The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
A universal ligand mediated method for large scale synthesis of transition metal single atom catalysts
Open accessAbstract
There is interest in metal single atom catalysts due to their remarkable activity and stability. However, the synthesis of metal single atom catalysts remains somewhat ad hoc, with no universal strategy yet reported that allows their generic synthesis. Herein, we report a universal synthetic strategy that allows the synthesis of transition metal single atom catalysts containing Cr, Mn, Fe, Co, Ni, Cu, Zn, Ru, Pt or combinations thereof. Aberration-corrected high-angle annular dark-field scanning transmission electron microscopy and extended X-ray absorption fine structure spectroscopy confirm that the transition metal atoms are uniformly dispersed over a carbon black support. The introduced synthetic method allows the production of carbon-supported metal single atom catalysts in large quantities (>1 kg scale) with high metal loadings. A Ni single atom catalyst exhibits outstanding activity for electrochemical reduction of carbon dioxide to carbon monoxide, achieving a 98.9% Faradaic efficiency at −1.2 V.
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Cites
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Cited by
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
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Self-citationUniversal strategies to multi-dimensional noble-metal-based catalysts for electrocatalysis
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Metadata
- Authors
- Yang, H., Shang, L., Zhang, Q., Shi, R., Waterhouse, G. I. N., Gu, L., & Zhang, T.
- Venue
- Nature Communications
- Published
- 2019-10-08
- Volume
- 10
- Issue
- 1
- Pages
- 4585-4585
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2979525526
- Cited by
- 721
- References
- 35
- FWCI
- 15.56
- Type
- journal article
- Language
- en
- Open access
- gold
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- Yang, H., Shang, L., Zhang, Q., Shi, R., Waterhouse, G. I. N., Gu, L., & Zhang, T. (2019). A universal ligand mediated method for large scale synthesis of transition metal single atom catalysts. Nature Communications. https://doi.org/10.1038/s41467-019-12510-0
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