The DOI matches its Crossref record; 30 of the 30 references it cites were found in a registry or an index.
An NMR Study of Biomimetic Fluorapatite – Gelatine Mesocrystals
Open accessAbstract
The mesocrystal system fluoroapatite—gelatine grown by double-diffusion is characterized by hierarchical composite structure on a mesoscale. In the present work we apply solid state NMR to characterize its structure on the molecular level and provide a link between the structural organisation on the mesoscale and atomistic computer simulations. Thus, we find that the individual nanocrystals are composed of crystalline fluorapatite domains covered by a thin boundary apatite-like layer. The latter is in contact with an amorphous layer, which fills the interparticle space. The amorphous layer is comprised of the organic matrix impregnated by isolated phosphate groups, Ca 3 F motifs and water molecules. Our NMR data provide clear evidence for the existence of precursor complexes in the gelatine phase, which were not involved in the formation of apatite crystals, proving hence theoretical predictions on the structural pre-treatment of gelatine by ion impregnation. The interfacial interactions, which may be described as the glue holding the composite materials together, comprise hydrogen bond interactions with the apatite PO 43− groups. The reported results are in a good agreement with molecular dynamics simulations, which address the mechanisms of a growth control by collagen fibers and with experimental observations of an amorphous cover layer in biominerals.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Modelling one‐ and two‐dimensional solid‐state NMR spectra
Massiot, D., Fayon, F., Capron, M., King, I., Le Calvé, S., Alonso, B., Durand, J., Bujoli, B., Gan, Z., & Hoatson, G. (2002) · Magnetic Resonance in Chemistry · doi:10.1002/mrc.984 · Cited by 4,279
Cölfen, H., & Antonietti, M. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200500496 · Cited by 1,728
Properties and emerging applications of self-assembled structures made from inorganic nanoparticles
Nie, Z., Petukhova, A., & Kumacheva, E. (2010) · Nature Nanotechnology · doi:10.1038/nnano.2009.453 · Cited by 1,598
Controlling Mineral Morphologies and Structures in Biological and Synthetic Systems
Meldrum, F. C., & Cölfen, H. (2008) · Chemical Reviews · doi:10.1021/cr8002856 · Cited by 1,397
Designing PbSe Nanowires and Nanorings through Oriented Attachment of Nanoparticles
Cho, K.-S., Talapin, D. V., Gaschler, W., & Murray, C. B. (2005) · Journal of the American Chemical Society · doi:10.1021/ja050107s · Cited by 1,215
Sea Urchin Spine Calcite Forms via a Transient Amorphous Calcium Carbonate Phase
Politi, Y., Arad, T., Klein, E., Weiner, S., & Addadi, L. (2004) · Science · doi:10.1126/science.1102289 · Cited by 963
Habraken, W. J. E. M., Tao, J., Brylka, L. J., Friedrich, H., Bertinetti, L., Schenk, A. S., Verch, A., Dmitrovic, V., Bomans, P. H. H., Frederik, P. M., et al. (2013) · Nature Communications · doi:10.1038/ncomms2490 · Cited by 821
Mesocrystals and Nonclassical Crystallization
Cölfen, H., & Antonietti, M. (2008) · Wiley eBooks · doi:10.1002/9780470994603 · Cited by 614
Mesocrystals—Ordered Nanoparticle Superstructures
Song, R., & Cölfen, H. (2010) · Advanced Materials · doi:10.1002/adma.200901365 · Cited by 590
Amorphous layer around aragonite platelets in nacre
Nassif, N., Pinna, N., Gehrke, N., Antonietti, M., Jäger, C., & Cölfen, H. (2005) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0502577102 · Cited by 371
Cited by
Supramolecular engineering of hydrogels for drug delivery
Bernhard, S., & Tibbitt, M. W. (2021) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2021.02.002 · Cited by 363
Fehr, J., Konigorski, S., Olivier, S., Gunda, R., Surujdeen, A., Gareta, D., Smit, T., Baisley, K., Moodley, S., Moosa, Y., et al. (2021) · npj Digital Medicine · doi:10.1038/s41746-021-00471-y · Cited by 74
Gut microbiome approaches to treat obesity in humans
Bianchi, F., Duque, A. L. R. F., Saad, S. M. I., & Sivieri, K. (2019) · Applied Microbiology and Biotechnology · doi:10.1007/s00253-018-9570-8 · Cited by 63
Biological effects of in vitro THz radiation exposure in human foetal fibroblasts
Amicis, A. D., Sanctis, S. D., Cristofaro, S. D., Franchini, V., Lista, F., Regalbuto, E., Giovenale, E., Gallerano, G. P., Nenzi, P., Bei, R., et al. (2015) · Mutation Research/Genetic Toxicology and Environmental Mutagenesis · doi:10.1016/j.mrgentox.2015.06.003 · Cited by 62
Comparing the tractability of young hand-raised wolves (Canis lupus) and dogs (Canis familiaris)
Ujfalussy, D. J., Virányi, Z., Gácsi, M., Faragó, T., Pogány, Á., Bereczky, B. M., Miklósi, Á., & Kubinyi, E. (2020) · Scientific Reports · doi:10.1038/s41598-020-71687-3 · Cited by 16
Metadata
- Authors
- Vyalikh, A., Simon, P., Rosseeva, E., Buder, J., Scheler, U., & Kniep, R.
- Venue
- Scientific Reports
- Published
- 2015-10-30
- Volume
- 5
- Issue
- 1
- Pages
- 15797-15797
- ISSN
- 2045-2322 (ISSN-L)
- OpenAlex
- W1874509609
- Cited by
- 275
- References
- 30
- FWCI
- 7.20
- Type
- journal article
- Language
- en
- Open access
- gold
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: An NMR Study of Biomimetic Fluorapatite – Gelatine Mesocrystals. https://app.cochat.ai/papers/10.1038/srep15797
- The paper
- Vyalikh, A., Simon, P., Rosseeva, E., Buder, J., Scheler, U., & Kniep, R. (2015). An NMR Study of Biomimetic Fluorapatite – Gelatine Mesocrystals. Scientific Reports. https://doi.org/10.1038/srep15797
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
