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Combination of ring-opening polymerization and “click” chemistry towards functionalization of aliphatic polyesters
Open accessAbstract
Azide pendent groups of aliphatic polyesters have been derivatized into tertiary amines, ammonium salts and poly(ethylene oxide) grafts. The experimental conditions have been optimized (organic solvent, 35 degrees C), such that the aliphatic polyesters are not degraded, including even poly(lactide) which is very sensitive to attack by weak nucleophiles.
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“ω-alkyne-PEO with poly(αN 3 εCL-co-LA), provided that the OH end-groups of the copolylactide chains are previously esterified with acetyl chloride gives PLA-g-PEO graft amphiphilic copolymers (Scheme 17) [154],”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [154]
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Metadata
- Authors
- Riva, R., Schmeits, S., Stoffelbach, F., Jérôme, C., Jérôme, R., & Lecomte, P.
- Affiliations
- University of Liège (BE)
- Corresponding author
- Jérôme, Robert
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2005
- Issue
- 42
- Pages
- 5334
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2083415276
- Cited by
- 208
- References
- 7
- Citations by year
- 2025: 2 · 2024: 8 · 2023: 3 · 2022: 4 · 2021: 4 · 2020: 2 · 2019: 6 · 2018: 7 · 2017: 8 · 2016: 4 · 2015: 10 · 2014: 10 · 2013: 17 · 2012: 17
- FWCI
- 9.36
- Type
- journal article
- Language
- en
- Open access
- green
- orbi.uliege.be
- Licence
- other-oa
- Locations
- Chemical Communications (publishedVersion)
- PubMed (publishedVersion)
- Open Repository and Bibliography (University of Liège) (submittedVersion, other-oa)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Chemistry › Organic Chemistry › Click Chemistry and Applications
- Keywords
- aliphatic polyesters, ring-opening polymerization, click chemistry, azide functionalization, tertiary amines, ammonium salts, polylactic acid, graft copolymerization
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