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Luminescent chiral lanthanide(iii) complexes as potential molecular probes
Open accessAbstract
This perspective gives an introduction into the design of luminescent lanthanide(iii)-containing complexes possessing chiral properties and used to probe biological materials. The first part briefly describes general principles, focusing on the optical aspect (i.e. lanthanide luminescence, sensitization processes) of the most emissive trivalent lanthanide ions, europium and terbium, incorporated into molecular luminescent edifices. This is followed by a short discussion on the importance of chirality in the biological and pharmaceutical fields. The second part is devoted to the assessment of the chiroptical spectroscopic tools available (typically circular dichroism and circularly polarized luminescence) and the strategies used to introduce a chiral feature into luminescent lanthanide(iii) complexes (chiral structure resulting from a chiral arrangement of the ligand molecules surrounding the luminescent center or presence of chiral centers in the ligand molecules). Finally, the last part illustrates these fundamental principles with recent selected examples of such chiral luminescent lanthanide-based compounds used as potential probes of biomolecular substrates.
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Cites
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Cited by
Lanthanide Circularly Polarized Luminescence: Bases and Applications
Zinna, F., & Di Bari, L. (2015) · Chirality · doi:10.1002/chir.22382 · Cited by 608
Lo, K. K.-W., Choi, A. W.-T., & Law, W. H.-T. (2012) · Dalton Transactions · doi:10.1039/c2dt11892k · Cited by 386
Ni, F., Zhu, Z., Tong, X., Xie, M., Zhao, Q., Zhong, C., Zou, Y., & Yang, C. (2018) · Chemical Science · doi:10.1039/c8sc01485j · Cited by 142
Symmetry Breaking in Self-Assembled Nanoassemblies
Sang, Y., & Liu, M. (2019) · Symmetry · doi:10.3390/sym11080950 · Cited by 35
Metadata
- Authors
- Muller, G.
- Venue
- Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2009
- Issue
- 44
- Pages
- 9692
- ISSN
- 1477-9226 (ISSN-L)
- 1477-9234
- OpenAlex
- W2012086002
- Cited by
- 364
- References
- 50
- FWCI
- 8.61
- Type
- journal article
- Language
- en
- Open access
- green
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