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Cited by 311

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Polyethyleneimine Incorporated Metal-Organic Frameworks Adsorbent for Highly Selective CO2 Capture

Open access
Lin, Yichao, Yan, Qiuju, Kong, Chunlong, Chen, Liang·2013·Scientific Reports

Abstract

A series of polyethyleneimine (PEI) incorporated MIL-101 adsorbents with different PEI loadings were reported for the first time in the present work. Although the surface area and pore volume of MIL-101 decreased significantly after loading PEI, all the resulting composites exhibited dramatically enhanced CO2 adsorption capacity at low pressures. At 100 wt% PEI loading, the CO2 adsorption capacity at 0.15 bar reached a very competitive value of 4.2 mmol g(-1) at 25°C, and 3.4 mmol g(-1) at 50°C. More importantly, the resulting adsorbents displayed rapid adsorption kinetics and ultrahigh selectivity for CO2 over N2 in the designed flue gas with 0.15 bar CO2 and 0.75 bar N2. The CO2 over N2 selectivity was up to 770 at 25°C, and 1200 at 50°C. We believe that the PEI based metal-organic frameworks is an attractive adsorbent for CO2 capture.

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Metadata

Authors
Lin, Y., Yan, Q., Kong, C., & Chen, L.
Venue
Scientific Reports
Published
2013-05-17
Volume
3
Issue
1
Pages
1859-1859
ISSN
2045-2322 (ISSN-L)
OpenAlex
W2040123693
Cited by
311
References
36
FWCI
23.91
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Polyethyleneimine Incorporated Metal-Organic Frameworks Adsorbent for Highly Selective CO2 Capture. https://app.cochat.ai/papers/10.1038/srep01859
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Lin, Y., Yan, Q., Kong, C., & Chen, L. (2013). Polyethyleneimine Incorporated Metal-Organic Frameworks Adsorbent for Highly Selective CO2 Capture. Scientific Reports. https://doi.org/10.1038/srep01859

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