Journal of Power Sources · doi:10.1016/j.jpowsour.2010.07.020 · Cited by 2,006 · see citing works
Wang, D.-W., Li, F., Liu, M., Lu, G., & Cheng, H.-M. (2008) · Angewandte Chemie · doi:10.1002/anie.200702721 · Cited by 1,999 · see citing works
Silicon‐Based Nanomaterials for Lithium‐Ion Batteries: A Review
Su, X., Wu, Q.-L., Li, J.-C., Xiao, X.-C., Lott, A., Lu, W., Sheldon, B. W., & Wu, J. (2014) · Advanced Energy Materials · doi:10.1002/aenm.201300882 · Cited by 1,602 · see citing works
Li-alloy based anode materials for Li secondary batteries.
Park, C.-M., Kim, J.-H., Kim, H.-S., & Sohn, H. (2010) · Chemical Society Reviews · doi:10.1039/b919877f · Cited by 1,601 · see citing works
Aurbach, D., Zinigrad, E., Cohen, Y., & Teller, H. (2002) · Solid State Ionics · doi:10.1016/s0167-2738(02)00080-2 · Cited by 1,365 · see citing works
Temperature dependent ageing mechanisms in Lithium-ion batteries – A Post-Mortem study
Waldmann, T., Wilka, M. D., Kasper, M., Fleischhammer, M., & Wohlfahrt-Mehrens, M. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.03.112 · Cited by 1,098 · see citing works
Chae, S. J., Güneş, F., Kim, K. K., Kim, E. S., Han, G., Kim, S. M., Shin, H., Yoon, S., Choi, J., Park, M. H., et al. (2009) · Advanced Materials · doi:10.1002/adma.200803016 · Cited by 873 · see citing works
Lithium Diffusion in Graphitic Carbon
Persson, K. A., Sethuraman, V. A., Hardwick, L. J., Hinuma, Y., Meng, Y. S., der Ven, A. V., Srinivasan, V., Kostecki, R. M., & Ceder, G. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz100188d · Cited by 861 · see citing works
In situ TEM of two-phase lithiation of amorphous silicon nanospheres.
Mcdowell, M., Lee, S., Harris, J. T., Korgel, B., Wang, C.-M., Nix, W., & Cui, Y. (2013) · Nano letters (Print) · doi:10.1021/nl3044508 · Cited by 825 · see citing works
Scalable synthesis of silicon-nanolayer-embedded graphite for high-energy lithium-ion batteries
Ko, M., Chae, S., Ma, J., Kim, N., Lee, H.-W., Cui, Y., & Cho, J. (2016) · Nature Energy · doi:10.1038/nenergy.2016.113 · Cited by 696 · see citing works
Self-citationNitta, N., & Yushin, G. (2014) · Particle & Particle Systems Characterization · doi:10.1002/ppsc.201300231 · Cited by 682 · see citing works
Optimizing areal capacities through understanding the limitations of lithium-ion electrodes
Gallagher, K., Trask, S., Bauer, C., Woehrle, T., Lux, S., Tschech, M., Lamp, P., Polzin, B., Ha, S., Long, B. R., et al. (2016) · Journal of The Electrochemical Society · doi:10.1149/2.0321602jes · Cited by 571 · see citing works
Electrical contacts to one- and two-dimensional nanomaterials.
Léonard, F., & Talin, A. (2011) · Nature Nanotechnology · doi:10.1038/nnano.2011.196 · Cited by 500
Levi, M., & Aurbach, D. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp9701911 · Cited by 442 · see citing works
Takami, N., Satoh, A., Hara, M., & Ohsaki, T. (1995) · Journal of The Electrochemical Society · doi:10.1149/1.2044017 · Cited by 416 · see citing works
Determination of the Lithium Ion Diffusion Coefficient in Graphite
Yu, P., Popov, B., Ritter, J., & White, R. (1999) · Journal of The Electrochemical Society · doi:10.1149/1.1391556 · Cited by 353 · see citing works
Lin, D.-C., Lu, Z.-D., Hsu, P.-C., Lee, H., Liu, N., Zhao, J., Wang, H.-T., Liu, C., & Cui, Y. (2015) · doi:10.1039/c5ee01363a · Cited by 346
Understanding undesirable anode lithium plating issues in lithium-ion batteries
Liu, Q.-Q., Du, C.-Y., Shen, B., Zuo, P.-J., Cheng, X.-Q., Ma, Y.-L., Yin, G., & Gao, Y.-Z. (2016) · RSC Advances · doi:10.1039/c6ra19482f · Cited by 337 · see citing works
High Rate Capability of Graphite Negative Electrodes for Lithium-Ion Batteries
Buqa, H., Goers, D., Holzapfel, M., Spahr, M., & Novák, P. (2005) · Journal of The Electrochemical Society · doi:10.1149/1.1851055 · Cited by 310 · see citing works
Challenges in Accommodating Volume Change of Si Anodes for Li‐Ion Batteries
Ko, M., Chae, S., & Cho, J. (2015) · ChemElectroChem · doi:10.1002/celc.201500254 · Cited by 302 · see citing works
Self-citationOuyang, M., Ren, D., Lu, L.-G., Li, J.-Q., Feng, X.-N., Han, X.-B., & Liu, G.-M. (2015) · Journal of Power Sources · doi:10.1016/j.jpowsour.2015.01.051 · Cited by 249 · see citing works
