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The role of twinning in shape evolution of anisotropic noble metal nanostructures

Elechiguerra, Jose Luis, Reyes-Gasga, Jose, Yacaman, Miguel Jose·2006·Journal of Materials Chemistry
DOI 10.1039/b607128g
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Abstract

Nanotechnology provides the ability to engineer the properties of materials by controlling their size and shape. Among the most interesting nanostructures are anisotropic noble metal nanocrystals such as nanorods and nanowires. Nevertheless, the production of such crystals in a controlled fashion remains as a challenging task, and many available colloidal techniques produce a mixture of morphologies. In cases where high yields of a particular anisotropic structure have been produced, the growth mechanism has been primarily explained in terms of the presence of surfactants or capping agents that regulate the growth of the crystal in a particular direction. However, the growth mechanism should also consider nucleation and kinetics, and not only thermodynamics or physical restrictions imposed by the surface stabilizing agent. In this work, we present several examples of anisotropic noble metal nanocrystals obtained by different methods. Finally, the important role of twinning in determining the habit of the final morphology is discussed.

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Metadata

Authors
Elechiguerra, J. L., Reyes-Gasga, J., & Yacaman, M. J.
Venue
Journal of Materials Chemistry
Publisher
Royal Society of Chemistry (RSC)
Published
2006
Volume
16
Issue
40
Pages
3906
ISSN
  • 0959-9428 (ISSN-L)
  • 1364-5501
DOI
10.1039/b607128g
OpenAlex
W2092188508
Cited by
491
References
2
FWCI
16.50
Type
journal article
Language
en
Open access
closed

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Elechiguerra, J. L., Reyes-Gasga, J., & Yacaman, M. J. (2006). The role of twinning in shape evolution of anisotropic noble metal nanostructures. Journal of Materials Chemistry. https://doi.org/10.1039/b607128g

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