The DOI matches its Crossref record; 61 of the 61 references it cites were found in a registry or an index.
A cocoon silk chemistry strategy to ultrathin N-doped carbon nanosheet with metal single-site catalysts
Open accessAbstract
Development of single-site catalysts supported by ultrathin two-dimensional (2D) porous matrix with ultrahigh surface area is highly desired but also challenging. Here we report a cocoon silk chemistry strategy to synthesize isolated metal single-site catalysts embedded in ultrathin 2D porous N-doped carbon nanosheets (M-ISA/CNS, M = Fe, Co, Ni). X-ray absorption fine structure analysis and spherical aberration correction electron microscopy demonstrate an atomic dispersion of metal atoms on N-doped carbon matrix. In particular, the Co-ISA/CNS exhibit ultrahigh specific surface area (2105 m 2 g−1) and high activity for C–H bond activation in the direct catalytic oxidation of benzene to phenol with hydrogen peroxide at room temperature, while the Co species in the form of phthalocyanine and metal nanoparticle show a negligible activity. Density functional theory calculations discover that the generated O = Co = O center intermediates on the single Co sites are responsible for the high activity of benzene oxidation to phenol.
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Self-citationPhotochemical route for synthesizing atomically dispersed palladium catalysts
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Single-Atom Catalysts across the Periodic Table
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General synthesis of single-atom catalysts with high metal loading using graphene quantum dots
Xia, C., Qiu, Y., Xia, Y., Zhu, P., King, G., Zhang, X., Wu, Z., Kim, J. Y., Cullen, D. A., Zheng, D., et al. (2021) · Nature Chemistry · doi:10.1038/s41557-021-00734-x · Cited by 699
Recent Advances for MOF‐Derived Carbon‐Supported Single‐Atom Catalysts
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Metadata
- Authors
- Zhu, Y., Sun, W., Luo, J., Chen, W., Cao, T., Zheng, L., Dong, J., Zhang, J., Zhang, M., Han, Y., Chen, C., Peng, Q., Wang, D., & Li, Y.
- Venue
- Nature Communications
- Published
- 2018-09-21
- Volume
- 9
- Issue
- 1
- Pages
- 3861-3861
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2891832413
- Cited by
- 265
- References
- 61
- FWCI
- 11.11
- Type
- journal article
- Language
- en
- Open access
- gold
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- Zhu, Y., Sun, W., Luo, J., Chen, W., Cao, T., Zheng, L., Dong, J., Zhang, J., Zhang, M., Han, Y., Chen, C., Peng, Q., Wang, D., & Li, Y. (2018). A cocoon silk chemistry strategy to ultrathin N-doped carbon nanosheet with metal single-site catalysts. Nature Communications. https://doi.org/10.1038/s41467-018-06296-w
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