Effects of Electrolyte Composition on Lithium Plating in Lithium-Ion Cells
Smart, M., & Ratnakumar, B. (2011) · Journal of The Electrochemical Society · doi:10.1149/1.3544439 · Cited by 238 · see citing works
A new method for detecting lithium plating by measuring the cell thickness
Bitzer, B., & Gruhle, A. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.03.142 · Cited by 237 · see citing works
Lin, L., Xu, X., Chu, C., Majeed, M. K., & Yang, J. (2016) · Angewandte Chemie · doi:10.1002/anie.201608146 · Cited by 217
Ko, M., Chae, S., Jeong, S., Oh, P., & Cho, J. (2014) · ACS Nano · doi:10.1021/nn503294z · Cited by 193
Self-citationHigh‐Rate Capability Silicon Decorated Vertically Aligned Carbon Nanotubes for Li‐Ion Batteries
Gohier, A., Laïk, B., Kim, K.-H., Maurice, J., Pereira-Ramos, J., Cojocaru, C. S., & Van, P. T. (2012) · Advances in Materials · doi:10.1002/adma.201104923 · Cited by 181
KOH etched graphite for fast chargeable lithium-ion batteries
Cheng, Q., Yuge, R., Nakahara, K., Tamura, N., & Miyamoto, S. (2015) · Journal of Power Sources · doi:10.1016/j.jpowsour.2015.03.036 · Cited by 176 · see citing works
Yi, R., Zai, J., Dai, F., Gordin, M. L., & Wang, D.-H. (2014) · doi:10.1016/j.nanoen.2014.04.006 · Cited by 162
Liang, J.-W., Li, X., Hou, Z.-G., Zhang, W.-Q., Zhu, Y.-C., & Qian, Y.-T. (2016) · ACS Nano · doi:10.1021/acsnano.5b06995 · Cited by 132
Micron-sized Fe–Cu–Si ternary composite anodes for high energy Li-ion batteries
Chae, S., Ko, M., Park, S., Kim, N., Ma, J., & Cho, J. (2016) · doi:10.1039/c6ee00023a · Cited by 119
Self-citationJeong, S., Lee, J.-P., Ko, M., Kim, G., Park, S., & Cho, J. (2013) · Nano letters (Print) · doi:10.1021/nl401836c · Cited by 117
Self-citationElectrical transport properties of CoSi2 and NiSi2 thin films
Hensel, J., Tung, R. T., Poate, J., & Unterwald, F. (1984) · doi:10.1063/1.94932 · Cited by 110
High energy density calendered Si alloy/graphite anodes
Du, Z., Dunlap, R. A., & Obrovac, M. N. (2014) · Journal of The Electrochemical Society · doi:10.1149/2.0941410jes · Cited by 107 · see citing works
Studies of the nickel-catalyzed hydrogenation of graphite
Keep, C., Terry, S., & Wells, M. (1980) · doi:10.1016/0021-9517(80)90047-0 · Cited by 81
Mukhopadhyay, A., Guo, F., Tokranov, A., Xiao, X.-C., Hurt, R., & Sheldon, B. W. (2013) · doi:10.1002/adfm.201201128 · Cited by 59
Catalytic subsurface etching of nanoscale channels in graphite
Lukas, M., Meded, V., Vijayaraghavan, A., Song, L., Ajayan, P., Fink, K., Wenzel, W., & Krupke, R. (2012) · Nature Communications · doi:10.1038/ncomms2399 · Cited by 57
Mechanism of graphite hydrogenation catalyzed by nickel
Goethel, P. J., & Yang, R. T. (1987) · doi:10.1016/0021-9517(87)90184-9 · Cited by 56
Deng, T.-S., & Zhou, X.-P. (2016) · doi:10.1016/j.matlet.2016.04.073 · Cited by 45
Ni-Silicide growth kinetics in Si and Si/SiO2 core/shell nanowires
Ogata, K., Sutter, E., Zhu, X., & Hofmann, S. (2011) · Nanotechnology · doi:10.1088/0957-4484/22/36/365305 · Cited by 43
Huang, B., Zheng, X.-D., Fan, X.-P., Song, G., & Lu, M. (2011) · doi:10.1016/j.electacta.2011.02.118 · Cited by 43
Lithium deposition on graphite anode during long-term cycles and the effect on capacity loss
Yang, L., Cheng, X.-Q., Gao, Y.-Z., Ma, Y.-L., Zuo, P.-J., Du, C.-Y., Cui, Y., Guan, T., Lou, S., Wang, F., et al. (2014) · RSC Advances · doi:10.1039/c4ra02096k · Cited by 42 · see citing works
Nanocomb Architecture Design Using Germanium Selenide as High-Performance Lithium Storage Material
Kim, H., Son, Y., Lee, J.-H., Lee, M., Park, S., Cho, J., & Choi, H. (2016) · doi:10.1021/acs.chemmater.6b02016 · Cited by 41
Self-citationCu-Si Nanocable Arrays As High-Rate Anode Materials for Lithium-Ion Batteries
Cao, F.-F., Zhang, Y.-C., & Guo, Y.-G. (2014) · doi:10.1149/ma2014-03/2/73 · Cited by 40
Yuge, R., Tamura, N., Manako, T., Nakano, K., & Nakahara, K. (2014) · doi:10.1016/j.jpowsour.2014.05.068 · Cited by 38
Zaghib, K., Nadeau, G., & Kinoshita, K. (2001) · doi:10.1016/s0378-7753(01)00596-1 · Cited by 35
Kinetic manipulation of silicide phase formation in Si nanowire templates.
