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High Performance Fe- and N- Doped Carbon Catalyst with Graphene Structure for Oxygen Reduction
Open accessAbstract
Proton exchange membrane fuel cells are promising candidates for a clean and efficient energy conversion in the future, the development of carbon based inexpensive non-precious metal ORR catalyst has becoming one of the most attractive topics in fuel cell field. Herein we report a Fe- and N- doped carbon catalyst Fe-PANI/C-Mela with graphene structure and the surface area up to 702 m 2 g −1 . In 0.1 M HClO 4 electrolyte, the ORR onset potential for the catalyst is high up to 0.98 V and the half-wave potential is only 60 mV less than that of the Pt/C catalyst (Loadings: 51 μg Pt cm −2 ). The catalyst shows high stability after 10,000 cyclic voltammetry cycles. A membrane electrode assembly made with the catalyst as a cathode is tested in a H 2 -air single cell, the maximum power density reached ~0.33 W cm 2 at 0.47 V.
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Self-citation
Metadata
- Authors
- Peng, H., Mo, Z., Liao, S., Liang, H., Yang, L., Luo, F., Song, H., Zhong, Y., & Zhang, B.
- Venue
- Scientific Reports
- Published
- 2013-05-03
- Volume
- 3
- Issue
- 1
- ISSN
- 2045-2322 (ISSN-L)
- OpenAlex
- W2068470686
- Cited by
- 601
- References
- 37
- FWCI
- 25.97
- Type
- journal article
- Language
- en
- Open access
- gold
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