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Cited by 356

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Sandwich-type functionalized graphene sheet-sulfur nanocomposite for rechargeable lithium batteries

Cao, Yuliang, Li, Xiaolin, Aksay, Ilhan A., Lemmon, John, Nie, Zimin, Yang, Zhenguo, Liu, Jun·2011·Physical Chemistry Chemical Physics

Abstract

A functionalized graphene sheet-sulfur (FGSS) nanocomposite was synthesized as the cathode material for lithium-sulfur batteries. The structure has a layer of functionalized graphene sheets/stacks (FGS) and a layer of sulfur nanoparticles creating a three-dimensional sandwich-type architecture. This unique FGSS nanoscale layered composite has a high loading (70 wt%) of active material (S), a high tap density of ∼0.92 g cm(-3), and a reversible capacity of ∼505 mAh g(-1) (∼464 mAh cm(-3)) at a current density of 1680 mA g(-1) (1C). When coated with a thin layer of cation exchange Nafion film, the migration of dissolved polysulfide anions from the FGSS nanocomposite was effectively reduced, leading to a good cycling stability of 75% capacity retention over 100 cycles. This sandwich-structured composite conceptually provides a new strategy for designing electrodes in energy storage applications.

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Metadata

Authors
Cao, Y., Li, X., Aksay, I. A., Lemmon, J., Nie, Z., Yang, Z., & Liu, J.
Venue
Physical Chemistry Chemical Physics
Published
2011
Volume
13
Issue
17
Pages
7660
ISSN
  • 1463-9076 (ISSN-L)
  • 1463-9084
OpenAlex
W2165881868
Cited by
356
References
1
FWCI
35.21
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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