Chen, Y., Lin, Y., Zhong, X., Cheng, H.-C., Duan, X., & Huang, Y. (2013) · Nano letters (Print) · doi:10.1021/nl401593f · Cited by 34
The Nanoparticle Size Effect in Graphene Cutting: A "Pac-Man" Mechanism.
Qiu, Z., Song, L., Zhao, J., Li, Z., & Yang, J.-L. (2016) · Angewandte Chemie · doi:10.1002/anie.201602541 · Cited by 31
Zhang, J.-F., Zhu, H.-M., Wu, P., Ge, C.-W., Sun, D.-M., Xu, L., Tang, Y.-W., & Zhou, Y.-M. (2015) · Nanoscale · doi:10.1039/c5nr05568g · Cited by 24
Electrochemical Activity of Nano-NiSi2 in Li Cells
Du, Z.-J., Hatchard, T., Bissonnette, P., Dunlap, R., & Obrovac, M. (2016) · doi:10.1149/2.0061613jes · Cited by 20
Flagged first, then by citations
2 of the 54 references couldn’t be matched to a known paper.
Research works printed but not linked: 1
- [39]Wu H Cui Y Designing nanostructured Si anodes for high energy lithium ion batteries Nano Today 2012 7 414 429 10.1016/j.nantod.2012.08.004 · DOI
Cited by
Sorted by citations
Fast Charging of Lithium‐Ion Batteries: A Review of Materials Aspects
Weiß, M., Ruess, R., Kasnatscheew, J., Levartovsky, Y., Levy, N. R., Minnmann, P., Stolz, L., Waldmann, T., Wohlfahrt-Mehrens, M., Aurbach, D., et al. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202101126 · Cited by 870 · see citing works
Fast charging of energy-dense lithium-ion batteries
Wang, C.-Y., Liu, T., Yang, X.-G., Ge, S., Stanley, N. V., Rountree, E., Leng, Y.-J., & McCarthy, B. D. (2022) · Nature · doi:10.1038/s41586-022-05281-0 · Cited by 824
Chae, S., Choi, S.-H., Kim, N., Sung, J., & Cho, J. (2020) · Angewandte Chemie · doi:10.1002/anie.201902085 · Cited by 722 · see citing works
Self-citationLithium Plating Mechanism, Detection, and Mitigation in Lithium-Ion Batteries
Lin, X., Khosravinia, K., Hu, X., Li, J., & Lu, W. (2021) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2021.100953 · Cited by 490 · see citing works
“A hybrid anode was developed which consists of an edge-plane activated graphite and Si nanolayer (SEAG), where the activated edge-plane increases the site reaction [217].”
BackgroundMethodInfluentialLi, P., Kim, H., Myung, S.-T., & Sun, Y.-K. (2021) · Energy storage materials · doi:10.1016/j.ensm.2020.11.028 · Cited by 447 · see citing works
Recent progress on silicon-based anode materials for practical lithium-ion battery applications
Li, P., Zhao, G., Zheng, X.-B., Xu, X., Yao, C., Sun, W.-P., & Dou, S. X. (2018) · Energy Storage Materials · doi:10.1016/j.ensm.2018.07.014 · Cited by 429
Zhang, C.-Z., Wang, F., Han, J.-Q., Bai, S., Tan, J., Liu, J., & Li, F. (2021) · Small Structures · doi:10.1002/sstr.202100009 · Cited by 361 · see citing works
Challenges and development of lithium-ion batteries for low temperature environments
Piao, N., Gao, X., Yang, H., Guo, Z., Hu, G., Cheng, H.-M., & Li, F. (2022) · eTransportation · doi:10.1016/j.etran.2021.100145 · Cited by 324 · see citing works
Asymmetric Temperature Modulation for Extreme Fast Charging of Lithium-Ion Batteries
Yang, X.-G., Liu, T., Gao, Y., Ge, S., Leng, Y.-J., Wang, D.-H., & Wang, C.-Y. (2019) · Joule · doi:10.1016/j.joule.2019.09.021 · Cited by 321 · see citing works
Tu, S., Zhang, B., Zhang, Y., Chen, Z., Wang, X., Zhan, R., Ou, Y., Wang, W., Liu, X., Duan, X., et al. (2023) · Nature Energy · doi:10.1038/s41560-023-01387-5 · Cited by 400 · see citing works
“25 and 26), which was regarded as the major reason for metallic Li plating at the anode surface 38 .”
Carbon-based materials for fast charging lithium-ion batteries
Li, L., Zhang, D., Deng, J., Gou, Y., Fang, J.-F., Cui, H., Zhao, Y., & Cao, M.-H. (2021) · Carbon · doi:10.1016/j.carbon.2021.07.053 · Cited by 291 · see citing works
Wang, R., Wang, L., Liu, R., Li, X., Wu, Y.-Z., & Ran, F. (2024) · ACS Nano · doi:10.1021/acsnano.3c08712 · Cited by 289 · see citing works
A review on energy chemistry of fast-charging anodes.
