Cited by 775Ionic liquids properties and applicationsAdvanced Cellulose Research StudiesCatalysis for Biomass Conversion

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Cellulose dissolution with polar ionic liquids under mild conditions: required factors for anions

Fukaya, Yukinobu, Hayashi, Kensaku, Wada, Masahisa, Ohno, Hiroyuki·2008·Green Chem.

DOI 10.1039/b713289a

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Abstract

A series of alkylimidazolium salts containing dimethyl phosphate, methyl methylphosphonate, or methyl phosphonate prepared by a facile, one-pot procedure were obtained as room temperature ionic liquids, which have the potential to solubilize cellulose under mild conditions. Especially, N-ethyl-N′-methylimidazolium methylphosphonate enables the preparation of 10 wt% cellulose solution by keeping it at 45 °C for 30 min with stirring and rendered soluble 2–4 wt% cellulose without pretreatments and heating.

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Authors: Fukaya, Y., Hayashi, K., Wada, M., & Ohno, H.
Affiliations: Tokyo University of Agriculture and Technology (JP)
The University of Tokyo (JP)
Corresponding author: Ohno, Hiroyuki
ORCID: Wada, Masahisa
Ohno, Hiroyuki
Venue: Green Chem.
Publisher: Royal Society of Chemistry (RSC)
Published: 2008
Volume: 10
Issue: 1
Pages: 44-46
ISSN: 1463-9262 (ISSN-L)
1463-9270
DOI: 10.1039/b713289a
OpenAlex: W1980836177
Cited by: 775
References: 23
Citations by year: 2026: 12 · 2025: 14 · 2024: 20 · 2023: 15 · 2022: 30 · 2021: 24 · 2020: 33 · 2019: 60 · 2018: 42 · 2017: 67 · 2016: 50 · 2015: 58 · 2014: 75 · 2013: 58 · 2012: 63
FWCI: 13.36
Type: journal article
Language: en
Open access: closed
Locations: Green Chemistry (publishedVersion)
Topics: Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Ionic liquids properties and applications
Physical Sciences › Materials Science › Biomaterials › Advanced Cellulose Research Studies
Physical Sciences › Chemical Engineering › Catalysis › Catalysis for Biomass Conversion
Keywords: cellulose dissolution, room temperature ionic liquids, anion effects, dimethyl phosphate, cellulose solubilization, cellulose solutions

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Cellulose dissolution with polar ionic liquids under mild conditions: required factors for anions

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