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Cited by 353

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Facile, scalable synthesis of edge-halogenated graphene nanoplatelets as efficient metal-free eletrocatalysts for oxygen reduction reaction

Open access
Jeon, In-Yup, Choi, Hyun-Jung, Choi, Min, Seo, Jeong-Min, Jung, Sun-Min, Kim, Min-Jung, Zhang, Sheng, Zhang, Lipeng, Xia, Zhenhai, Dai, Liming, Park, Noejung, Baek, Jong-Beom·2013·Scientific Reports

Abstract

A series of edge-selectively halogenated (X = Cl, Br, I) graphene nanoplatelets (XGnPs = ClGnP, BrGnP, IGnP) were prepared simply by ball-milling graphite in the presence of Cl2, Br2 and I2, respectively. High BET surface areas of 471, 579 and 662 m(2)/g were observed for ClGnP, BrGnP and IGnP, respectively, indicating a significant extent of delamination during the ball-milling and subsequent workup processes. The newly-developed XGnPs can be well dispersed in various solvents, and hence are solution processable. Furthermore, XGnPs showed remarkable electrocatalytic activities toward oxygen reduction reaction (ORR) with a high selectivity, good tolerance to methanol crossover/CO poisoning effects, and excellent long-term cycle stability. First-principle density-functional calculations revealed that halogenated graphene edges could provide decent adsorption sites for oxygen molecules, in a good agreement with the experimental observations.

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Metadata

Authors
Jeon, I.-Y., Choi, H.-J., Choi, M., Seo, J.-M., Jung, S.-M., Kim, M.-J., Zhang, S., Zhang, L., Xia, Z., Dai, L., Park, N., & Baek, J.-B.
Venue
Scientific Reports
Published
2013-06-05
Volume
3
Issue
1
Pages
1810-1810
ISSN
2045-2322 (ISSN-L)
OpenAlex
W2150556972
Cited by
353
References
3
FWCI
15.39
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Facile, scalable synthesis of edge-halogenated graphene nanoplatelets as efficient metal-free eletrocatalysts for oxygen reduction reaction. https://app.cochat.ai/papers/10.1038/srep01810
The paper
Jeon, I.-Y., Choi, H.-J., Choi, M., Seo, J.-M., Jung, S.-M., Kim, M.-J., Zhang, S., Zhang, L., Xia, Z., Dai, L., Park, N., & Baek, J.-B. (2013). Facile, scalable synthesis of edge-halogenated graphene nanoplatelets as efficient metal-free eletrocatalysts for oxygen reduction reaction. Scientific Reports. https://doi.org/10.1038/srep01810

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