Cai, W.-L., Yao, Y.-X., Zhu, G., Yan, C., Jiang, L.-L., He, C.-X., Huang, J.-Q., & Zhang, Q. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00728h · Cited by 285 · see citing works
Fast charging of lithium-ion batteries at all temperatures
Yang, X.-G., Zhang, G.-S., Ge, S., & Wang, C.-Y. (2018) · Proceedings of the National Academy of Sciences of the United States of America · doi:10.1073/pnas.1807115115 · Cited by 280 · see citing works
“To enhance fast charging ability, research in the literature has been focusing on improving anode materials such as coating graphite with an amorphous silicon nanolayer (16, 17) and developing new materials like lithium titanate (18, 19) and graphene balls (20), and on developing new electrolytes (21, 22) and additive…”
BackgroundChallenges and opportunities toward fast-charging of lithium-ion batteries
Xie, W., Liu, X., He, R., Li, Y., Gao, X., Li, X., Peng, Z., Feng, S., Feng, X., & Yang, S. (2020) · Journal of Energy Storage · doi:10.1016/j.est.2020.101837 · Cited by 309 · see citing works
A review of recent developments in Si/C composite materials for Li-ion batteries
Shi, Q.-T., Zhou, J.-H., Ullah, S., Yang, X.-Q., Tokarska, K., Trzebicka, B., Ta, H. Q., & Rümmeli, M. (2021) · Energy storage materials · doi:10.1016/j.ensm.2020.10.026 · Cited by 260 · see citing works
Chen, K.-H., Namkoong, M., Goel, V., Yang, C., Kazemiabnavi, S., Mortuza, S., Kazyak, E., Mazumder, J., Thornton, K., Sakamoto, J., et al. (2020) · Journal of Power Sources · doi:10.1016/j.jpowsour.2020.228475 · Cited by 247 · see citing works
Zhang, Y.-L., Mu, Z., Lai, J., Chao, Y., Yang, Y., Zhou, P., Li, Y.-J., Yang, W.-X., Xia, Z.-H., & Guo, S.-J. (2019) · ACS Nano · doi:10.1021/acsnano.8b08821 · Cited by 237
Cangaz, S., Hippauf, F., Reuter, F. S., Doerfler, S., Abendroth, T., Althues, H., & Kaskel, S. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001320 · Cited by 226
Liang, K., Matsumoto, R. A., Zhao, W., Osti, N., Popov, I., Thapaliya, B., Fleischmann, S., Misra, S., Prenger, K., Tyagi, M., et al. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202104007 · Cited by 198
Few‐Layer Bismuthene with Anisotropic Expansion for High‐Areal‐Capacity Sodium‐Ion Batteries
Zhou, J., Chen, J.-C., Chen, M., Wang, J., Liu, X.-Z., Wei, B., Wang, Z., Li, J.-J., Gu, L., Zhang, Q.-H., et al. (2019) · Advances in Materials · doi:10.1002/adma.201807874 · Cited by 193
Wu, Y., Wang, W., Ming, J., Li, M., Xie, L.-Q., He, X., Wang, J., Liang, S., & Wu, Y.-P. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201805978 · Cited by 192
Li, G., Li, J.-Y., Yue, F., Xu, Q., Zuo, T.-T., Yin, Y.-X., & Guo, Y.-G. (2019) · Nano Energy · doi:10.1016/j.nanoen.2019.03.077 · Cited by 189
Rapid Lithium Diffusion in Order@Disorder Pathways for Fast‐Charging Graphite Anodes
Cai, W.-L., Yan, C., Yao, Y.-X., Xu, L., Xu, R., Jiang, L.-L., Huang, J.-Q., & Zhang, Q. (2020) · Small Structures · doi:10.1002/sstr.202000010 · Cited by 188 · see citing works
Mo, R., Tan, X., Li, F., Tao, R., Xu, J., Kong, D.-J., Wang, Z.-Y., Xu, B., Wang, X., Wang, C.-M., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-14859-z · Cited by 175
Li, G.-X. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202002891 · Cited by 169 · see citing works
Challenges and prospects of nanosized silicon anodes in lithium-ion batteries
Zhao, X.-Y., & Lehto, V. (2020) · Nanotechnology · doi:10.1088/1361-6528/abb850 · Cited by 164
Son, Y., Kim, N., Lee, T., Lee, Y.-S., Ma, J., Chae, S., Sung, J., Cha, H., Yoo, Y., & Cho, J. (2020) · Advances in Materials · doi:10.1002/adma.202003286 · Cited by 164
Self-citationExtremely fast-charging lithium ion battery enabled by dual-gradient structure design
Lu, L.-L., Lu, Y.-Y., Zhu, Z.-X., Shao, J.-X., Yao, H.-B., Wang, S.-G., Zhang, T.-W., Ni, Y., Wang, X.-X., & Yu, S.-H. (2022) · Science Advances · doi:10.1126/sciadv.abm6624 · Cited by 162 · see citing works
“The 12 ), a-Si nanolayer and edge-plane–activated graphite ( 12 ), magnetically aligned graphite ( 9 ), graphite with staged porosity ( 24 ), and KOH-etched graphite ( 42 ).”
