The DOI matches its Crossref record; 25 of the 25 references it cites were found in a registry or an index.
Cross-linked Composite Gel Polymer Electrolyte using Mesoporous Methacrylate-Functionalized SiO2 Nanoparticles for Lithium-Ion Polymer Batteries
Open accessAbstract
Liquid electrolytes composed of lithium salt in a mixture of organic solvents have been widely used for lithium-ion batteries. However, the high flammability of the organic solvents can lead to thermal runaway and explosions if the system is accidentally subjected to a short circuit or experiences local overheating. In this work, a cross-linked composite gel polymer electrolyte was prepared and applied to lithium-ion polymer cells as a safer and more reliable electrolyte. Mesoporous SiO 2 nanoparticles containing reactive methacrylate groups as cross-linking sites were synthesized and dispersed into the fibrous polyacrylonitrile membrane. They directly reacted with gel electrolyte precursors containing tri(ethylene glycol) diacrylate, resulting in the formation of a cross-linked composite gel polymer electrolyte with high ionic conductivity and favorable interfacial characteristics. The mesoporous SiO 2 particles also served as HF scavengers to reduce the HF content in the electrolyte at high temperature. As a result, the cycling performance of the lithium-ion polymer cells with cross-linked composite gel polymer electrolytes employing methacrylate-functionalized mesoporous SiO 2 nanoparticles was remarkably improved at elevated temperatures.
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Nanoparticles: Properties, applications and toxicities
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Polymers in Lithium‐Ion and Lithium Metal Batteries
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Metadata
- Authors
- Shin, W.-K., Cho, J., Kannan, A. G., Lee, Y.-S., & Kim, D.-W.
- Venue
- Scientific Reports
- Published
- 2016-05-18
- Volume
- 6
- Issue
- 1
- Pages
- 26332-26332
- ISSN
- 2045-2322 (ISSN-L)
- OpenAlex
- W2401263926
- Cited by
- 283
- References
- 25
- FWCI
- 6.86
- Type
- journal article
- Language
- en
- Open access
- gold
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