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Gram-scale bottom-up flash graphene synthesis
Abstract
Most bulk-scale graphene is produced by a top-down approach, exfoliating graphite, which often requires large amounts of solvent with high-energy mixing, shearing, sonication or electrochemical treatment 1-3. Although chemical oxidation of graphite to graphene oxide promotes exfoliation, it requires harsh oxidants and leaves the graphene with a defective perforated structure after the subsequent reduction step 3,4. Bottom-up synthesis of high-quality graphene is often restricted to ultrasmall amounts if performed by chemical vapour deposition or advanced synthetic organic methods, or it provides a defect-ridden structure if carried out in bulk solution 4-6. Here we show that flash Joule heating of inexpensive carbon sources-such as coal, petroleum coke, biochar, carbon black, discarded food, rubber tyres and mixed plastic waste-can afford gram-scale quantities of graphene in less than one second. The product, named flash graphene (FG) after the process used to produce it, shows turbostratic arrangement (that is, little order) between the stacked graphene layers. FG synthesis uses no furnace and no solvents or reactive gases. Yields depend on the carbon content of the source; when using a high-carbon source, such as carbon black, anthracitic coal or calcined coke, yields can range from 80 to 90 per cent with carbon purity greater than 99 per cent. No purification steps are necessary. Raman spectroscopy analysis shows a low-intensity or absent D band for FG, indicating that FG has among the lowest defect concentrations reported so far for graphene, and confirms the turbostratic stacking of FG, which is clearly distinguished from turbostratic graphite. The disordered orientation of FG layers facilitates its rapid exfoliation upon mixing during composite formation. The electric energy cost for FG synthesis is only about 7.2 kilojoules per gram, which could render FG suitable for use in bulk composites of plastic, metals, plywood, concrete and other building materials.
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In the citing paper
“The Luong team further confirmed that FJH-produced FG possesses the lowest defect concentration, with its turbostratic stacking structure enabling excellent exfoliation properties [54] .”
From Functional carbon materials from waste plastics: synthesis and applications (2025) · cites this paper as [54]
In the citing paper
“The plastic is heated to high temperature in a short period of time, and most non-carbon atoms are removed through sublimation to obtain high-quality turbine layer flash graphene, with a yield of over 90% (Luong et al. 2020).”
From Conversion of waste plastics into value-added carbon materials (2023) · cites this paper as Luong et al. 2020
In the citing paper
“| Flash Joule heat- | Polyethylene tere- | Quartz or ceramic | Greater than 3000 | Graphene | 80-90 | Luong et al. (2020) |”
From Conversion of waste plastics into value-added carbon materials (2023) · cites this paper as Luong et al. (2020)
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Metadata
- Authors
- Luong, D. X., Bets, K. V., Algozeeb, W. A., Stanford, M. G., Kittrell, C., Chen, W., Salvatierra, R. V., Ren, M., McHugh, E. A., Advincula, P. A., Wang, Z., Bhatt, M., Guo, H., Mancevski, V., Shahsavari, R., Yakobson, B. I., & Tour, J. M.
- Affiliations
- Rice University (US)
- Corresponding author
- Shahsavari, Rouzbeh
- Yakobson, Boris I.
- Tour, James M.
- ORCID
- Venue
- Nature
- Published
- 2020-01-27
- Volume
- 577
- Issue
- 7792
- Pages
- 647-651
- ISSN
- 0028-0836 (ISSN-L)
- 1476-4687
- OpenAlex
- W3000867797
- Cited by
- 950
- References
- 36
- Citations by year
- 2026: 167 · 2025: 201 · 2024: 165 · 2023: 131 · 2022: 132 · 2021: 109 · 2020: 45
- FWCI
- 40.48
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Nature (publishedVersion)
- PubMed (publishedVersion)
- RePEc: Research Papers in Economics (submittedVersion)
- Funders
- European Commission (696656)
- Agence Nationale de la Recherche (ANR-10LABX-0026CSC)
- Narodowe Centrum Nauki (2015/18/E/ST5/00188, 2016/21/B/ST5/00175)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Graphene research and applications
- Physical Sciences › Materials Science › Materials Chemistry › Graphite, nuclear technology, radiation studies
- Physical Sciences › Materials Science › Materials Chemistry › Carbon Nanotubes in Composites
- Keywords
- Joule heating, turbostratic stacking, graphene defects, carbon black, coal, petroleum coke, biochar, rubber tires, plastic waste, solvent-free synthesis, graphene composites, energy costs
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