Mo, R., Li, F., Tan, X., Xu, P., Tao, R., Shen, G.-R., Lu, X., Liu, F., Shen, L., Xu, B., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-09274-y · Cited by 162
Wang, B., Ryu, J., Choi, S., Zhang, X., Pribat, D., Li, X., Zhi, L., Park, S., & Ruoff, R. (2019) · ACS Nano · doi:10.1021/acsnano.8b09034 · Cited by 161 · see citing works
Singh, A. R., Vishnuram, P., Alagarsamy, S., Bajaj, M., Blažek, V., Damaj, I., Rathore, R. S., Al‐Wesabi, F. N., & Othman, K. M. (2024) · Alexandria Engineering Journal · doi:10.1016/j.aej.2024.06.093 · Cited by 201 · see citing works
Yao, Y., Rui, X.-H., Bai, R.-L., Ouyang, Y., Li, G., Zhao, Y., Zhu, Y.-H., Zhao, M., Li, B.-Q., Zhang, X.-H., et al. (2025) · ACS Nano · doi:10.1021/acsnano.4c10091 · Cited by 142 · see citing works
Self-citationQiu, Z., Tai, C., Niklasson, G., & Edvinsson, T. (2019) · Energy & Environmental Science · doi:10.1039/c8ee03282c · Cited by 138 · see citing works
Ryu, J., Chen, T., Bok, T., Song, G., Ma, J., Hwang, C., Luo, L., Song, H.-K., Cho, J., Wang, C.-M., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-05398-9 · Cited by 134 · see citing works
Self-citationNatarajan, S., Divya, M. L., & Aravindan, V. (2022) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2022.04.012 · Cited by 132 · see citing works
Identifying rate limitation and a guide to design of fast‐charging Li‐ion battery
Zhang, S.-B. (2020) · InfoMat · doi:10.1002/inf2.12058 · Cited by 131 · see citing works
An innovative approach to recover anode from spent lithium-ion battery
Cao, N., Zhang, Y.-L., Chen, L.-L., Chu, W.-D., Huang, Y.-G., Jia, Y., & Wang, M. (2021) · Journal of Power Sources · doi:10.1016/j.jpowsour.2020.229163 · Cited by 130 · see citing works
A cooperative biphasic MoOx–MoPx promoter enables a fast-charging lithium-ion battery
Lee, S.-M., Kim, J., Moon, J., Jung, K.-N., Kim, J. H., Park, G., Choi, J.-H., Rhee, D. Y., Kim, J.-S., Lee, J.-W., et al. (2021) · Nature Communications · doi:10.1038/s41467-020-20297-8 · Cited by 128 · see citing works
Boosting fast energy storage by synergistic engineering of carbon and deficiency
Deng, S., Zhu, H.-K., Wang, G.-Z., Luo, M., Shen, S., Ai, C., Yang, L., Lin, S.-W., Zhang, Q.-H., Gu, L., et al. (2020) · Nature Communications · doi:10.1038/s41467-019-13945-1 · Cited by 128 · see citing works
Kinetic Limits and Enhancement of Graphite Anode for Fast-Charging Lithium-Ion Batteries
Zhong, C., Weng, S., Wang, Z.-X., Zhan, C., & Wang, X.-F. (2023) · Nano Energy · doi:10.1016/j.nanoen.2023.108894 · Cited by 126 · see citing works
Towards high energy density lithium battery anodes: silicon and lithium
Zhu, B., Wang, X., Yao, P.-C., Li, J.-L., & Zhu, J. (2019) · Chemical Science · doi:10.1039/c9sc01201j · Cited by 119 · see citing works
Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries
Tan, S., Shadike, Z., Cai, X., Lin, R., Kludze, A., Borodin, O., Lucht, B. L., Wang, C., Hu, E., Xu, K., et al. (2023) · Electrochemical Energy Reviews · doi:10.1007/s41918-023-00199-1 · Cited by 118 · see citing works
“Typically, surface coating with amorphous silicon nanolayer or doping with nano-metal particles can improve initial Coulombic efficiency and Li + diffusion kinetics [168, 169].”
Dong, Y., Liu, C., Rui, M., Zhang, X., Guan, Y.-B., Chen, L., Huang, Q., Wang, M., Su, Y.-F., Wu, F., et al. (2025) · Advanced Functional Materials · doi:10.1002/adfm.202506190 · Cited by 116 · see citing works
Fast Charging Li-Ion Batteries for a New Era of Electric Vehicles
Li, M., Feng, M., Luo, D., & Chen, Z. (2020) · Cell Reports Physical Science · doi:10.1016/j.xcrp.2020.100212 · Cited by 136 · see citing works
Asymmetric electrolyte design for high-energy lithium-ion batteries with micro-sized alloying anodes
Li, A.-M., Wang, Z.-Y., Lee, T., Zhang, N., Li, T., Zhang, W.-R., Jayawardana, C., Yeddala, M., Lucht, B. L., & Wang, C.-S. (2024) · Nature Energy · doi:10.1038/s41560-024-01619-2 · Cited by 113
“55b) at room temperature, showing great potential for fast-charge LIBs 47,48 .”
