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Cellulose dissolution with polar ionic liquids under mild conditions: required factors for anions
Abstract
A series of alkylimidazolium salts containing dimethyl phosphate, methyl methylphosphonate, or methyl phosphonate prepared by a facile, one-pot procedure were obtained as room temperature ionic liquids, which have the potential to solubilize cellulose under mild conditions. Especially, N-ethyl-N′-methylimidazolium methylphosphonate enables the preparation of 10 wt% cellulose solution by keeping it at 45 °C for 30 min with stirring and rendered soluble 2–4 wt% cellulose without pretreatments and heating.
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“Cellulose dissolution is an industrially attractive application of ionic liquids, due to good solubilities (5-20 wt%, depending on the ionic liquid and the conditions), the competitive properties of cellulose reprecipitated from the ionic liquid solutions, 73 the increased stability of ionic liquid cellulose solutions 74 and the low toxicity of certain relevant ionic liquids (for example, [C 2 C 1”
From Deconstruction of lignocellulosic biomass with ionic liquids (2013) · cites this paper as [73]
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Metadata
- Authors
- Fukaya, Y., Hayashi, K., Wada, M., & Ohno, H.
- Affiliations
- Tokyo University of Agriculture and Technology (JP)
- The University of Tokyo (JP)
- Corresponding author
- Ohno, Hiroyuki
- Venue
- Green Chem.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2008
- Volume
- 10
- Issue
- 1
- Pages
- 44-46
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W1980836177
- Cited by
- 775
- References
- 23
- Citations by year
- 2026: 12 · 2025: 14 · 2024: 20 · 2023: 15 · 2022: 30 · 2021: 24 · 2020: 33 · 2019: 60 · 2018: 42 · 2017: 67 · 2016: 50 · 2015: 58 · 2014: 75 · 2013: 58 · 2012: 63
- FWCI
- 13.36
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Green Chemistry (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Ionic liquids properties and applications
- Physical Sciences › Materials Science › Biomaterials › Advanced Cellulose Research Studies
- Physical Sciences › Chemical Engineering › Catalysis › Catalysis for Biomass Conversion
- Keywords
- cellulose dissolution, room temperature ionic liquids, anion effects, dimethyl phosphate, cellulose solubilization, cellulose solutions
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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