Synthesis and post-polymerisation modifications of aliphatic poly(carbonate)s prepared by ring-opening polymerisation
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Owing to their low toxicity, biocompatibility and biodegradability, aliphatic poly(carbonate)s have been widely studied as materials for biomedical application. Furthermore, the synthetic versatility of the six-membered cyclic carbonates for the realization of functional degradable polymers by ring-opening polymerisation has driven wider interest in this area. In this review, the synthesis and ring-opening polymerisation of functional cyclic carbonates that have been reported in the literature in the past decade are discussed. Finally, the post-polymerisation modification methods that have been applied to the resulting homopolymers and copolymers and the application of the materials are also discussed.
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The synthetic versatility of six-membered cyclic carbonates allows the incorporation of a wide range of functional groups to the resulting polycarbonates, which has led to a versatile material platform for biomedical applications.
“The synthetic versatility of 6CCs allows the incorporation of a wide range of functional groups to the resulting polycarbonates, which has led to a versatile material platform for biomedical applications.”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [282]
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- Authors
- Tempelaar, S., Mespouille, L., Coulembier, O., Dubois, P., & Dove, A. P.
- Affiliations
- University of Warwick (GB)
- University of Mons (BE)
- Corresponding author
- Dove, Andrew P.
- Venue
- Chem. Soc. Rev.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 42
- Issue
- 3
- Pages
- 1312-1336
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2130472233
- Cited by
- 345
- References
- 163
- Citations by year
- 2026: 4 · 2025: 17 · 2024: 19 · 2023: 22 · 2022: 29 · 2021: 28 · 2020: 27 · 2019: 32 · 2018: 33 · 2017: 34 · 2016: 31 · 2015: 30 · 2014: 22 · 2013: 15 · 2012: 2
- FWCI
- 1.14
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- cc-by
- Locations
- Chemical Society Reviews (publishedVersion, cc-by)
- PubMed (publishedVersion)
- University of Birmingham Research Portal (University of Birmingham) (submittedVersion)
- Funders
- Research Councils UK
- European Commission
- Fonds De La Recherche Scientifique - FNRS
- Belgian Federal Science Policy Office (PAI-6/27)
- Promotion and Mutual Aid Corporation for Private Schools of Japan
- Engineering and Physical Sciences Research Council (EP/F068808/1)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- cyclic carbonates, ring-opening polymerization, biodegradable polymers, biocompatible polymers, functional copolymers, homopolymers, biomedical materials
- MeSH terms
- Biocompatible Materials, Carbonates, Polycarboxylate Cement, Polymerization
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