InfluentialWu, H., Zheng, L., Zhan, J., Du, N., Liu, W., Ma, J., Su, L.-W., & Wang, L.-B. (2020) · doi:10.1016/j.jpowsour.2019.227513 · Cited by 113
Self-citationKim, J., Nithya Jeghan, S. M., & Lee, G. (2020) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2020.110325 · Cited by 112 · see citing works
Han, M., Mu, Y., Wei, L., Zeng, L., & Zhao, T.-S. (2023) · Carbon Energy · doi:10.1002/cey2.377 · Cited by 111
Senol, M., Bayram, I. S., Naderi, Y., & Galloway, S. (2023) · IEEE Access · doi:10.1109/access.2023.3268615 · Cited by 110 · see citing works
“improve the fast-charging ability of EVs further [137], [138].”
BackgroundMulti-Scale Buffering Engineering in Silicon-Carbon Anode for Ultrastable Li-Ion Storage.
Hou, G., Cheng, B., Yang, Y., Du, Y., Zhang, Y., Li, B., He, J.-P., Zhou, Y., Yi, D., Zhao, N., et al. (2019) · ACS Nano · doi:10.1021/acsnano.9b03355 · Cited by 108
A Scalable Silicon Nanowires-Grown-On-Graphite Composite for High Energy Lithium Batteries.
Karuppiah, S., Keller, C., Kumar, P., Jouneau, P.-H., Aldakov, D., Ducros, J., Lapertot, G., Chenevier, P., & Haon, C. (2020) · ACS Nano · doi:10.1021/acsnano.0c05198 · Cited by 103
Zhao, H., Bo, X., Xu, H., Wang, L., Daoud, W. A., & He, X.-M. (2024) · Energy Storage Materials · doi:10.1016/j.ensm.2024.103696 · Cited by 100
Growing vertical graphene sheets on natural graphite for fast charging lithium-ion batteries
Mu, Y., Han, M., Li, J.-Y., Liang, J.-B., & Yu, J. (2021) · doi:10.1016/j.carbon.2020.11.027 · Cited by 99
Ultrafast charging of energy-dense lithium-ion batteries for urban air mobility
Liu, T., Yang, X.-G., Ge, S., Leng, Y.-J., & Wang, C.-Y. (2021) · eTransportation · doi:10.1016/j.etran.2021.100103 · Cited by 99 · see citing works
He, J., Deng, Y.-B., Han, J., Xu, T., Qi, J., Li, J.-H., Zhang, Y.-B., Zhao, Z., Li, Q., Xiao, J., et al. (2025) · Nature Communications · doi:10.1038/s41467-025-60191-9 · Cited by 95
“4b), the appearance of a new peak at 468 cm − 1 in the SC and SSC samples also supports the amorphous state of the deposited Si 41 .”
Yi, Z., Lin, N., Xu, T.-R., & Qian, Y.-T. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.04.101 · Cited by 95
Yi, S., Yan, Z.-L., Li, X.-D., Wang, Z., Ning, P., Zhang, J.-W., Huang, J., Yang, D.-R., & Du, N. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.145161 · Cited by 94
Silicon-based all-solid-state batteries operating free from external pressure
Zhang, Z.-Y., Zhang, X., Liu, Y., Lan, C.-F., Han, X., Pei, S.-P., Luo, L., Su, P.-F., Zhang, Z.-Q., Liu, J.-J., et al. (2025) · Nature Communications · doi:10.1038/s41467-025-56366-z · Cited by 92
“In this study, we present an anode design to homogenize the electric fi eldofSi-ASSBsviaLi 21 Si 5 alloys,whicheliminatestheneedfor the force fi eldfrom high external pressureand simultaneouslyenables atwofoldenhancementofthelithium-ion fl uxattheanodeinterface.”
Challenges and Strategies for Fast Charge of Li‐Ion Batteries
Zhang, S. S. (2020) · ChemElectroChem · doi:10.1002/celc.202000650 · Cited by 90 · see citing works
Quantification of Pseudocapacitive Contribution in Nanocage‐Shaped Silicon–Carbon Composite Anode
Son, Y., Ma, J., Kim, N., Lee, T., Lee, Y.-S., Sung, J., Choi, S.-H., Nam, G., Cho, H., Yoo, Y., et al. (2019) · Advanced Energy Materials · doi:10.1002/aenm.201803480 · Cited by 90
Self-citationMultiscale Designed Niobium Titanium Oxide Anode for Fast Charging Lithium Ion Batteries
Tian, T., Lu, L.-L., Yin, Y., Li, F., Zhang, T.-W., Song, Y.-H., Tan, Y., & Yao, H.-B. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202007419 · Cited by 88
Structural Design and Challenges of Micron‐Scale Silicon‐Based Lithium‐ion Batteries
He, W., Xu, W., Li, Z.-G., Hu, Z.-T., Yang, J., Qin, G., Teng, W.-M., Zhang, T.-F., Zhang, W., Sun, Z.-M., et al. (2025) · Advancement of science · doi:10.1002/advs.202407540 · Cited by 87
Parikh, D., Christensen, T., & Li, J.-L. (2020) · Journal of Power Sources · doi:10.1016/j.jpowsour.2020.228601 · Cited by 87 · see citing works
Thakur, A., Ahmed, M. S., Kang, H., Prabakaran, R., Said, Z., Rahman, S., Sathyamurthy, R., Kim, J., & Hwang, J.-Y. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202202944 · Cited by 85 · see citing works
A Scalable Silicon/Graphite Anode with High Silicon Content for High-Energy Lithium-Ion Batteries
Yan, Z.-L., Yi, S., Li, X.-D., Jiang, J.-W., Yang, D.-R., & Du, N. (2022) · Social Science Research Network · doi:10.2139/ssrn.4246689 · Cited by 85
Performance degradation due to anodic failure mechanisms in lithium-ion batteries
Sarkar, A., Nlebedim, I., & Shrotriya, P. (2020) · Journal of Power Sources · doi:10.1016/j.jpowsour.2020.229145 · Cited by 85 · see citing works
The synthesis and application of crystalline–amorphous hybrid materials
Lan, H., Wang, J., Cheng, L., Yu, D., Wang, H., & Guo, L. (2023) · Chemical Society Reviews · doi:10.1039/d3cs00860f · Cited by 171 · see citing works
Wang, M., Wang, J.-R., Xiao, J., Ren, N., Pan, B.-C., Chen, C.-S., & Chen, C.-H. (2022) · ACS Applied Materials and Interfaces · doi:10.1021/acsami.2c02169 · Cited by 79 · see citing works
Zhao, H.-L., Zuo, H.-B., Wang, J.-X., & Jiao, S. (2024) · Journal of Energy Storage · doi:10.1016/j.est.2024.113125 · Cited by 77 · see citing works
Zhou, J.-H., Ma, K.-N., Lian, X.-Y., Shi, Q.-T., Wang, J.-Q., Chen, Z., Guo, L.-L., Liu, Y., Bachmatiuk, A., Sun, J.-Y., et al. (2022) · Small · doi:10.1002/smll.202107460 · Cited by 77
Zhang, X., Cui, Z.-H., & Manthiram, A. (2022) · doi:10.1002/aenm.202103611 · Cited by 77
SiOC nanolayers directly-embedded in graphite as stable anode for high-rate lithium ion batteries
Wu, Z.-L., Cheng, X.-Q., Tian, D., Gao, T., He, W.-D., & Yang, C.-H. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.121997 · Cited by 76
Xu, G.-J., Wang, X., Li, J., Shangguan, X.-H., Huang, S.-Q., Lu, D., Chen, B.-B., Ma, J., Dong, S.-M., Zhou, X.-H., et al. (2018) · Chemistry of Materials · doi:10.1021/acs.chemmater.8b03764 · Cited by 76
Self-citationAjdari, F. B., Asghari, P., Aghdam, A. M., Abbasi, F., Rao, R. P., Abbasi, A., Ghasemi, F., Ramakrishna, S., & Chahartagh, N. M. (2024) · Advanced Functional Materials · doi:10.1002/adfm.202314822 · Cited by 75
Heavy oil-derived carbon for energy storage applications
Hu, H., & Wu, M.-B. (2020) · doi:10.1039/d0ta00095g · Cited by 74
Emerging interfacial chemistry of graphite anodes in lithium-ion batteries.
Yao, Y.-X., Yan, C., & Zhang, Q. (2020) · Chemical Communications · doi:10.1039/d0cc05084a · Cited by 72 · see citing works
A Toolbox of Reference Electrodes for Lithium Batteries
Xiao, Y., Xu, R., Yan, C., Huang, J.-Q., Zhang, Q., & Ouyang, M. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202108449 · Cited by 70
JRCS: Joint Routing and Charging Strategy for Logistics Drones
Arafat, M. Y., & Moh, S. (2022) · IEEE Internet of Things Journal · doi:10.1109/jiot.2022.3182750 · Cited by 69 · see citing works
“Currently, batteries have a high capacity and can charge quickly [28].”
BackgroundLee, J., Kim, C., Cheong, J., & Kim, I.-D. (2022) · Chem · doi:10.1016/j.chempr.2022.05.002 · Cited by 69
Design Strategies of Si/C Composite Anode for Lithium-Ion Batteries.
You, S., Tan, H., Wei, L., Tan, W., & Li, C.-C. (2021) · Chemistry · doi:10.1002/chem.202100842 · Cited by 69
Review of resource and recycling of silicon powder from diamond-wire sawing silicon waste.
Li, X., Lv, G.-Q., Ma, W.-H., Li, T., Zhang, R., Zhang, J., Li, S.-Y., & Lei, Y. (2022) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2021.127389 · Cited by 68
Baek, M., Kim, J., Jin, J., & Choi, J. (2021) · Nature Communications · doi:10.1038/s41467-021-27095-w · Cited by 68 · see citing works
“(SO2CF3)N(SO2CF2) – → (SO2CF3)N(SO2CF2) + e (to graphite) (4)”
Fast-Charging Phosphorus-Based Anodes: Promises, Challenges, and Pathways for Improvement.
Han, X., Gong, H., Li, H., & Sun, J. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00646 · Cited by 67 · see citing works
Silicon: toward eco-friendly reduction techniques for lithium-ion battery applications
Zhu, G.-J., Luo, W., Wang, L.-J., Jiang, W., & Yang, J.-P. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta08554h · Cited by 67
Suh, J. H., Han, S. A., Yang, S.-Y., Lee, J. W., Shimada, Y., Lee, S.-M., Lee, J.-W., Park, M., & Kim, J. H. (2025) · Advances in Materials · doi:10.1002/adma.202414117 · Cited by 66
Cai, J., Cai, R., Sun, Z.-T., Wang, X., Wei, N., Xu, F., Shao, Y., Gao, P., Dou, S. X., & Sun, J.-Y. (2020) · Nano-Micro Letters · doi:10.1007/s40820-020-00460-y · Cited by 65
Mu, T., Zuo, P.-J., Lou, S., Pan, Q.-R., Zhang, H., Du, C.-Y., Gao, Y.-Z., Cheng, X.-Q., Ma, Y.-L., Huo, H., et al. (2019) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2018.10.177 · Cited by 63
Astonishing performance improvements of dry-film graphite anode for reliable lithium-ion batteries
Suh, Y., Koo, J., Im, H., & Kim, Y.-J. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.146299 · Cited by 62 · see citing works
Horowitz, Y., Schmidt, C., Yoon, D., Riegger, L., Katzenmeier, L., Bosch, G., Noked, M., Ein-Eli, Y., Janek, J., Zeier, W., et al. (2020) · Energy Technology · doi:10.1002/ente.202000580 · Cited by 62 · see citing works
Liu, S.-G., Liu, B.-W., Yu, Z., Sun, Z., Liu, M., Luo, X., Wang, M.-S., Gao, Y., & Wang, B. (2024) · ACS Nano · doi:10.1021/acsnano.4c06067 · Cited by 61
Rolling up MXene sheets into scrolls to promote their anode performance in lithium-ion batteries
Meng, J., Zhang, F., Zhang, L., Liu, L.-Y., Chen, J.-T., Yang, B.-J., & Yan, X.-B. (2020) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2019.10.008 · Cited by 61
Zhou, P., Zhang, M.-Y., Wang, L., Huang, Q.-Z., Su, Z.-A., Xu, P., Zou, R., Wang, X.-D., Zeng, C., & Ba, K. (2022) · Small · doi:10.1002/smll.202203964 · Cited by 60
Lee, D., Kondo, A., Lee, S.-W., Myeong, S., Sun, S.-H., Hwang, I., Song, T., Naito, M., & Paik, U. (2020) · doi:10.1016/j.jpowsour.2020.228021 · Cited by 60
Amorphous Al2O3 with N-Doped Porous Carbon as Efficient Polysulfide Barrier in Li–S Batteries
Deng, S., Yan, Y.-C., Wei, L., Li, T., Su, X., Yang, X.-J., Li, Z.-T., & Wu, M.-B. (2019) · ACS Applied Energy Materials · doi:10.1021/acsaem.8b01815 · Cited by 59
Extremely Fast-Charging Batteries: Principle, Strategies, Detection, and Prediction.
Liu, H., Zhao, L.-Y., Ye, Y., Yang, X.-T., Zhang, Y., Li, Q., Li, R.-X., Liu, H., Huang, B., Wu, F., et al. (2025) · Chemical Reviews · doi:10.1021/acs.chemrev.5c00203 · Cited by 57 · see citing works
Du, P., Fan, X., Zhang, B., Cao, L., Ren, J., Ou, X., Guo, X.-D., & Liu, Q. (2022) · Energy Storage Materials · doi:10.1016/j.ensm.2022.05.056 · Cited by 56
Kim, J., Park, K., Cho, Y., Shin, H., Kim, S., Char, K., & Choi, J. (2021) · Advancement of science · doi:10.1002/advs.202004290 · Cited by 56
Ayyaswamy, A., Vishnugopi, B., & Mukherjee, P. (2023) · Joule · doi:10.1016/j.joule.2023.07.014 · Cited by 54 · see citing works
Zhu, G.-B., Wang, Y., Yang, S., Qu, Q., & Zheng, H. (2019) · Journal of Materiomics · doi:10.1016/j.jmat.2019.03.005 · Cited by 54
- Authors
- Kim, N., Chae, S., Ma, J., Ko, M., & Cho, J.
- Affiliations
- Ulsan National Institute of Science and Technology (KR)
- Corresponding author
- Ko, Minseong
- Cho, Jaephil
- Venue
- Nature Communications
- Published
- 2017-10-09
- Volume
- 8
- Issue
- 1
- Pages
- 812-812
- ISSN
- 2041-1723 (ISSN-L)
- PMC
- PMC5634447
- OpenAlex
- W2764301473
- Cited by
- 434
- References
- 54
- Citations by year
- 2026: 34 · 2025: 66 · 2024: 67 · 2023: 51 · 2022: 57 · 2021: 47 · 2020: 44 · 2019: 46 · 2018: 22
- FWCI
- 12.73
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Locations
- Nature Communications (publishedVersion, cc-by)
- Europe PMC (PubMed Central) (publishedVersion, cc-by)
- PubMed Central (publishedVersion, cc-by)
- PubMed (publishedVersion)
- RePEc: Research Papers in Economics (submittedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- Scholarworks@UNIST (Ulsan National Institute of Science and Technology) (submittedVersion)
- Funders
- Samsung
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Keywords
- lithium-ion batteries, fast charging, graphite anode, hybrid anode, Coulombic efficiency, lithium plating, energy density, lithium ion transport
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
